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101.
Weisshoff H Preiss A Nehls I Win T Mügge C 《Analytical and bioanalytical chemistry》2002,373(8):810-819
A hyphenated HPLC-(1)H NMR method for the identification and quantification of PAHs in soil samples has been developed and applied to a PAH reference sample provided by the Federal Institute for Materials Research and Testing (BAM, Berlin, Germany). The results were compared with those obtained by HPLC-DAD, HPLC-F, and GC-MS analyses of the same sample. 相似文献
102.
The new anhydrous borate Na2Co2B12O21 has been synthesized by flux methods and studied by single-crystal X-ray diffraction (space group I2/a with a = 17.1447(15) A, b = 4.5530(5) A, c = 19.4408(15) A, beta = 103.212(5) degrees , V = 1477.4(2) A3, Z = 4). Refinement of its structure reveals it is the first metaborate exhibiting a tunnel network, with internal dimensions of 4.5 x 8.8 A2. Further single-crystal diffraction studies show that the Na+ ions within the tunnels are exchangeable with Li+ along with the absorption of water molecules to form Li2(H2O)2Co2B12O21, making this compound a unique non-siliceous zeotype. 相似文献
103.
Linda Jean Richter 《Israel Journal of Mathematics》1979,32(1):27-31
IfF is an automorphism of the degrees of unsolvability that preserves the jump operator, thenF leaves fixed all the degreesc that satisfyc≧0
(3).
The results of this paper were part of the author’s PhD thesis (Illinois 1977), supervised by Carl G. Jockusch, Jr. 相似文献
104.
105.
Amos LA 《Organic & biomolecular chemistry》2004,2(15):2153-2160
Microtubules are designed to be dynamically unstable. GTP hydrolysis converts an initially stable polymeric structure into an unstable one in which strain at the interfaces between longitudinal neighbours in the helical lattice of subunits is balanced by lateral interactions. However, stability can be modulated by a variety of factors, including associated proteins and a variety of drug molecules. Stabilising drugs such as Taxol and the assembly-promoting repeat motifs of tau protein occupy a special pocket in beta-tubulin. Microtubule destabilizing drugs such as colchicine alter the longitudinal interfaces of the subunits so that they cannot assemble into a microtubule lattice. These mechanisms are discussed in terms of the atomic structure of the protein. 相似文献
106.
Quantitative analysis of spatially resolved valence electron energy-loss spectra shows strong physical property contrasts for Sigma5 and near Sigma13 grain boundaries in Fe-doped SrTiO3, resulting in London dispersion interaction energies of 14 to 50 mJ/m(2) between the adjacent grains. The determination of local physical properties of grain boundary cores and the appreciable contribution of long-range London dispersion to interface energies provides new information on formation and control of interfaces in materials. 相似文献
107.
Series of dipeptides, including homodipeptides and alanyl dipeptides, were separated using quadruplex (G-quartet) DNA stationary phases in open-tubular capillary electrochromatography (OTCEC). The stationary phases were constructed by covalently attaching the DNA oligonucleotides to the inner capillary surface. Three different G-quartet forming oligonucleotides were investigated: the two-plane G-quartet forming thrombin-binding aptamer, the four-plane analogue of the thrombin-binding aptamer, and a two-plane oligonucleotide identical to the thrombin-binding aptamer except for the replacement of the guanine by thymine in the central bridging loop of the G-quartet structure. Results were compared with results obtained using capillary electrophoresis on a bare capillary and OTCEC using an oligonucleotide with the same base composition as the thrombin-binding aptamer but in a different sequence that does not allow G-quartet formation as the stationary phase. 相似文献
108.
Mladenova G Singh G Acton A Chen L Rinco O Johnston LJ Lee-Ruff E 《The Journal of organic chemistry》2004,69(6):2017-2023
The photochemical pinacol reaction of a series of nonsymmetrical 9-fluorenyl-substituted vic-diols was investigated and compared with their acid-catalyzed thermal reaction. Unlike the thermal reaction, the radiation-induced processes involve only fluorenyl cations, as is reflected in differences of product distribution between the two reactions. From the product studies, substituent migratory aptitudes are reversed in the photochemical process, suggesting that kinetic control takes place under neutral conditions unlike the acid-catalyzed thermal reactions. The presence of fluorenyl cation intermediates and their lifetimes were established by laser flash spectroscopy studies. 相似文献
109.
110.
9-Diazofluorene, on treatment with stoichiometric or substoichiometric amounts of quaternary ammonium hydroxide or methoxide or of potassium t-butoxide in solution in aqueous or alcoholic dimethyl sulfoxide or acetonitrile at 30 degrees C, decomposes with evolution of nitrogen to yield fluorenone azine [bis(fluorenylidene)hydrazine] in almost quantitative yield. Studies are reported of the identity of the minor by-products, together with an examination of the kinetics of the reactions and additional spectroscopic experiments. The general rate equation is v = k[FIN2]3/2[Nu-]1/2, where Nu- represents the nucleophile. It is concluded that the oxyanions, most probably after nucleophilic attack on 9-diazofluorene under these basic conditions to generate a new anionic species, are capable of transferring an electron to the diazo-compound. This initiates decomposition of further diazo-molecules in a process of electron-transfer chain catalysis that bears some similarities to, but has also some differences from, that encountered using cathodic initiation. In support of this interpretation it is found that reactions can be accelerated by the introduction of carbon acids (fluorene, 9-phenylfluorene) into the reaction mixtures. The nature of the initiation, propagation and termination steps of the chain mechanism are discussed. 相似文献