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81.
Dhiab Jabli Khaireddine Dridi Mohamed Lotfi Efrit 《Phosphorus, sulfur, and silicon and the related elements》2016,191(5):759-764
In this study, we describe a new and easy synthetic approach to variously substituted triazoles based on the reaction of imidates with phosphorylated hydrazine in good yields. A general mechanism of the reactions was also proposed. Characterization of the products was carried out by several analytical and spectroscopic tools including infrared and nuclear magnetic resonance spectroscopies (1H, 13C NMR, 31P NMR). 相似文献
82.
Zahra?Lotfi Hassan?Zavvar?MousaviEmail author S.?Maryam Sajjadi 《Mikrochimica acta》2017,184(5):1427-1436
Carbon nanotubes were modified with magnetite nanoparticles, and 1,4-diazabicyclo[2.2.2]octane (DABCO) was then covalently attached to their surface. The resulting material is shown to be a viable sorbent for the preconcentration of the selective serotonin reuptake inhibitors citalopram, sertraline, fluvoxamine and fluoxetine via ultrasound-assisted magnetic solid phase extraction. The effects of pH value, sorbent dosage, eluent volume and salt concentration were optimized by central composite design and desirability function. The drugs were quantified by HPLC with UV detection. Detection limits are as low as 0.2, 0.25, 0.3, and 0.5 ng mL?1 for citalopram, sertraline, fluvoxamine and fluoxetine, respectively. The intra-day precisions (RSDs) are <4.0%. The method was applied to the determination of the selective serotonin reuptake inhibitors in plasma samples and gave recoveries of >91%. The sorbent can be reused 12 times without a noticeable decrease in extraction efficiency. 相似文献
83.
Lotfi Shiri Mosstafa Kazemi 《Phosphorus, sulfur, and silicon and the related elements》2017,192(11):1171-1176
We report a new strategy to immobilize a bromine source on the surface of magnetic Fe3O4 nanoparticles (Fe3O4 MNPs-DETA/Benzyl-Br3) leading to a magnetically recoverable catalyst, which exhibits high catalytic efficiency in oxidative coupling of thiols to the disulfides (89–98%). The Fe3O4 MNPs-DETA/Benzyl-Br3 catalyst was fabricated by anchoring 3-chloropropyltrimethoxysilane (CPTMS) on magnetic Fe3O4 nanoparticles, followed with N-benzylation and reaction with bromine in tetrachloridecarbon. The resulting nanocomposite was analyzed by a series of characterization techniques such as FT-IR, SEM, TGA, VSM and XRD. The catalyst could be recovered via magnetic attraction and could be recycled at least 5 times without appreciable decrease in activity. 相似文献
84.
We report the use of silver (Ag)-modified carbon and Ag ultramicroelectrodes (UMEs) for electrochemical detection of nitrate. We investigated several methods for electrodeposition of Ag; our results show that the addition of a complexation agent (ammonium sulfate) in the Ag deposition solution is necessary for electrodeposition of nanostructured Ag that adheres well to the electrode. The electrodeposited Ag on both types of electrodes has branch-like structures that are well-suited for electrocatalytic reduction of nitrate. The use of UMEs is advantageous; the sigmoidal-shaped cyclic voltammogram allows for sensitive detection of nitrate by reducing the capacitive current, as well as enabling easy quantification of the nitrate reduction current. Both cyclic voltammetry and chronoamperometry were used to characterize the electrodes; and independent of the electrochemical interrogation technique, both UMEs were found to have a wide linear dynamic range (4–1000 μM) and a low limit of detection (3.2–5.1 μM). More importantly, they are reusable up to ∼100 interrogation cycles and are selective enough to be used for direct detection of nitrate in a synthetic aquifer sample without any sample pretreatment and/or pH adjustment. 相似文献
85.
M M Lotfi M Rabbani S F Ghaderi 《The Journal of the Operational Research Society》2011,62(6):1128-1137
We propose a mixed integer non-linear goal programming model for replenishment planning and space allocation in a supermarket in which some constraints on budget, space, holding times of perishable items, and number of replenishments are considered and weighted deviations from two conflicting objectives, namely profitability and customer service level, are minimized. We apply a minimum–maximum approach to introduce demand where the maximum demand is a function of price change and allocated space. Each item is presented in the form of multiple brands, probably exposed to price changes, competing to obtain more space. In addition to inventory investment costs, replenishment costs, and inventory holding costs we also include costs related to non-productive use of space. The order quantity, the amount of allocated showroom and backroom spaces, and the cycle time of joint replenishments are key decision variables. We also propose an extended model in which price is a decision variable. Finally we solve the model using LINGO software and provide computational results. 相似文献
86.
