Application of hollow fiber liquid-phase microextraction in identification of oil spill sources

In this study, hollow fiber based liquid-phase microextraction (HF-LPME), coupled with GC, GC–MS and GC–IRMS detections, was employed to determine petroleum hydrocarbons in spilled oils. According to the results, the HF-LPME method collected more low-molecular weight components, such as C₇–C₁₁n-alkanes, naphthalene, and phenanthrene, than those collected in conventional liquid–liquid extraction (LLE). The results also showed that this method had no remarkable effect on the distributions of high-molecular weight compounds such as >C₁₈n-alkanes, C₁–C₃ phenanthrene, and hopanes. Also, the carbon isotopic compositions of individual n-alkanes in the two preparation processes were identical. Accordingly, HF-LPME, as a simple, fast, and inexpensive sample preparation technique, could become a promising method for the identification of oil spill sources.     

Biodegradability of poly(butylene succinate) (PBS) composite reinforced with jute fibre

Poly(butylene succinate) (PBS)/jute composites were prepared, and the effects of fibre content, diameter, surface modification and arrangement forms on the biodegradability were evaluated by compost-soil burial test. The weight losses of PBS/jute composites are higher than that of pure PBS film and bulk jute fibre, and decreased with increasing fibre content. The weight loss of PBS/10% jute composite after 180 days is 62.5%. In the case of the effect of fibre diameter, the weight loss is found to decrease with decreasing fibre diameter. For the effect of fibre surface modification, the order of higher weight loss is PBS/untreated jute > PBS/alkali treated jute > PBS/coupling agent treated jute. Furthermore, the composite of PBS/woven fabric has the highest weigh loss, followed by that of PBS/nonwoven fabric and PBS/bulk jute fibre, respectively.     

Relative Entropy and Relative Entropy of Entanglement for Infinite-Dimensional Systems

In this paper, firstly, we derive some inequalities about the relative entropy for infinite-dimensional quantum systems. Secondly, we propose a new measurement based on the relative entropy of entanglement for infinite-dimensional systems with bounded mean energy, and give a lower bound on this entanglement measure. Lastly, we generalize this measure to multi-partite quantum systems.     

Stochastic resonance in time-delayed exponential monostable system driven by weak periodic signals

Based on the exponential monostable potential, we study an exponential monostable system with time-delayed feedback driven by weak periodic signals and additive Gaussian white noises. The small delay approximation is used to deduce the steady-state probability distribution and the effective potential function is derived. The system parameters l and b, time delay τ, feedback strength β can change the shapes of the potential function. The mean first-passage time (MFPT) is calculated, which plays an extremely important role in the research of particles escape. And the signal-to-noise ratio (SNR) of the system can be obtained by using the adiabatic approximation theory. The phenomenon of stochastic resonance is investigated under different system parameters and time-delayed feedback. The amplitude of SNR can be changed by adjusting the system parameters. When the feedback strength β is positive (or negative), the time delay τ can promote (or suppress) the stochastic resonance phenomenon. The SNR versus the noise intensity D presents the stochastic resonance phenomenon. In addition, the SNR increases non-monotonically with the increasing feedback strength β and the parameter b. Also, the analysis and numerical simulation results of SNR are in good agreement with the formula simulation.     

