Two-Photon Absorption Enhancement by the Inclusion of a Tropone Ring in Distorted Nanographene Ribbons

A new family of distorted ribbon-shaped nanographenes was designed, synthesized, and their optical and electrochemical properties were evaluated, pointing out an unprecedented correlation between their structural characteristics and the two-photon absorption (TPA) responses and electrochemical band gaps. Three nanographene ribbons have been prepared: a seven-membered-ring-containing nanographene presenting a tropone moiety at the edge, its full-carbon analogue, and a purely hexagonal one. We have found that the TPA cross-sections and the electrochemical band gaps of the seven-membered-ring-containing compounds are higher and lower, respectively, than those of the fully hexagonal polycyclic aromatic hydrocarbon (PAH). Interestingly, the inclusion of additional curvature has a positive effect in terms of non-linear optical properties of those ribbons.     

Sugawara and Vertex Operator Constructions for Deformed Virasoro Algebras

From the defining exchange relations of the elliptic quantum algebra, we construct subalgebras which can be characterized as q-deformed W_N algebras. The consistency conditions relating the parameters p, q, N and the central charge c are shown to be related to the singularity structure of the functional coefficients defining the exchange relations of specific vertex operators representations of available when N = 2. Communicated by Petr Kulish Submitted: January 13, 2006; Accepted: March 6, 2006 Dedicated to our friend Daniel Arnaudon     

Contingent derivatives of set-valued maps and applications to vector optimization

In this paper we investigate contingent derivatives of set-valued maps and their lower and upper semidifferentiability properties. We provide also some calculus rules for these derivatives in infinite dimensional spaces. The concept of contingent derivatives is then applied to produce several necessary and sufficient conditions for vector optimization problems with set-valued objectives.This paper was written when the author was at the University of Erlangen-Nurnberg under a grant of the Alexander von Humboldt Foundation.On leave from the Institute of Mathematics, Hanoi, Vietnam.     

Superintegrability in Two Dimensions and the Racah–Wilson Algebra

The analysis of the most general second-order superintegrable system in two dimensions: the generic 3-parameter model on the 2-sphere is cast in the framework of the Racah problem for the \({\mathfrak{su}(1,1)}\) algebra. The Hamiltonian of the 3-parameter system and the generators of its quadratic symmetry algebra are seen to correspond to the total and intermediate Casimir operators of the combination of three \({\mathfrak{su}(1,1)}\) algebras, respectively. The construction makes explicit the isomorphism between the Racah–Wilson algebra, which is the fundamental algebraic structure behind the Racah problem for \({\mathfrak{su}(1, 1)}\) , and the invariance algebra of the generic 3-parameter system. It also provides an explanation for the occurrence of the Racah polynomials as overlap coefficients in this context. The irreducible representations of the Racah–Wilson algebra are reviewed as well as their connection with the Askey scheme of classical orthogonal polynomials.     

Controllability cost of conservative systems: resolvent condition and transmutation

This article concerns the exact controllability of unitary groups on Hilbert spaces with unbounded control operator. It provides a necessary and sufficient condition not involving time which blends a resolvent estimate and an observability inequality. By the transmutation of controls in some time L for the corresponding second-order conservative system, it is proved that the cost of controls in time T for the unitary group grows at most like exp(αL²/T) as T tends to 0. In the application to the cost of fast controls for the Schrödinger equation, L is the length of the longest ray of geometric optics which does not intersect the control region. This article also provides observability resolvent estimates implying fast smoothing effect controllability at low cost, and underscores that the controllability cost of a system is not changed by taking its tensor product with a conservative system.     

On well-posedness for some dispersive perturbations of Burgers' equation

We show that the Cauchy problem for a class of dispersive perturbations of Burgers' equations containing the low dispersion Benjamin–Ono equation

${?}_{t}u?D_x^{\alpha }{?}_{x}u={?}_x(u^2),0<\alpha \le 1,$

is locally well-posed in $H^s(\mathbb{R})$ when $s>s_{\alpha }:=\frac{3}{2}?\frac{5\alpha }{4}$. As a consequence, we obtain global well-posedness in the energy space $H^{\frac{\alpha }{2}}(\mathbb{R})$ as soon as $\frac{\alpha }{2}>s_{\alpha }$, i.e. $\alpha >\frac{6}{7}$.     

On the height of random m-ary search trees

A random m-ary seach tree is constructed from a random permutation of 1,…, n. A law of large numbers is obtained for the height H_n of these trees by applying the theory of branching random walks. in particular, it is shown that H_n/log n→γ in probability as n→∞ where γ = γ(m) is a constant depending upon m only. Interestingly, as m→∞, γ(m) is asymptotic to 1/log m, the coefficient of log n in the asymptotic expression for the height of the complete m-ary search tree. This proves that for large m, random m-ary search trees behave virtually like complete m-ary trees.     

A Generalized Mass Involving Higher Order Symmetric Functions of the Curvature Tensor

We define a generalized mass for asymptotically flat manifolds using some higher order symmetric function of the curvature tensor. This mass is non-negative when the manifold is locally conformally flat and the σ _k curvature vanishes at infinity. In addition, with the above assumptions, if the mass is zero, then, near infinity, the manifold is isometric to a Euclidean end.     

Higher Sugawara Operators for the Quantum Affine Algebras of Type A

We give explicit formulas for the elements of the center of the completed quantum affine algebra in type A at the critical level that are associated with the fundamental representations. We calculate the images of these elements under a Harish-Chandra-type homomorphism. These images coincide with those in the free field realization of the quantum affine algebra and reproduce generators of the q-deformed classical \({{\mathcal W}}\)-algebra of Frenkel and Reshetikhin.