Super-efficiency in DEA by effectiveness of each unit in society 总被引:1,自引:0,他引:1
A.A. Noura F. Hosseinzadeh Lotfi G.R. Jahanshahloo S. Fanati Rashidi 《Applied Mathematics Letters》2011,24(5):623-626
One of the most important topics in management science is determining the efficiency of Decision Making Units (DMUs). The Data Envelopment Analysis (DEA) technique is employed for this purpose. In many DEA models, the best performance of a DMU is indicated by an efficiency score of one. There is often more than one DMU with this efficiency score. To rank and compare efficient units, many methods have been introduced under the name of super-efficiency methods. Among these methods, one can mention Andersen and Petersen’s (1993) [1] super-efficiency model, and the slack-based measure introduced by Tone (2002) [4]. Each of the methods proposed for ranking efficient DMUs has its own advantages and shortcomings. In this paper, we present a super-efficiency method by which units that are more effective and useful in society have better ranks. In fact, in order to determine super-efficiency by this method, the effectiveness of each unit in society is considered rather than the cross-comparison of the units. To do so, we divide the inputs and outputs into two groups, desirable and undesirable, at the discretion of the manager, and assign weights to each input and output. Then we determine the rank of each DMU according to the weights and the desirability of inputs and outputs. 相似文献
87.
Lotfi ZekriAhmed Kaiss Jean-Pierre ClercBernard Porterie Nouredine Zekri 《Physics letters. A》2011,375(3):346-351
Percolation properties and d.c. conductivity were determined for an L2×h-random resistor network model of metal-insulator composite films. The effects of the thickness h on the percolation threshold and conductivity were studied numerically in the limit of an infinite size of the L2-plane parallel to the film. For thicknesses ranging from h/L=0.01 to h/L=0.24, a crossover between a finite-size regime and a saturation regime was observed at h/L≈0.1. In the finite-size regime (h/L?0.01), the percolation threshold scales as pc(h)−pc3∝h−1/x, the exponent x being compatible with that of the critical exponent of the 3D correlation length, ν3. The conductivity exponent t appeared to depend linearly on the ratio h/L with a slope νD compatible with 2+ν2, where ν2 is the 2D correlation length exponent. In the saturation regime, a scaling correction for the percolation threshold was found with an exponent 1+1/ν3. In this regime we also observed a logarithmic dependence of the conductivity exponent on h/L. 相似文献
88.
E. Lotfi K. Jamshidi-Ghaleh F. Moslemi H. Masalehdan 《Applied Physics A: Materials Science & Processing》2011,103(3):669-672
A 1D photonic crystal structure contains 16 layers, 8 common dielectric layers and 8 layers with nonlinear medium, with an
arrangement similar to the 5th generation, Thue–Morse multilayer is presented. The properties of photonics band gap, field
distribution and optical multistability are investigated. On the band gap, 5 resonant modes is observed. On the behavior of
output intensity versus input intensity around resonant frequencies, the multistability response observed. When the frequency
of incident field is close to the resonant frequency, the threshold intensity of multistability is decreased. 相似文献
89.
Artus M Tahar LB Herbst F Smiri L Villain F Yaacoub N Grenèche JM Ammar S Fiévet F 《J Phys Condens Matter》2011,23(50):506001
Highly crystalline CoFe(2)O(4) nanoparticles with different diameters ranging from 2.4 to 6.1 nm have been synthesized by forced hydrolysis in polyol. The size can be controlled through adjusting the nominal water/metal molar ratio. X-ray diffraction, transmission electron microscopy, x-ray absorption spectroscopy and (57)Fe M?ssbauer spectrometry were employed to investigate the structure and the microstructure of the particles produced. Magnetic measurements performed on these particles show that they are superparamagnetic with a size-dependent blocking temperature. At 5 K, high saturation magnetization (~85 emu g(-1)) approaching that of the bulk was found for the larger particles, whereas a very large coercivity (14.5 kOe) is observed for the 3.5 nm sized particles. 相似文献
90.
In this study,the performances of fixed and fluidized bed reactors in the production of single-walled carbon nanotubes(SWNTs)have been investigated.In both reactors,single-walled carbon nanotubes were grown by catalytic chemical vapor decomposition(CCVD)of methane over Co-Mo/MgO nanocatalyst under two different operating conditions.The synthesized samples were characterized by TEM,TGA and Raman spectroscopy.It is found that the performance of a fluidized bed in the synthesis of carbon nanotubes is much better than that of a fixed bed.The quality of carbon nanotubes obtained from the fluidized bed was significantly higher than that from the fixed bed and the former one with the ID/IG ratio of 0.11 while the latter one with the ID/IG ratio of 0.71.Also,the yield of SWNTs in the fluidized bed was 92 wt%,while it was 78 wt%in the fixed bed.These advantages of fluidized bed reactors for the synthesis of carbon nanotubes can be attributed to more available space for the growth of carbon nanotubes and more uniform temperature and concentration profiles. 相似文献