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991.
Zhenpin Lu Luca Schweighauser Dr. Heike Hausmann Prof. Dr. Hermann A. Wegner 《Angewandte Chemie (International ed. in English)》2015,54(51):15556-15559
The storage of energy in a safe and environmentally benign way is one of the main challenges of today’s society. Ammonia–borane (AB=NH3BH3) has been proposed as a possible candidate for the chemical storage of hydrogen. However, the efficient release of hydrogen is still an active field of research. Herein, we present a metal‐free bis(borane) Lewis acid catalyst that promotes the evolution of up to 2.5 equivalents of H2 per AB molecule. The catalyst can be reused multiple times without loss of activity. The moderate temperature of 60 °C allows for controlling the supply of H2 on demand simply by heating and cooling. Mechanistic studies give preliminary insights into the kinetics and mechanism of the catalytic reaction. 相似文献
992.
Annamaria Giorgi Alessandra Manzo Niranjala Nanayakkarawasam Masachchige Chandrika Nanayakkara Luca Giupponi Maurizio Cocucci Sara Panseri 《Natural product research》2015,29(18):1695-1702
This study describes the application of headspace solid-phase microextraction (HS-SPME)–gas chromatography/mass spectrometry (GC/MS) to characterise the volatile fingerprint changes of Achillea collina, induced by aphids' infestation, mechanical damage and jasmonic acid (JA) treatment. The volatile organic compound profiles of A. collina, Prunus persica and Pisum sativum infested by Myzus persicae were also compared. Several changes were observed between control, infested, mechanically damaged and JA-treated plants, and new inducible volatile organic compounds (IVOCs) were emitted in response to biotic or abiotic stresses. Some of these were in common for all stresses and other compounds were in common only for two types of stress. Conversely some IVOCs were emitted only in response to the specific stimuli. The results suggested that there were species-specific and common IVOCs emitted by A. collina, P. persica and P. sativum in response to M. persicae infestation. In conclusion, HS-SPME–GC/MS seems to be a reliable analytical approach to study in vivo plant reaction to external stimuli. 相似文献
993.
Assessment of the Antioxidant Capacity of Standard Compounds and Fruit Juices by a Newly Developed Electrochemical Method: Comparative Study with Results from Other Analytical Methods 下载免费PDF全文
Isacco Gualandi Luca Ferraro Pietro Matteucci Domenica Tonelli 《Electroanalysis》2015,27(8):1906-1914
The antioxidant capacity (AOC) of some standard compounds and commercial beverages was determined using an electroanalytical method which measures the OH radical scavenging ability (OH‐RSC). It is based on the degradation of a thin polyphenol film electrodeposited on glassy carbon following the attack by OH radicals produced by hydrogen peroxide photolysis. The degradation is prevented in presence of increasing concentrations of antioxidants. The same samples were also analyzed by DPPH, ABTS, and ORAC assays. The OH‐RSC method provided AOC values highly correlated with those resulting from the application of ORAC assay for both juices (R=0.90) and standard antioxidants (R=0.96). 相似文献
994.
Innocenzi P Figus C Takahashi M Piccinini M Malfatti L 《The journal of physical chemistry. A》2011,115(38):10438-10444
Time resolved infrared spectroscopy has been applied to study in situ the evaporation process of a 3-glycidoxypropyltrimethoxysilane hybrid sol by casting a droplet on a ZnSe substrate; the analysis has been performed in the middle-infrared range and in the near-infrared range. The experiment has allowed following the structural changes induced by water evaporation and the formation of ordered structures within the cast film; the CH(2) scissoring bands have been used as a fingerprint for the disorder to order transition of the hybrid. The experiment has been done using both a fresh sol and an aged sol which produce respectively an amorphous material and a crystalline hybrid material. The analysis has shown that the epoxy groups do not react during the evaporation while the silica structure shows only a slight condensation and an increase in open cage-like species. At the end of evaporation the hybrid has a "soft-like" state which allows structural rearrangements to self-order. 相似文献
995.
A chemometric approach based on the combined use of the principal component analysis (PCA) and artificial neural network (ANN) was developed for the multicomponent determination of caffeine (CAF), mepyramine (MEP), phenylpropanolamine (PPA) and pheniramine (PNA) in their pharmaceutical preparations without any chemical separation. The predictive ability of the ANN method was compared with the classical linear regression method Partial Least Squares 2 (PLS2). The UV spectral data between 220 and 300 nm of a training set of sixteen quaternary mixtures were processed by PCA to reduce the dimensions of input data and eliminate the noise coming from instrumentation. Several spectral ranges and different numbers of principal components (PCs) were tested to find the PCA-ANN and PLS2 models reaching the best determination results. A two layer ANN, using the first four PCs, was used with log-sigmoid transfer function in first hidden layer and linear transfer function in output layer. Standard error of prediction (SEP) was adopted to assess the predictive accuracy of the models when subjected to external validation. PCA-ANN showed better prediction ability in the determination of PPA and PNA in synthetic samples with added excipients and pharmaceutical formulations. Since both components are characterized by low absorptivity, the better performance of PCA-ANN was ascribed to the ability in considering all non-linear information from noise or interfering excipients. 相似文献
996.
