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121.
David E. Salazar Marcano Mhamad Aly Moussawi Alexander V. Anyushin Sarah Lentink Luc Van Meervelt Ivana Ivanovi-Burmazovi Tatjana N. Parac-Vogt 《Chemical science》2022,13(10):2891
Hybrid structures incorporating different organic and inorganic constituents are emerging as a very promising class of materials since they synergistically combine the complementary and diverse properties of the individual components. Hybrid materials based on polyoxometalate clusters (POMs) are particularly interesting due to their versatile catalytic, redox, electronic, and magnetic properties, yet the controlled incorporation of different clusters into a hybrid structure is challenging and has been scarcely reported. Herein we propose a novel and general strategy for combining multiple types of metal-oxo clusters in a single hybrid molecule. Two novel hybrid POM structures (HPOMs) bis-functionalised with dipentaerythritol (R–POM1–R; R = (OCH2)3CCH2OCH2C(CH2OH)) were synthesised as building-blocks for the formation of heterometallic hybrid triads (POM2–R–POM1–R–POM2). Such a modular approach resulted in the formation of four novel heterometallic hybrids combing the Lindqvist {V6}, Anderson–Evans {XMo6} (X = Cr or Al) and trisubstituted Wells–Dawson {P2V3W15} POM structures. Their formation was confirmed by multinuclear Nuclear Magnetic Resonance (NMR), infrared (IR) and UV-Vis spectroscopy, as well as Mass Spectrometry, Diffusion Ordered Spectroscopy (DOSY) and elemental analysis. The thermal stability of the hybrids was also examined by Thermogravimetric Analysis (TGA), which showed that the HPOM triads exhibit higher thermal stability than comparable hybrid structures containing only one type of POM. The one-pot synthesis of these novel compounds was achieved in high yields in aqueous and organic media under simple reflux conditions, without the need of any additives, and could be translated to create other hybrid materials based on a variety of metal-oxo cluster building-blocks.A versatile modular approach has been developed for incorporating different metal-oxo nanoclusters with characteristic structures into a single hybrid molecule by covalently linking them with polyol ligands. 相似文献
122.
Jocelyn D Laughton Philippe Bittar Yves Charnay Luc Pellerin Enikö Kovari Pierre J Magistretti Constantin Bouras 《BMC neuroscience》2007,8(1):35
Background
For a long time now, glucose has been thought to be the main, if not the sole substrate for brain energy metabolism. Recent data nevertheless suggest that other molecules, such as monocarboxylates (lactate and pyruvate mainly) could be suitable substrates. Although monocarboxylates poorly cross the blood brain barrier (BBB), such substrates could replace glucose if produced locally. 相似文献123.
Two main existence conditions for solutions of variational relation problems are established without convexity. The first one is based on a finite solvability property and the second one on generalized KKM mappings. These conditions unify and strengthen several existing results in the literature on the topic. A model of satisficing process by rejection is considered which gives an economic interpretation of the introduced concepts. 相似文献
124.
We prove that a real function is operator monotone (operator convex) if the corresponding monotonicity (convexity) inequalities
are valid for some normal state on the algebra of all bounded operators in an infinite-dimensional Hilbert space. We describe
the class of convex operator functions with respect to a given von Neumann algebra in dependence of types of direct summands
in this algebra. We prove that if a function from ℝ+ into ℝ+ is monotone with respect to a von Neumann algebra, then it is also operator monotone in the sense of the natural order on
the set of positive self-adjoint operators affiliated with this algebra. 相似文献
125.
126.
Wenqi Zeng Tammy Gillis Michael Hakky Luc Djoussé Richard H Myers Marcy E MacDonald James F Gusella 《BMC neuroscience》2006,7(1):62-9
Background
In Huntington's disease (HD), age at neurological onset is inversely correlated with the length of the CAG trinucleotide repeat mutation, but can be modified by genetic factors beyond the HD gene. Association of a relatively infrequent 16 TAA allele of a trinucleotide repeat polymorphism in the GRIK2 3'UTR with earlier than expected age at neurological onset has been suggested to reflect linkage disequilibrium with a functional polymorphism in GRIK2 or an adjacent gene. 相似文献127.
The DELPHI experiment at the LEP e + e- collider collected almost 700 pb-1 at centre-of-mass energies above the Z0 mass pole and up to 208 GeV. Those data were used to search for SUSY in the Anomaly Mediated SUSY Breaking (AMSB) scenario with a flavour independent common sfermion mass parameter. The searches covered several possible signatures experimentally accessible at LEP, with either the neutralino, the sneutrino or the stau being the Lightest Supersymmetric Particle (LSP). They included: the search for nearly mass-degenerate chargino and neutralino, which is a typical feature of AMSB; the search for Standard-Model-like or invisibly decaying Higgs boson; the search for stable staus; the search for cascade decays of SUSY particles resulting in the LSP and a low multiplicity final state containing neutrinos. No evidence of a signal was found, and thus constraints were set in the space of the parameters of the model.Received: 3 September 2003, Revised: 3 February 2004, Published online: 9 March 2004 相似文献
128.
Dr. David Tejedor Samuel Delgado-Hernández Lucía Colella Dr. Fernando García-Tellado 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(66):15046-15049
A universal, practical and scalable organocatalytic hydrocyanation manifold to provide β-substituted acrylonitriles bearing an electron-withdrawing functionality has been implemented. The catalytic manifold operates under the reactivity generation principle “a good nucleophile generates a strong base”, and it uses 1,4-diazabicyclo[2.2.2]octane (DABCO) as the catalyst, activated terminal alkynes as substrates and acetone cyanohydrin as the cyanide source. The acrylonitriles obtained as E,Z mixtures are straightforwardly resolved by simple flash chromatography delivering the pure isomers in preparative amounts. 相似文献
129.
Dr. Silvia Castro-Fernández Carlos M. Cruz Dr. Inês F. A. Mariz Dr. Irene R. Márquez Vicente G. Jiménez Lucía Palomino-Ruiz Prof. Juan M. Cuerva Dr. Ermelinda Maçôas Dr. Araceli G. Campaña 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(18):7205-7211
A new family of distorted ribbon-shaped nanographenes was designed, synthesized, and their optical and electrochemical properties were evaluated, pointing out an unprecedented correlation between their structural characteristics and the two-photon absorption (TPA) responses and electrochemical band gaps. Three nanographene ribbons have been prepared: a seven-membered-ring-containing nanographene presenting a tropone moiety at the edge, its full-carbon analogue, and a purely hexagonal one. We have found that the TPA cross-sections and the electrochemical band gaps of the seven-membered-ring-containing compounds are higher and lower, respectively, than those of the fully hexagonal polycyclic aromatic hydrocarbon (PAH). Interestingly, the inclusion of additional curvature has a positive effect in terms of non-linear optical properties of those ribbons. 相似文献
130.