有序大孔二氧化硅孔壁聚合物功能化修饰及葡萄糖淀粉酶固载化

介绍了一种简易的制备方法用于制备功能化有序大孔氧化硅@聚合物材料,并将其用作固载酶的新型载体。     

偏振光干涉演示仪的简单制作

采用简单的实验材料，改进偏振光的干涉演示实验，使实验简单易行，且偏振光的干涉原理以及干涉中相位和光强的关系在简单实验中得以具体体现．     

光强检测型光纤光栅温变不敏感动态压力传感研究

报道了基于光纤光栅反射谱带宽调制和光强差分检测技术实现单一光纤光栅温变不敏感动态压力传感的新方法。设计了一种结构新颖的双孔梁压力传感装置,依据双孔梁有限元受力分析将光纤光栅准确定位于线性梯度应变区,压力作用下光纤光栅反射谱对称展宽,反射光强线性正比于压力变化。基于光波导理论和材料力学原理推导了线性梯度应变场作用下光栅反射谱带宽、反射光强与压力之间的响应关系。利用光强差分检测技术取代传统波长解调方法,简化解调过程的同时传感系统免受温变影响。实验表明,在-10~80℃的温度变化范围内,系统测量误差小于总量程(120kPa)的1.8%,动态响应速度约80Hz,重复测量系统输出稳定,具有较好的应用价值。     

First-principles study of oxygenated diamond (0 0 1) surfaces with and without hydrogen

The structural characterization of oxygenated diamond (0 0 1) surface with and without H-presence has been investigated by the density-functional theory within the generalized gradient approximation and the plane-wave pseudopotential method. It is shown that, without the H, the O-bridge site has lower energy than the O-on-top site for both half and fully monolayer (ML) oxygen coverage. For hydrogenated diamond (0 0 1) surfaces, we found for half ML O coverage, a more stable (2 × 2):0.5H&0.5(OH) phase than the previously reported (2 × 1):0.5H&0.5(OH) phase [H. Tamura, H. Zhou, K. Sugisako, Y. Yokoi, S. Takami, M. Kubo, K. Teraishi, A. Miyamoto, A. Imamura, M.N. Gamo, T. Ando, Phys. Rev. B 61 (2000) 11025]. Furthermore, at one ML O coverage, a (2 × 2):(OH) phase is the most stable structure than the previously reported (2 × 1):(OH) phase. With the increase of the (OH) coverage, the importance of the hydrogen bonds increases in terms of stabilizing these structures.     

一种反应型染料的合成及其在聚氨酯革染色中的应用

针对传统聚氨酯色浆中色基与聚氨酯结合力弱(分子间力),导致成品革色牢度差、色迁移严重等技术难题,本文设计合成了一种反应型彩色二元醇:在四氢呋喃介质中,控制n(对苯二胺)∶n(乙酸酐)=1.00∶0.95,0~5℃下,用乙酸酐将对苯二胺单酰化反应15 h,得到对氨基乙酰苯胺(产率85%),经重氮化,与过量摩尔分数为5%N-苯基二乙醇胺偶合制得了一种含两个端羟甲基的偶氮化合物4-乙酰基胺基-4'-N,N-二羟乙氨基偶氮苯(产率82%);将其与聚酯二元醇、聚醚二元醇以不同比例混合,与双异氰酸酯预聚、扩链后形成红色聚氨酯树脂色浆,在离型纸上铺展成膜,其断裂增长率443.0%,断裂相对强度125.5 g,色迁移量21.4μg,进口同类产品形成膜后的断裂增长率、断裂相对强度与色迁移量分别为442.2%、125.3 g和29.2μg.合成产品优于同类进口产品。     

Synthesis of novel PEG-modified nitroimidazole derivatives via “hot-click” reaction and their biological evaluation as potential PET imaging agent for tumors

Ten novel PEG-modified nitroimidazole derivatives labeled with ¹⁸F were synthesized via “hot-click” reaction and evaluated as PET tumor tracers. The radiolabeling method was convenient and efficient, all compounds displayed high radiochemical purity (>95%), high yield (30–50%) and good stability in saline and human serum. The biodistribution studies in EMT-6 tumor-bearing mice demonstrated their tumor uptake values at 60 min postinjection were 1.46–2.99%ID/g, which were lower than [¹⁸F]FMISO (5.43%ID/g), their tumor-to-liver ratios were 0.73–1.07, higher than [¹⁸F]FMISO (0.69). In vitro MCF-7 cell uptake studies showed their uptake values have no significant difference between hypoxic and aerobic cells.