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841.
We describe a kernel energy method (KEM) for applying quantum crystallography to large molecules, with an emphasis on the calculation of the molecular energy of peptides. The computational difficulty of representing the system increases only modestly with the number of atoms. The calculations are carried out on modern parallel supercomputers. By adopting the approximation that a full biological molecule can be represented by smaller “kernels” of atoms, the calculations are greatly simplified. Moreover, collections of kernels are, from a computational point of view, well suited for parallel computation. The result is a modest increase in computational time as the number of atoms increases, while retaining the ab initio character of the calculations. We describe a test of our method, and establish its accuracy using 15 different peptides of biological interest. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2005 相似文献
842.
Rodriguez Roldan A. M. Auffrédic J. -P. Louër D. 《Journal of Thermal Analysis and Calorimetry》1983,28(1):131-146
The solid solid equilibria in the binary system Ca3(PO4)2-CaNaPO4 have been studied. Different diagrams have been proposed for this system. The differences relate to the limits of the field of existence of a non-stoichiometric phase (phase A) stable at high temperature and undergoing eutectoid decomposition during cooling; they can be explained by the existence of two metastable equilibria diagrams which are superposed in the stable diagram. These metastabilities depend on both the cooling rates and the maximum temperatures reached before this cooling.
Zusammenfassung Fest fest Gleichgewichte des binären Systems Ca3(PO4)2-CaNaPO4 wurden untersucht. Verschiedene Diagramme wurden für dieses System vorgeschlagen. Diese Unterschiede beziehen sich auf die Grenzen des Existenzbereiches einer nichtstöchiometrischen, hochtemperaturstabilen Phase (Phase A), die sich beim Abkühlen nach einer eutektoiden Reaktion zersetzt; sie können durch die Existenz von zwei dem stabilen Diagramm überlagerten metastabilen Gleichgewichtsdiagrammen erklärt werden. Diese metastabilen Zustände hängen sowohl von der Abkühlungsgeschwindigkeit als auch von den vor dem Abkühlen erreichten maximalen Temperaturen ab.
Ca3(PO4)2-CaNaPO4 — . . / A/, , - , , . , , .相似文献
843.
The reaction scheme of thermal decomposition for four zinc hydroxynitrates was investigated by means of differential scanning calorimetry, thermogravimetry, mass spectrometry, and radiocrystallography. The thermal transformation of Zn(OH)(NO3) · H2O and of Zn3(OH)4(NO3)2 involves the formation of gaseous water and nitric acid from an actual chemical reaction. This reaction is not observed for Zn5(OH)8(NO3)2 · 2H2O and Zn5(OH)8(NO3)2. These results show that the formation of gaseous nitric acid molecules inside the solids is specific to hydroxynitrates of divalent metals M, whose lamellar crystalline structure is characterized by a stacking of hexagonal close-packed layers of formula MX2+m, where m = 0 or 1 and X = OH?, H2O, or NO?3. 相似文献
844.
Zhao‐Xun Lian Ping Liu Jia‐Min Zhang Tian‐Xi Wang Tian‐Jun Lou 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(11):m525-m527
In the title compound, [V4O8(SeO3)2(C10H8N2)4], there are two distinct vanadium coordination environments. Alternating corner‐shared VO4N2 octahedra and SeO3 pyramids result in eight‐membered centrosymmetric V2Se2O4 rings. In addition, pairs of V centres form centrosymmetric V2O6N4 clusters via edge‐sharing. These two kinds of secondary building units are linked in an ABABAB fashion to give an infinite chain whose nature is unprecedented in Se–V–O systems. 相似文献
845.
The possibility of using supercritical-fluid chromatographic retention data for examining the effects of operational parameters, such as pressure and flow rate, on the extraction characteristics in supercritical-fluid extraction (SFE) was investigated. A model was derived for calculating the extraction efficiency in SFE from retention data and peak shapes measured in supercritical-fluid chromatography (SFC). By performing the SFC experiments at the same pressure and temperature as the SFE extractions using the SFE extraction cell as the SFC column, an accurate prediction of extraction efficiencies could be made. Finally, the effects of matrix composition and analyte concentration on extraction efficiency were studied. 相似文献
846.
Haas P Hempstead M Jensen T Johnson DR Kagan H Kass R Baringer P McIlwain RL Miller DH Ng CR Shibata EI Behrends S Guida JM Guida JA Morrow F Poling R Thorndike EH Tipton P Alam MS Katayama N Kim IJ Li WC Lou XC Sun CR Tanikella V Bortoletto D Goldberg M Holmes R Horwitz N Jawahery A Lubrano P Moneti GC Sharma V Shipsey IP Thoma P Csorna SE Letson T Mestayer MD Panvini RS Word GB Bean A Bobbink GJ Brock IC Ferguson T Kraemer RW Vogel H Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R 《Physical review letters》1988,60(16):1614-1617
847.
Global well-posedness of the non-isentropic full compressible magnetohydrodynamic equations 下载免费PDF全文
In this paper, we are concerned with Cauchy problem for the multi-dimensional (N ≥ 3) non-isentropic full compressible magnetohydrodynamic equations. We prove the existence and uniqueness of a global strong solution to the system for the initial data close to a stable equilibrium state in critical Besov spaces. Our method is mainly based on the uniform estimates in Besov spaces for the proper linearized system with convective terms. 相似文献
848.
Inside Back Cover: Synthesis of Highly Uniform Molybdenum–Glycerate Spheres and Their Conversion into Hierarchical MoS2 Hollow Nanospheres for Lithium‐Ion Batteries (Angew. Chem. Int. Ed. 26/2016) 下载免费PDF全文
Dr. Yawen Wang Dr. Le Yu Prof. Xiong Wen Lou 《Angewandte Chemie (International ed. in English)》2016,55(26):7549-7549
849.
850.