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121.
122.
Biomimetic Surface Engineering of Lanthanide‐Doped Upconversion Nanoparticles as Versatile Bioprobes
123.
A method for characterizing and identifying firing patterns of neural spike trains is presented. Three characteristic variables defined at sequential moments, including two formal derivatives and the integration of the counting process, are introduced to reflect the temporal patterns of a spike train. This paper also examines how noise interacts with encoding mechanisms of neuronal stimulus in a cold receptor. From ISI series and bifurcation diagrams it is shown that there are considerable differences in interval distributions and impulse patterns caused by purely deterministic simulations and noisy simulations. The ISI-distance can be used as an effective and powerful way to measure the noise effects on spike trains quantitatively. It is found that spike trains observed in cold receptors can be more strongly affected by noise for low temperatures than for high temperatures in some aspects; meanwhile, spike train has greater variability with the noise intensity increasing. 相似文献
124.
Rongji Liu Kecheng Cao Adam H. Clark Peilong Lu Montaha Anjass Johannes Biskupek Ute Kaiser Guangjin Zhang Carsten Streb 《Chemical science》2020,11(4):1043
The top-down fabrication of catalytically active molecular metal oxide anions, or polyoxometalates, is virtually unexplored, although these materials offer unique possibilities, for catalysis, energy conversion and storage. Here, we report a novel top-down route, which enables the scalable synthesis and deposition of sub-nanometer molybdenum-oxo clusters on electrically conductive mesoporous carbon. The new approach uses a unique redox-cycling process to convert crystalline MoIVO2 particles into sub-nanometer molecular molybdenum-oxo clusters with a nuclearity of ∼1–20. The resulting molybdenum-oxo cluster/carbon composite shows outstanding, stable electrocatalytic performance for the oxygen reduction reaction with catalyst characteristics comparable to those of commercial Pt/C. This new material design could give access to a new class of highly reactive polyoxometalate-like metal oxo clusters as high-performance, earth abundant (electro-)catalysts.The top-down synthesis and deposition of polyoxometalate-like clusters on porous carbon is reported together with the high electrocatalytic oxygen reduction reactivity of the composite. 相似文献
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Zhewen Lu Junqiu Jiang Yi Yang Joshua Lacey Michael J. Brear 《Proceedings of the Combustion Institute》2021,38(1):243-250
This work investigates the oxidation of hydrogen near its second explosion limit in a turbulent flow reactor at pressures of 1 to 8 bar, temperatures of 950 K and an equivalence ratio of 0.035. The concentrations of H2, O2 and H2O are measured along the reactor and simulated using several kinetic models from the literature. These experiments demonstrate evident negative pressure dependence from roughly 1 to 4 bar, with further increases in pressure resuming its positive impact on reaction rates. The simulated and measured species concentrations along the reactor generally agree within a factor of 2.Further investigation is then conducted to measure the rate coefficient of reaction H + O2 (+ M) = HO2 (+M) (R2), which is one of the most sensitive reactions in hydrogen's oxidation chemistry at these conditions. This investigation is conducted by using nitric oxide (NO) as a dopant and measuring the resulting, quasi-steady-state concentrations of NO2. The rate coefficients are obtained at 950 – 1010 K. Combined with literature results, an Arrhenius expression is proposed, = 4.50 × 1020 (T/K)?1.73 [cm6 mole?2 s?1], for the reaction rate at the low-pressure limit over 500 K – 2000 K with N2 as the bath gas. Simulations using the models from the literature with the proposed Arrhenius expression for this reaction then demonstrate improved agreement with the experiments. 相似文献
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本文研究涉及差分算子的亚纯函数的唯一性问题,得到一个唯一性定理:设f是一个级不小于2的有限级整函数,η是非零复数,a(z)是不恒等于0的整函数,满足ρ(a)ρ(f)和λ(f-a)ρ(f).若f-a与Δnηf-a(n=1或2)CM分担0,则f(z)是整数级的,且ρ(a)=1或ρ(a)≥ρ(f)-1,f(z)=a(z)+[Δnηa(z)-a(z)]eA(z),其中A(z)是一个次数和ρ(f)相等的多项式. 相似文献
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