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排序方式: 共有138条查询结果,搜索用时 31 毫秒
31.
Hruška Branislav Osipov Armenak A. Osipova Leyla M. Chromčíková Mária Černá Andrea Liška Marek 《Journal of Thermal Analysis and Calorimetry》2018,133(1):429-433
Journal of Thermal Analysis and Calorimetry - The temperature dependence of Raman spectra of 25Na2O·75B2O3 melts recorded in the temperature range 321–1142 °C was studied... 相似文献
32.
Alkylidene Meldrum's acids and 2,6‐dimethylphenyl isocyanide react smoothly in the presence of arylhydroxylamines at room temperature to produce 2,5‐dioxo‐pyrrolidines in fairly high yield. 相似文献
33.
Phosphorus‐nitrogen compounds. Part 39. Syntheses and Langmuir‐Blodgett thin films and antimicrobial activities of N/N and N/O spirocyclotriphosphazenes with monoferrocenyl pendant arm
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Nuran Asmafiliz Mehmet Civan Arda Özben Zeynel Kılıç Nagehan Ramazanoğlu Leyla Açık Tuncer Hökelek 《应用有机金属化学》2018,32(4)
The Cl substitution reactions of the N/N ( 1 ‐ 3 ) and N/O ( 4 and 5 ) spirocyclic monoferrocenylphosphazenes with 1,4‐dioxa‐8‐azaspiro[4,5]decane (DASD) produce the mono‐ ( 1a ‐ 5a ), geminal‐ ( 1b ‐ 5b ) and tetrakis‐DASD‐substituted ferrocenylspirocyclotriphosphazenes ( 1c ‐ 5c ). The mono‐ and geminal‐DASD‐substituted phosphazenes have two and one stereogenic P‐centers, respectively. The structures of the compounds were established by spectroscopic techniques. The molecular structures of 3a and 2b were evaluated using X‐ray crystallography. Additionally, the ultrathin and highly ordered Langmuir‐Blodgett (LB) films of 3a and 2b were also prepared. The characterizations of the LB films were done using p‐polarized grazing angle (GAIR) and horizontal attenuated total reflectance (HATR) techniques. On the other hand, the antimicrobial activities of the eight phosphazene derivatives against G(+) and G(‐) bacteria and fungi were investigated. Furthermore, the interactions between the compounds and plasmid DNA were studied by agarose gel electrophoresis. 相似文献
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35.
This article reports on an exploratory investigation of the measurement estimation performance of ten Iranian high school students on a set of real-world length and area measurement tasks. The results of a qualitative analysis of the data indicate that the students employed a variety of either mental or physically present Individual Frames of Reference as the non-tool units of measure in various estimation tasks. The analysis also found that a range of types of frames of reference was used across students in response to particular tasks and to the physical environments in which the tasks were situated. These results suggest that there is a complex interaction among a student’s individual preference for a particular type of Individual Frame of Reference, the nature of the estimation activity, and the physical context in which the activity takes place. These findings, which contribute to an understanding of the nature of the measurement unit that is employed during an estimation process, provide a different perspective from other studies that focus on categorizing estimation strategies, or processes. 相似文献
36.