Siebler D Linseis M Gasi T Carrella LM Winter RF Förster C Heinze K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(16):4540-4551
Trinuclear ferrocene tris-amides were synthesized from an Fmoc- or Boc-protected ferrocene amino acid, and hydrogen-bonded zigzag conformations were determined by NMR spectroscopy, molecular modelling, and X-ray diffraction. In these ordered secondary structures orientation of the individual amide dipole moments approximately in the same direction results in a macrodipole moment similar to that of α-helices composed of α-amino acids. Unlike ordinary α-amino acids, the building blocks in these ferrocene amides with defined secondary structure can be sequentially oxidized to mono-, di-, and trications. Singly and doubly charged mixed-valent cations were probed experimentally by Vis/NIR, paramagnetic 1H NMR and M?ssbauer spectroscopy and investigated theoretically by DFT calculations. According to the appearance of intervalence charge transfer (IVCT) bands in solution, the ferrocene/ferrocenium amides are described as Robin-Day class II mixed-valent systems. M?ssbauer spectroscopy indicates trapped valences in the solid state. The secondary structure of trinuclear ferrocene tris-amides remains intact (coiled form) upon oxidation to mono- and dications according to DFT calculations, while oxidation to the trication should break the intramolecular hydrogen bonding and unfold the ferrocene peptide (uncoiled form). 相似文献
997.
Zanarini S Felici M Valenti G Marcaccio M Prodi L Bonacchi S Contreras-Carballada P Williams RM Feiters MC Nolte RJ De Cola L Paolucci F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(16):4640-4647
Cationic cyclometalated iridium complexes containing two anionic phenylpyridine (ppy) ligands and the neutral bidentate triazole-pyridine ligand, 2-(1-substituted-1H-1,2,3-triazol-4-yl)pyridine (pytl), were investigated. The complexes display a rich and reversible electrochemical behavior, upon investigations by cyclic voltammetry in strictly aprotic conditions, that couples with excellent emission quantum yields and long lifetimes of the excited states. Therefore, in organic media, all complexes have generated intense green electrochemiluminescence (ECL) through the so-called annihilation procedure and, importantly, a modulation of the emission energy (to blue) has been easily obtained by simple fluorination of the ppy ligand. Finally, taking advantage of their remarkable solubility in water, intense ECL was also obtained from aqueous buffer solutions using the co-reactant method, thus making all the investigated complexes highly promising for their effective use as ECL labels in bioanalytical applications. 相似文献
998.
Solutions of negatively charged graphene sheets and ribbons 总被引:1,自引:0,他引:1
Vallés C Drummond C Saadaoui H Furtado CA He M Roubeau O Ortolani L Monthioux M Pénicaud A 《Journal of the American Chemical Society》2008,130(47):15802-15804
Negatively charged graphene layers from a graphite intercalation compound spontaneously dissolve in N-methylpyrrolidone, without the need for any sonication, yielding stable, air-sensitive, solutions of laterally extended atom-thick graphene sheets and ribbons with dimensions over tens of micrometers. These can be deposited on a variety of substrates. Height measurements showing single-atom thickness were performed by STM, AFM, multiple beam interferometry, and optical imaging on Sarfus wafers, demonstrating deposits of graphene flakes and ribbons. AFM height measurements on mica give the actual height of graphene (ca. 0.4 nm). 相似文献
999.
Zinellu A Sotgia S Galistu F Lumbau F Pasciu V Mario Pes G Tadolini B Deiana L Carru C 《Talanta》2004,64(2):428-434
The aim of this work is the application of Stocks and Miller capillary electrophoresis (CE) method in order to evaluate the human LDL susceptibility to Cu2+-induced oxidation. Lipid peroxidation determines a change in the relative electrophoretic mobility (REM) of lipoprotein that can be monitored by capillary electrophoresis using uncoated fused silica capillaries and tricine-methylglucamine as electrophoretic buffer.We have evaluated the differences in the susceptibility to oxidation of LDL subjected to different preparations (dialysis or gel filtration, after ultracentrifugation, to remove EDTA), and different storage (4 °C for 1 week or lyophilization) by measuring REM and lipid hydroperoxides (ROOH) with a spectrophotometer assay. Our results indicate that gel filtration is a more convenient procedure than dialysis for the isolation of LDL and that lyophilised samples are less prone to oxidation than those stored at 4 °C. Moreover, REM appears to be a more sensitive and easier method than spectrophotometer assay both to monitor the oxidative modification of LDL and to evaluate oxidative state of native LDL. 相似文献
1000.
Philipp Vana Luca Albertin Leonie Barner Thomas P. Davis Christopher Barner‐Kowollik 《Journal of polymer science. Part A, Polymer chemistry》2002,40(22):4032-4037
Electrospray ionization mass spectrometry was performed to identify the structure of polymeric methyl acrylates generated via the cumyl dithiobenzoate (CDB), cumyl p‐fluorodithiobenzoate (CPFDB), and 1‐phenylethyl dithiobenzoate (PEDB) mediated reversible addition–fragmentation chain‐transfer (RAFT) polymerizations. The relatively simple spectra clearly demonstrate the end groups of this living free‐radical polymerization technique. Only polymeric chains carrying one leaving group of the RAFT agent and the dithiobenzoate end group as the active RAFT center were discovered. Multiple‐stage mass spectrometric experiments and oxidation of the dithioester end group confirmed the structure of the generated polymers. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4032–4037, 2002 相似文献