Characterization of the cholesteric phase of filamentous bacteriophage fd for molecular alignment

Residual dipolar couplings arise from small degrees of alignment of molecules in a magnetic field and have proven to provide valuable structural information. Colloidal suspensions of rod-shaped viruses and bacteriophages constitute a frequently employed medium for imparting such alignment onto biomolecules. The stability and behavior of the liquid crystalline phases with respect to solution conditions such as pH, ionic strength, and temperature vary, and characterization should benefit practical applications as well as theoretical understanding. In this Communication we describe the pH dependence of the cholesteric liquid crystalline phase of the filamentous bacteriophage fd and demonstrate that the alignment tensor of the solute protein is modulated by pH. We also report the interesting observation that the relative sign of the residual dipolar coupling changes at low pH values. In addition, we demonstrate that the degree of alignment inversely scales with the lengths of the phage particles for phages with identical mass and charge per unit length.     

Experimental investigation of high-quality synchronization of coupled oscillators

We describe two experiments in which we investigate the synchronization of coupled periodic oscillators. Each experimental system consists of two identical coupled electronic periodic oscillators that display bursts of desynchronization events similar to those observed previously in coupled chaotic systems. We measure the degree of synchronization as a function of coupling strength. In the first experiment, high-quality synchronization is achieved for all coupling strengths above a critical value. In the second experiment, no high-quality synchronization is observed. We compare our results to the predictions of the several proposed criteria for synchronization. We find that none of the criteria accurately predict the range of coupling strengths over which high-quality synchronization is observed. (c) 2000 American Institute of Physics.     

Electrospinning of complex oxide nanofibers

Electrospinning is a versatile process for drawing fibers of diverse materials including polymers, ceramics, and composites. We demonstrate here its application in the synthesis of complex ceramic oxide materials. The phase formation and morphology of BaTiO₃ nanofibers synthesized via electrospinning is investigated as a function of heat treatment conditions. Fully crystallized BaTiO₃ nanofibers with the perovskite structure are obtained after annealing at 750 °C and show an average grain size of about 30 nm. Tetragonal crystal structure of the fibers is indicated by XRD peak splitting (calculated c/a ratio=1.007), and confirmed by Raman spectroscopy. Furthermore, the advancement in heat treatment of the electrospun fibers yields single crystalline BaTiO₃ nanofibers with 50 nm in diameter and lengths up to 1 μm.     

Periodic homogenization of nonlinear non-monotone parabolic operators with three time scales

Multiscale homogenization of nonlinear non-monotone degenerated parabolic operators is investigated. Under a periodicity assumption on the coefficients of the operators under consideration, we obtain by means of multiscale convergence method, an accurate homogenization result. It is also shown that in spite of the presence of several time scales the global homogenized problem is not a reiterated one.     

A hybrid optimization technique coupling an evolutionary and a local search algorithm

Evolutionary algorithms are robust and powerful global optimization techniques for solving large-scale problems that have many local optima. However, they require high CPU times, and they are very poor in terms of convergence performance. On the other hand, local search algorithms can converge in a few iterations but lack a global perspective. The combination of global and local search procedures should offer the advantages of both optimization methods while offsetting their disadvantages. This paper proposes a new hybrid optimization technique that merges a genetic algorithm with a local search strategy based on the interior point method. The efficiency of this hybrid approach is demonstrated by solving a constrained multi-objective mathematical test-case.     

Radiative decay ofJ/ψ into γ π+ π−

The radiative decayJ/ψ → γ π⁺ π^? has been studied using the 8.6 millionJ/ψ produced in the DM2 experiment at the DCIe ⁺e^? storage rings at Orsay. The π⁺ π^? mass spectrum shows a cleanf ₂ (1270) signal, and the possible presence of two other states at thef ₂ (1720) andf ₄ (2030) masses. For thef ₂ (1270), the branching ratio BR(J/ψ →γf)xBR(f→π⁺ π^?) is measured to be (7.50±0.30±1.12)×10^?4, and the spin analysis prefers theJ=2 assignment, with helicity parametersx=0.83±0.06 andy=0.01±0.06. The existence of higher mass states is discussed.     

Enumeration in Convex Geometries and Associated Polytopal Subdivisions of Spheres

We construct CW spheres from the lattices that arise as the closed sets of a convex closure, the meet-distributive lattices. These spheres are nearly polytopal, in the sense that their barycentric subdivisions are simplicial polytopes. The complete information on the numbers of faces and chains of faces in these spheres can be obtained from the defining lattices in a manner analogous to the relation between arrangements of hyperplanes and their underlying geometric intersection lattices.