全文获取类型
收费全文 | 466篇 |
免费 | 17篇 |
国内免费 | 3篇 |
专业分类
化学 | 379篇 |
晶体学 | 4篇 |
力学 | 5篇 |
数学 | 53篇 |
物理学 | 45篇 |
出版年
2023年 | 2篇 |
2022年 | 10篇 |
2021年 | 11篇 |
2020年 | 3篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2017年 | 11篇 |
2016年 | 14篇 |
2015年 | 10篇 |
2014年 | 17篇 |
2013年 | 45篇 |
2012年 | 29篇 |
2011年 | 52篇 |
2010年 | 29篇 |
2009年 | 21篇 |
2008年 | 37篇 |
2007年 | 36篇 |
2006年 | 23篇 |
2005年 | 20篇 |
2004年 | 18篇 |
2003年 | 23篇 |
2002年 | 20篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 5篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1970年 | 1篇 |
1968年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有486条查询结果,搜索用时 547 毫秒
51.
Stanis?aw Gawiejnowicz Wies?aw Kurc Lidia Pankowska 《Discrete Applied Mathematics》2006,154(15):2150-2166
In the paper a single machine time-dependent scheduling problem is considered. The processing time pj of each job is described by a function of the starting time t of the job, pj=1+αjt, where the job deterioration rate αj?0 for j=0,1,…,n and t?0. Jobs are nonpreemptable and independent, there are no ready times and no deadlines. The criterion of optimality of a schedule is the total completion time.First, the notion of a signature for a given sequence of job deterioration rates is introduced, two types of the signature are defined and their properties are shown. Next, on the basis of these properties a greedy polynomial-time approximation algorithm for the problem is formulated. This algorithm, starting from an initial sequence, iteratively constructs a new sequence concatenating the previous sequence with new elements, according to the sign of one of the signatures of this sequence.Finally, these results are applied to the problem with job deterioration rates which are consecutive natural numbers, αj=j for j=0,1,…,n. Arguments supporting the conjecture that in this case the greedy algorithm is optimal are presented. 相似文献
52.
Lidia Gonzlez Xavier Ramis Josep Maria Salla Ana Mantecn Angels Serra 《Journal of polymer science. Part A, Polymer chemistry》2006,44(23):6869-6879
Ytterbium and lanthanum triflates were used as initiators to cure mixtures of diglycidyl ether of bisphenol A and 6,6‐dimethyl‐(4,8‐dioxaspiro[2.5]octane‐5,7‐dione) in several proportions. The evolution of the epoxy and 6,6‐dimethyl‐(4,8‐dioxaspiro[2.5]octane‐5,7‐dione) bands during curing and the linear ester groups in the final materials were evaluated with Fourier transform infrared in the attenuated‐total‐reflection mode. The use of a conventional cationic initiator, boron trifluoride monoethylamine, was also studied to test the advantages of lanthanide triflates. The shrinkage after curing and the thermal degradability of the materials with variations in the comonomer ratio and the initiator were evaluated and related to the chemical structure of the final network. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6869–6879, 2006 相似文献
53.
Daniel Ari Mendelson Janice Filion Heinsbergen Scott D. Kennedy Lidia S. Szczepaniak Cathy Coolbaugh Lester Robert G. Bryant 《Magnetic resonance imaging》1991,9(6):975-978
Measurements of the magnetic field dependence of spin-lattice relaxation rates and the response of the water-proton signal intensity to off-resonance radio frequency fields show that the commonly used agarose phantom provides a less faithful representation for the magnetic response of tissue than does a cross-linked protein system. The origin of these differences lies in the structure and intramolecular dynamics of the macromolecular system used to make the gel. These distinctions will also cause differences in the magnetic response of the water spin system when paramagnetic relaxation agents or contrast agents are incorporated. Use of a thermally cross-linked bovine serum albumin phantom is suggested. 相似文献
54.
