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81.
82.
Monika Kuemmel Cédric Boissière Lionel Nicole Christel Laberty-Robert Clément Sanchez David Grosso 《Journal of Sol-Gel Science and Technology》2008,48(1-2):102-112
TiO2, Al2O3, and ZrO2 patterns composed of ordered nano motifs of various morphologies (i.e. perforations (craters), rings, canyons, wires, dots, or channels) with typical lateral dimensions of less than 40 nm and thickness below 15 nm are presented. Simple chemical solution deposition (CSD) of molecular inorganic precursors and commercial block copolymers was used to create patterns on several substrate surfaces (bare, hydrophobized or gold covered silicon wafers and ITO). Self-assembly during evaporation and subsequent stabilization at 500 °C leads to the various nanostructures. Compared to other techniques for surface nano patterning, the present method has the advantage of being cheap, reproducible and easy to scale up and does not require specialized equipment. The type, dimension, and organization of these motifs were assessed by AFM, FE-SEM, spectroscopic ellipsometry, and GI-SAXS and are shown to depend on the conditions of preparation. Usage as model surfaces for modelling of wetting properties and as nanoelectrode arrays were investigated. 相似文献
83.
Comparison of the lattice mode region of the low-temperature Raman spectrum of MCH and MCH-d14 under various cooling rates shows that there are two crystalline modifications. The molecular mode region frequencies however, remain invariant to cooling rate suggesting a single molecular conformation for both crystalline phases. 相似文献
84.
Lionel R. Milgrom 《Polyhedron》1985,4(9):1661-1664
1H and 13C NMR spectra of the title compound are reported and peaks assigned by comparison with the free-base porphyrin. Long-range spin—spin coupling is observed between platinum and the macrocyclic protons and carbon atoms. Meso-protons are assigned from line-broadening observed for three of the peaks, possibly caused by residual coupling of these protons to the pyrrole β-protons. Allylic coupling of the pyrrole β-protons to adjacent methyl groups is also noted, and supports the tautomeric model of an 18-atom delocalisation pathway around the macrocycle. The 1H NMR spectrum of the title compound is more concentration-dependent than that of the free-base porphyrin and probably reflects additional macrocyclic interactions via the platinum atoms. 相似文献
85.
86.
Dr. Lionel Weiss 《Probability Theory and Related Fields》1968,10(3):193-197
Summary
X
1,...,X
n
are independent random variables, identically distributed over the unit interval, with common probability density function 1 + r(x)/n
for all sufficiently large n, where is a positive constant,
and |r(x)| <D. V
1, ..., V
n+1 are the sample spacings generated by X
1,..., X
n
. It is shown that in many cases, the asymptotic joint distribution of homogeneous functions of V
1,..., V
n+1 can be found directly from the asymptotic joint distribution of homogeneous functions of independent exponential random variables.Research supported by NSF Grant GP 3783. 相似文献
87.
R. Rimet R. Buder C. Schlenker R. Roques J.V. Zanchetta 《Solid State Communications》1981,37(9):693-697
The α and β phases of MnGa2S4-α and β have been prepared and characterized. Single crystals of the α-phase have been grown by the vapor phase transport method ; their structure found monoclinic, space group C 2/c, has been refined by the X-ray technique and the positional and thermal parameters are reported. Both compounds are antiferromagnetic with Néel temperatures of 23.5 K and 11 K, for α and β respectively. EPR spectra show a single line, exchange-narrowed at 300 K, with a strong critical broadening above TN. These results are discussed in relation with the crystal structure and the possible superexchange interactions between the Mn2+. 相似文献
88.
89.
In this paper computations in the two dimensional case of a harmonic Navier-Stokes problem with periodic boundary conditions are presented. This study of an incompressible viscous fluid leads to a non-symmetric linear problem (very low Reynolds number). Moreover unknown functions have complex values (monochromatic dynamic behaviour). Numerical treatment of the incompressibility condition is a generalization of the classical treatment of Stokes problem. A mixed formulation, where discrete pressure plays the role of Lagrange multipliers is used (Uzawa algorithm). Two conforming finite element methods are tested on different meshes. The second one uses a classical refinement in the shape function: the so-called bulb function. All computational tests show that the use of a bulb function on each element gives better results than refinement in the mesh without introducing too many degrees of freedom. Finally numerical results are compared to experimental data. 相似文献
90.
B. Lionel Funt Wendy Severs Arnold Glasel 《Journal of polymer science. Part A, Polymer chemistry》1976,14(11):2763-2771
An electroanalytical technique has been utilized in a new method for the study of reactive intermediates in polymerization reactions. A ring-disk electrode system generated persistent carbocation radicals whose stability decreased in the order: 1,3,6,8-tetraphenylpyrene (TPP), rubrene (Ru), 9,10-diphenylanthracene (DPA), and 9,10-dimethylanthracene (DMA). Radical cations from these parent compounds flowed to a collecting ring which was controlled potentiostatically to reduce unreacted cations. When styrene or isobytyl vinyl ether was added to the solution, the concentration of carbocation radicals reaching the electrode was reduced. Current collection efficiencies N were determined as a function of rotation speed ω for each monomer concentration. Plots of N?1 as ω?1 in the absence of monomer show no dependence on ω (indicative of stable intermediates), but a linear dependence is found with each concentration of monomer. This indicates a first-order dependence on radical cation concentration. The rate constants show a trend in cation reactivities which is in agreement with that obtained by other methods. This technique, however, extends the range of investigation to a much shorter time scale. 相似文献