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961.
962.
M. Liang H. Ohm B. De Sutter K. Sistemich B. Fazekas G. Molnär 《Zeitschrift für Physik A Hadrons and Nuclei》1991,340(2):223-224
The half-lives of low-lying levels of the neutron-rich isotopes102Mo and104Mo have been measured at the fission product separator Josef with the ß-- triple coincidence technique. Values of t1/2= 126(4)ps and 0.72(4)ns have been obtained for the 21
+ levels at 296 keV and 192 keV in102Mo and104Mo, respectively. Deformation parameters of ßq=0.28(1) and 0.31(1), respectively, are deduced, which are smaller than those of the isotones of Sr and Zr. The interacting boson model accounts well for the trend of 2+ energies in the Mo isotopes but slightly overpredicts the B(E2) values at saturation. A smooth dependence of 21
+ vs. E 21
+ is found for the A 100 region in agreement with the hydrodynamical model.Dedicated to Prof. Dr. P. Kienle on the occasion of his 60th birthday 相似文献
963.
964.
965.
2‐Aminobenzyl alcohol undergoes oxidative cyclization with aryl(alkyl), alkyl(alkyl) and cyclic ketones in dioxane at 80° in the presence of a catalytic amount of RhCl(PPh3)3 along with KOH to afford the corresponding quinolines in good yields. The catalytic pathway seems to be proceeded via a sequence involving initial oxidation of 2‐aminobenzyl alcohol to 2‐aminobenzaldehyde by a rhodium catalyst, cross aldol reaction between 2‐aminobenzaldehyde and ketones, and cyclodehydration. 相似文献
966.
A new fluorinated polystyrene bearing a p-sulbstiuted perfluoro[1-(2-fluorosulfonylethoxy)]ethyl group was synthesized via one-electron oxidation of polystyrene by perfluoro[2-(2-fluorosulfonylethoxy)]propionyl peroxide at different peroxide to polystyrene molar ratios.The yield of perfluoroalkylation decreases with the increase of the reactant molar ratio.The modified polymer has been characterized by various techniques:the ring pefluoro[1-(2-fluorosulfonylethoxy)]ethylation has been proved by FT-IR and ^19FNMR;the X-ray photoelectron spectra(XPS) show the maximum binding energy of F18,O18,C18(two kinds of carbon atoms,namely C-H and C-F)and S2p,respectively; desulfonylation of the fluorinated polystyrene appearing at 217℃ has been found by its thermogravimetric analysis (TGA).The determinations of contact angle,refractive index and glass transition temperature of the modified polymer have disclosed that when the contact angle increases with the increase of the molar ratio,the refractive index and glass transition temperature decrease.The polydispersity values indicate that the degradation of the polymer chains did not occur during the reaction. 相似文献
967.
In this paper, multi-wall carbon nanotubes fuctionalized with carboxylic groups modified electrode (MWNT-COOH CME) was fabricated. This chemically modified electrode (CME) can be used as the working electrode in the liquid chromatography for the determination of 6-mercaptopurine (6-MP). The results indicate that the CME exhibits efficiently electrocatalytic oxidation for 6-MP with relatively high sensitivity, stability and long-life. The peak currents of 6-MP are linear to its concentrations ranging from 4.0×10−7 to 1.0×10−4 mol l−1 with the calculated detection limit (S/N=3) of 2.0×10−7 mol l−1. Coupled with microdialysis, the method has been successfully applied to the pharmacokinetic study of 6-MP in rabbit blood. This method provides a fast, sensible and simple technique for the pharmacokinetic study of 6-MP in vivo. 相似文献
968.
A facile total synthesis of (+)-hernandulcin (1) was accomplished from (−)-isopulegol in 6 steps with 15% overall yield. Epoxidation of (−)-isopulegol with m-chloroperbenzoic acid followed by opening of the epoxide 3a with prenyl Grignard afforded the tertiary alcohol 4a with correct C-6 and C-1′ stereochemistry as a major product. Oxidation of the secondary alcohol in compound 4a to the ketone 5a was accomplished in high yield by using TPAP and N-methylmorpholine N-oxide. Conversion of the ketone 5a to α,β-unsaturated ketone via organoselenium intermediate gave (+)-hernandulcin (1). This method was also successfully applied to the synthesis of (+)-epihernandulcin (2). 相似文献
969.
Guo-dong Liang Jun-ting Xu Zhi-qiang Fan 《高分子科学》2006,(4):341-344
Thin film morphology of a symmetric semicrystalline oxyethylene/oxybutylene diblock copolymer (E76B38) on silicon was investigated by tapping mode atomic force microscopy (AFM). It is found that the nascent thin film is composed of multiple polymer layers having mixed thicknesses of L ≈ L0 and L ≈ L0/2 (L0 is the long period of the block copolymer in bulk) besides the first layer near the substrate. This shows that the crystalline domain in the block copolymer consists of double poly(oxyethylene) layers. Annealing leads to disappearance of the polymer layers with thickness L ≈L0/2, indicating that such polymer layers are metastable. 相似文献
970.
Pb(Zr0.25Ti0.75)O3 (PZT25) thin films were prepared on LaNiO3-coated thermally oxidized silicon substrates by chemical solution deposition method, where LaNiO3 electrodes were also prepared by a chemical solution deposition technique. The dielectric constant and dielectric loss of
the PZT25 thin films were 570 and 0.057, respectively. The remanent polarization and coercive field were 20.11 μC/cm2 and 60.7 kV/cm, respectively. The PZT25 thin films on LaNiO3-coated thermally oxidized silicon substrates showed improved fatigue characteristics compared with their counterparts on
plantium-coated silicon substrates. 相似文献