Rafael Jimnez Elena Bueno Israel Cano Elizabeth Corbacho M. Eugenia Fernndez Lidia Gmez Jesús Graciani María Hernndez M. Teresa Matitos Jos Ortíz Pilar Lpez‐Cornejo Rafael Prado‐Gotor 《国际化学动力学杂志》2004,36(12):627-633
The kinetics of substitution of H2O by Ru(NH3)5pz2+ (pz = pyrazine) in Fe(CN)5H2O3? have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach is better than others based on the pseudophase model, which can also be used, because it is able to give a clear meaning to the parameters of the model. Trends in the observed reactivity are explained by a change in the degree of association of one of the reactants to the micelles (Ru(NH3)5pz2+ in the present work). This association is governed by an equilibrium constant that depends on the electrostatic potential at the surface of the micelles. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 627–633, 2004 相似文献
55.
Lidia Prajer-Janczewska Anna Postawka Krystyna Koćma Krystyna Rudolf 《Monatshefte für Chemie / Chemical Monthly》1968,99(3):1175-1176
Ohne ZusammenfassungMit 1 Abbildung 相似文献
56.
Many models of market dynamics make use of the idea of conservative wealth exchanges among economic agents. A few years ago an exchange model using extremal dynamics was developed and a very interesting result was obtained: a self-generated minimum wealth or poverty line. On the other hand, the wealth distribution exhibited an exponential shape as a function of the square of the wealth. These results have been obtained both considering exchanges between nearest neighbors or in a mean field scheme. In the present paper we study the effect of distributing the agents on a complex network. We have considered archetypical complex networks: Erdös–Rényi random networks and scale-free networks. The presence of a poverty line with finite wealth is preserved but spatial correlations are important, particularly between the degree of the node and the wealth. We present a detailed study of the correlations, as well as the changes in the Gini coefficient, that measures the inequality, as a function of the type and average degree of the considered networks. 相似文献
57.
58.
Dr. Lidia A. Maslovskaya Dr. Andrei I. Savchenko Prof. Elizabeth H. Krenske Dr. Sharon Chow Tina Holt Dr. Victoria A. Gordon Dr. Paul W. Reddell Carly J. Pierce Prof. Peter G. Parsons Prof. Glen M. Boyle Prof. Andrei G. Kutateladze Prof. Craig M. Williams 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(51):11862-11867
Structurally unique halimanes EBC-232 and EBC-323, isolated from the Australian rainforest plant Croton insularis, proved considerably difficult to elucidate. The two diastereomers, which consist an unusual oxo-6,7-spiro ring system fused to a dihydrofuran, were solved by unification and consultation of five in silico NMR elucidation and prediction methods [i.e., ACDLabs, olefin strain energy (OSE), DP4, DU8+ and TD DFT CD]. Structure elucidation challenges of this nature are prime test case examples for empowering future AI learning in structure elucidation. 相似文献
59.
Journal of Thermal Analysis and Calorimetry - The structural relaxation of Na2O–K2O–CaO–ZrO2–SiO2 (NKCZ), Na2O–K2O–ZnO–ZrO2–SiO2 (NKzZ),... 相似文献
60.
Dey S Pal C Nandi D Giri VS Zaidlewicz M Krzeminski M Smentek L Hess BA Gawronski J Kwit M Babu NJ Nangia A Jaisankar P 《Organic letters》2008,10(7):1373-1376
3,3'-Bipyrroles 3 could be synthesized using a double Michael addition reaction involving diaroyl acetylene 1 and the appropriate 1,3-dicarbonyls 2 using ammonium acetate as a nitrogen source. The axial chirality of bipyrrole was anticipated from the X-ray crystal structure and DFT calculations and confirmed by separating the racemates on a chiral column and subsequent CD spectra of the enantiomers. The absolute configuration of the enantiomers was achieved by theoretical CD spectra calculation using the ZINDO method. 相似文献