Murat Aydemir Akın Baysal Nevin Gürbüz İsmail Özdemir Bahattin Gümgüm Saim Özkar Nagihan Çaylak Leyla Tatar Yıldırım 《应用有机金属化学》2010,24(1):17-24
Three new (N‐diphenylphosphino)‐isopropylanilines, having isopropyl substituent at the carbon 2‐ (1) 4‐ (2) or 2,6‐ (3) were prepared from the aminolysis of chlorodiphenylphosphine with 2‐isopropylaniline, 4‐isopropylaniline or 2,6‐diisopropylaniline, respectively, under anaerobic conditions. Oxidation of 1,2 and 3 with aqueous hydrogen peroxide, elemental sulfur or gray selenium gave the corresponding oxides, sulfides and selenides (Ph2P?E)NH? C6H4? 2‐CH(CH3)2, (Ph2P?E)NH? C6H4? 4‐CH(CH3)2 and (Ph2P?E)NH? C6H4? 2,6‐{CH(CH3)2}2, where E = O, S, or Se, respectively. The reaction of [M(cod)Cl2] (M = Pd, Pt; cod = 1,5‐cyclooctadiene) with two equivalents of 1,2 or 3 yields the corresponding monodendate complexes [M((Ph2P)NH? C6H4? 2‐CH(CH3)2)2Cl2], M = Pd 1d, M = Pt 1e, [M((Ph2P)NH? C6H4? 4‐CH(CH3)2)2Cl2], M = Pd 2d, M = Pt 2e and [M((Ph2P)NH? C6H4? 2,6‐(CH(CH3)2)2)2Cl2], M = Pd 3d, M = Pt 3e, respectively. All the compounds were isolated as analytically pure substances and characterized by NMR, IR spectroscopy and elemental analysis. Furthermore, representative solid‐state structure of [(Ph2P?S)NH? C6H4? 4‐CH(CH3)2] (2b) was determined using single crystal X‐ray diffraction technique. The complexes 1d–3d were tested and found to be highly active catalysts in the Suzuki coupling and Heck reaction, affording biphenyls and stilbenes, respectively. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
37.
Leyla Gidi Jessica Honores José Ibarra María Jesús Aguirre Roxana Arce Galo Ramírez 《Electroanalysis》2022,34(7):1163-1173
In this work, the determination of gallic acid was performed using surface-renewable carbon paste electrodes fabricated with multi-walled carbon nanotubes (MWCNT) and a mixture of N-octylpyridinium hexafluorophosphate (OPyPF6) ionic liquid with mineral oil (MO) as binder. This system shows remarkable amperometric sensor characteristics and promotes a better electronic transfer. An electroanalytical study of gallic acid shows a linear range from 4.98±0.25 to 74.1±2.2 μmol L−1, with R2=0.9958 and an experiment a limit of detection of 2.70±0.08 μmol L−1 (S/N=3), and a sensitivity of 0.029 μA μmol−1 L. 相似文献
38.
Leyla Daruis Pablo Gonzlez-Vera Francisco Marcelln 《Journal of Computational and Applied Mathematics》2002,140(1-2)
Let μ be a probability measure on [0,2π]. In this paper we shall be concerned with the estimation of integrals of the form
For this purpose we will construct quadrature formulae which are exact in a certain linear subspace of Laurent polynomials. The zeros of Szegö polynomials are chosen as nodes of the corresponding quadratures. We will study this quadrature formula in terms of error expressions and convergence, as well as, its relation with certain two-point Padé approximants for the Herglotz–Riesz transform of μ. Furthermore, a comparison with the so-called Szegö quadrature formulae is presented through some illustrative numerical examples. 相似文献
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39.
A. N. Bugay S. V. Sazonov 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(12):1632-1636
The propagation and transverse dynamics of extremely short pulses in a nonequilibrium medium consisting of two-level atoms has been investigated. It is shown that, if the spectrum of such pulses does not overlap the characteristic frequency of quantum transitions, non-1D superluminal pulses with retained shape may exist. 相似文献
40.
Leyla Tatar Gülsün Gkaac Diner Ülkü 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(6):668-669
The title compound, [Cu(C6H2Br3O)2(NH3)2], a monomeric centrosymmetric CuII complex, crystallizes in the monoclinic system. The CuO2N2 coordination sphere is trans planar, [Cu—O 1.943 (5) Å and Cu—N 1.977 (6) Å], with the fifth and sixth coordination sites occupied by Br atoms from the phenoxide ions [Cu—Br 3.129 (1) Å], resulting in an elongated distorted octahedral structure for the CuO2N2Br2 coordination. Each of the NH3 groups forms two hydrogen bonds with the Br and O atoms of the CuO2N2Br2 moiety of a neighbouring molecule. This arrangement constitutes a one‐dimensional chain along the x axis of the unit cell. 相似文献