Copper‐catalyzed Clauson–Kass pyrroles synthesis in aqueous media

An efficient and convenient copper‐catalyzed Clauson–Kass reaction of 2,5‐dimethoxytetrahydrofuran with amines in aqueous media has been developed, providing a wide range of N‐substituted pyrroles in good yields. It is noteworthy that the Clauson–Kass reaction of 2,5‐dimethoxytetrahydrofuran with p‐phenylenediamine or m‐phenylenediamine proceeds smoothly to afford the corresponding monopyrroles and bispyrroles with high selectivity in impressive yields. A plausible mechanism for the formation of N‐substituted pyrroles has been proposed. Copyright © 2012 John Wiley & Sons, Ltd.     

测定核间距的不对称2D NOESY方法2.Cis-Pt(NH3)2(Guo)2Cl2的不对称2D NOESY实验研究

应用不对称2DNOESHY实验方法研究了顺铂配合物Cis-Pt (NH₃)₂(Guo)₂Cl₂的水溶液中的构象,表明鸟苷同铂配合后其糖环构象发生明显的变化。     

Convergent-beam electron diffraction of CaZr4O9, a complex zirconia alloy phase

The point-group and space-group symmetry of the controversial fluorite-based stoichiometric superlath phase of ø₁ (CaZr₄O₉: Z=16), considered to be a coherently-intergrown subphase of lime-stabilized zirconia, is examined. Using convergent-beam and selected-area electron diffraction, it is determined that the space group of ø₁ is C2/c, in apparent agreement with earlier studies utilizing other diffraction techniques.     

计算机在配合物研究中的应用一处理电位溶出法、极谱法、电位法数据的通用程序

本文根据电化学方法研究配合物的特性,设计了一个计算配合物稳定常数的通用程序,其程序用BASIC语言编写。此程序能用于电位溶出法、极谱法和电势法研究配合物的实验数据处理。     

对Cluster模型的几点质疑

本文证明Cluster模型违背了细致平衡原理,指出了海中核子pick-up图象的不合理性。该模型的发射几率中不考虑复杂粒子正确构成的影响更是一个显著的倒退。     

石墨烯纳米带电极区N掺杂电子输运性质研究

运用密度泛函理论和非平衡格林函数结合的方法,研究电极区N掺杂对扶手椅型石墨烯纳米带电子输运特性的影响.结果表明,与本征扶手椅型石墨烯纳米带电流-电压曲线相比,宽度为7的石墨烯纳米带电流-电压曲线表现出明显的不对称性,其中心N掺杂表现强烈的整流特性,整流系数达到102数量级,且将N原子从电极区中心位置移动到边缘,整流特性减弱.研究结果表明宽度为7的扶手椅型石墨烯纳米带出现强整流现象的原因主要是负向偏压下能量窗内没有透射峰引起的,该研究结果对将来石墨烯整流器件的设计具有重要的意义.     

凸度量空间中单值和集值映象的公共不动点定理

§ 1.　Introduction　　Anecessaryandsufficientconditionandasufficientconditiontoensurethataset valuedmappingandasingle valuedmappinginacompletemetricspaceandacompleteconvexmetricspacehavingacommonfixedpointarerespectivelygivenin [1 ] .Meanwhilethemainresultsin[2 ]— [5]areimprovedandextendedin [1 ] .Inthispaper ,theexistenceatcommonfixedpointsoftwoset valuedmappingandasing valuedmappingwerestudied ,andthecorrespond ingresultsin [1 ]— [5]wereextendedandimproved .Let(X ,d)beanon emptymetricspa…