利用F－P标准具组实时测量被动入射激光波长

从理论上分析利用Ｆ－Ｐ标准具组实时测量被动入射激光波长的能量分布及信噪比，提供了计算公式及误差分析，给出了实验光路图、处理软件框图和一组实验照片；最后对给出的实验结果数据进行了讨论。     

高精度光学中心偏测量仪主要技术指标的检测

简要阐述高精度光学中心偏测量仪主要技术指标，即仪器基准轴运动误差、测微目镜值误差、测量系统倍率误差和偏心测量误差的检测原理，最后人出计算实例。     

聚合物的交流示波极谱滴定分析——碱解法测定聚苯乙烯-顺丁烯二酸共聚物的磺化度

本文提出苯乙烯-顺丁烯二酸共聚物的磺酸盐(SSMA)中磺酸基的测定方法。将SSMA与KOH在340℃共熔进行磺基碱解,所分解的SO_3~(2-)氧化为SO_4~(2-)后用过量Ba~(2+)予以沉淀,剩余Ba~(2+)用K_2CrO_4,进行交流示波极谱滴定,以间接求得磺酸基含量。     

Morphology and thermal properties of conductive polyaniline/polyamide composite films

Polyaniline (PANI) in an emeraldine‐base form, synthesized by chemical oxidation polymerization, was doped with camphor sulfonic acid (CSA). The conducting complex (PANI–CSA) and a matrix, polyamide‐66, polyamide‐11, or polyamide‐1010, were dissolved in a mixed solvent, and the blend solution was dropped onto glass and dried for the preparation of PANI/polyamide composite films. The conductivity of the films ranged from 10^?7 to 10⁰ S/cm when the weight fraction of PANI–CSA in the matrices changed from 0.01 to 0.09, and the percolation threshold was about 2 wt %. The morphology of the composite films before and after etching was studied with scanning electron microscopy, and the thermal properties of the composite films were monitored with differential scanning calorimetry. The results indicated that the morphology of the blend systems was in a globular form. The addition of PANI–CSA to the films resulted in a decrease in the melting temperature of the composite films and also affected the crystallinity of the blend systems. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2531–2538, 2002     

低码率语音编码中过渡帧对合成语音的影响*

过渡段对语音清晰度、可懂度和人耳听觉感知都起到不可忽视的作用。参数语音编码中,包含有过渡段的语音帧能否得到恰当处理,是决定其合成语音是否清晰可懂的关键。本文以混合激励线性预测编码为参考,将其中的语音帧划分为静音、清音、浊音、过渡四大类后分别处理,在以往低码率语音编码(1 kbps)工作基础上,比较了八种过渡帧划分方法对合成语音PESQ MOS的影响。经分析后发现:不同的过渡帧对PESQ MOS的贡献也不同。由清、静音向浊音变化的过渡帧的贡献最大;介于浊辅音与元音之间的过渡帧的贡献也不应被忽略。     

Thioethers as Dichotomous Electrophiles for Site-Selective Silylation via C−S Bond Cleavage

The development of aryl alkyl sulfides as dichotomous electrophiles for site-selective silylation via C−S bond cleavage has been achieved. Iron-catalyzed selective cleavage of C(aryl)−S bonds can occur in the presence of β-diketimine ligands, and the cleavage of C(alkyl)−S bonds can be achieved by t-BuONa without the use of transition metals, resulting in the corresponding silylated products in moderate to excellent yields. Mechanistic studies suggest that Fe−Si species may undergo metathesis reactions during the cleavage of C(aryl)−S bonds, while silyl radicals are involved during the cleavage of C(alkyl)−S bonds.     

Distributional expansion of maximum from logarithmic general error distribution

Logarithmic general error distribution is an extension of lognormal distribution. In this paper, with optimal norming constants the higher-order expansion of distribution of partial maximum of logarithmic general error distribution is derived.     

Synthesis of aromatic liquid crystals with asymmetric diester based on rod-like multi-ring system by two-step esterification method

A novel method of two-step esterifications was developed to synthesize compounds with asymmetric double ester groups. By using this method, six rod-like double ester compounds were prepared with p-hydroxy benzaldehyde, p-hydroxy benzoic acid bicyclohexyl carboxylic acid, cyclohexyl benzoic acid and biphenyl carboxylic acid substituted by n-propyl and n-pentyl as main reactants. The structures and properties of target compounds were confirmed by IR, MS, ¹H NMR, elemental analysis, differential scanning calorimetry (DSC) and hot stage polarizing optical microscope (HS-POM). Typical yields of the target molecules were more than 70%. All the molecules have mesophases with the textures of nematic type, indicating a rod-like molecule with a longer rigid skeleton can keep its mesophases. There was no clearing point observed for any of the derivatives before they decomposed so that the temperature ranges of the mesophases could not be determined. The energy differences between frontier molecular orbitals (HOMO-LUMO) (E_g) of the compounds were calculated by cyclic voltammetry (CV). The terminal ring system has an obvious influence on the energy levels and the energy gaps (E_g).     

Syntheses, structures, magnetism, and optical properties of lutetium-based interlanthanide selenides

Ln3LuSe6 (Ln = La, Ce), beta-LnLuSe3 (Ln = Pr, Nd), and LnxLu4-xSe6 (Ln = Sm, Gd; x = 1.82, 1.87) have been synthesized using a Sb2Se3 flux at 1000 degrees C. Ln3LuSe6 (Ln = La, Ce) adopts the U3ScS6-type three-dimensional structure, which is constructed from two-dimensional 2(infinity)[Ln3Se6](3-) slabs with the gaps between these slabs being filled by octahedrally coordinated Lu(3+) ions. The series of beta-LnLuSe3 (Ln = Pr, Nd) are isotypic with UFeS3. Their structures include layers formed from LuSe6 octahedra that are separated by eight-coordinate Ln(3+) (Ln = Pr, Nd) ions in bicapped trigonal prismatic environments. Sm1.82Lu2.18Se6 and Gd1.87Lu2.13Se6 crystallize in the disordered F-Ln2S3 type structure with the eight-coordinate bicapped trigonal prismatic Ln(1) ions residing in the one-dimensional channels formed by three different double chains via edge- and corner-sharing. These double chains are constructed from Ln(2)Se7 monocapped trigonal prisms, Ln(3)Se6 octahedra, and Ln(4)S6 octahedra, respectively. The magnetic susceptibilities of beta-PrLuSe3 and beta-NdLuSe3 follow the Curie-Weiss law. Sm1.82Lu2.18Se6 shows van Vleck paramagnetism. Magnetic susceptibility measurements show that Gd1.87Lu2.13Se6 undergoes an antiferromagnetic transition around 4 K. Ce3LuSe6 exhibits soft ferromagnetism below 5 K. The optical band gaps for La3LuSe6, Ce3LuSe6, beta-PrLuSe3, beta-NdLuSe3, Sm1.82Lu2.18Se6, and Gd1.87Lu2.13Se6 are 1.26, 1.10, 1.56, 1.61, 1.51, and 1.56 eV, respectively.