A note on the nonexistence of Barker sequences

A Barker sequence is a sequence with elements ±1 such that all out-of-phase aperiodic autocorrelation coefficients are 0, 1 or -1. It is known that if a Barker sequence of length s > 13 exists then s = 4N ² for some odd integer N 55, and it has long been conjectured that no such sequence exists. We review some previous attempts to improve the bound on N which, unfortunately, contain errors. We show that a recent theorem of Eliahou et al. [5] rules out all but six values of N less than 5000, the smallest of which is 689.     

Mitigation of signal suppression caused by the use of trifluoroacetic acid in liquid chromatography mobile phases during liquid chromatography/mass spectrometry analysis via post‐column addition of ammonium hydroxide

A method has been developed to reduce the mass spectrometric ion signal suppression associated with the use of TFA as an additive in LC mobile phases. Through post‐column infusion of diluted NH₄OH solution to LC eluents, the ammonium ion introduced causes the neutral analyte‐TFA ion pair to dissociate which consequently releases the protonated analyte as free ions into the gas phase (through regular electrospray ionization mechanisms). An ion signal improvement from 1.2 to 20 times for a variety of compounds had been achieved through the application of this method. The molar ratios of NH₄OH:TFA which result in a reduction of signal suppression were determined to be between 0.5:1 and 50:1. In addition, it was shown that this NH₄OH infusion method could reduce the level of doubly‐charged species and the product ions formed via in‐source collision. The use of diluted NH₄OH solution is favorable since it is compatible with mass spectrometry analysis, and it is applicable in both positive and negative‐ion generation mode. Copyright © 2012 John Wiley & Sons, Ltd.     

Preparation and characterization of microcapsules loaded with polyphenols-enriched Uncaria tomentosa extract using spray-dryer technique

Journal of Thermal Analysis and Calorimetry - This work prepared and characterized microcapsule of Uncaria tomentosa (UT) in order to standardize a spray-dryer Uncaria tomentosa extract. The UT...     

Beam-helicity asymmetry in photon and pion electroproduction in the Δ(1232)-resonance region at Q2 = 0.35(GeV/c)2

The beam-helicity asymmetry has been measured simultaneously for the reactions p→epγ and p→epπ ⁰ in the Δ(1232)-resonance region at Q ² = 0.35(GeV/c)². The experiment was performed at MAMI with a longitudinally polarized beam and an out-of-plane detection of the proton. The results are compared with calculations based on dispersion relations for virtual Compton scattering and with the MAID model for pion electroproduction. There is an overall good agreement between experiment and theoretical calculations. The remaining discrepancies may be ascribed to an imperfect parametrization of some γ ^(*) N→πN multipoles, mainly contributing to the non-resonant background. The beam-helicity asymmetry in both channels (γ and π ⁰) shows a good sensitivity to these multipoles and should allow future improvement in their parametrization.     

A Computerized Operations Scheduling Model for the Reduction of Commercial Bank Float

The reduction in bank float requires that cheque processing procedures be upgraded in order to reduce the elapsed time between the receipt of a cheque and its presentation for collection at the bank upon which it is drawn. Traditionally, attempts to reduce float have focussed on the procedures for receiving checks and processing steps in preparation for clearing. Although the transporting of cheques from receiving locations to the processing location would most likely be the most significant factor in the elapsed time between receipt and eventual presentation for clearance, the float implications has largely been ignored in the development of transportation schedules in commercial banks. In attempting to maximize cheques processed, the timing of branch pickups should be based upon branch volume available and proof and transit processing capacity as well as travel time considerations. A heuristic model described in this paper represents the first methodology providing the opportunity for simultaneously evaluating these variables to develop schedules which offer opportunities for improvements in bank funds flow.     

Quantum private queries

We propose a cheat sensitive quantum protocol to perform a private search on a classical database which is efficient in terms of communication complexity. It allows a user to retrieve an item from the database provider without revealing which item he or she retrieved: if the provider tries to obtain information on the query, the person querying the database can find it out. The protocol ensures also perfect data privacy of the database: the information that the user can retrieve in a single query is bounded and does not depend on the size of the database. With respect to the known (quantum and classical) strategies for private information retrieval, our protocol displays an exponential reduction in communication complexity and in running-time computational complexity.     

Strong laboratory double layers in the presence of a magnetic field

Using a triple plasma device, strong double layers (Δ 20 T_e/e) have been produced in an axial magnetic field of 50 G. Numerical results indicate that suppression of plasma generation in the region of a double layer is necessary for its existence.     

Effect of particulate filler on cell size in membranes formed via liquid–liquid thermally induced phase separation

This paper discusses the effects of adding particulate filler to a system undergoing liquid–liquid thermally induced phase separation (L–L TIPS). While much is known about the growth of droplets in L–L TIPS, little is known about the effect particular fillers have on droplet growth and the final cell size in the resulting microporous membranes. In this work, zeolite particles are shown to have a significant effect on the final cell size of these microporous membranes, the extent of which depends on the particle loading and processing conditions used to form the membrane. Two polymer–diluent–zeolite systems are reported: isotactic polypropylene–diphenyl ether and poly(methyl methacrylate)–cyclohexanol, both with zeolite 4A particles.