全文获取类型
收费全文 | 595篇 |
免费 | 37篇 |
国内免费 | 11篇 |
专业分类
化学 | 500篇 |
晶体学 | 4篇 |
力学 | 2篇 |
数学 | 58篇 |
物理学 | 79篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 12篇 |
2021年 | 22篇 |
2020年 | 18篇 |
2019年 | 41篇 |
2018年 | 43篇 |
2017年 | 24篇 |
2016年 | 37篇 |
2015年 | 38篇 |
2014年 | 34篇 |
2013年 | 84篇 |
2012年 | 37篇 |
2011年 | 53篇 |
2010年 | 26篇 |
2009年 | 28篇 |
2008年 | 25篇 |
2007年 | 18篇 |
2006年 | 11篇 |
2005年 | 16篇 |
2004年 | 21篇 |
2003年 | 4篇 |
2002年 | 15篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有643条查询结果,搜索用时 46 毫秒
101.
The tandem catalysis system including the trimerization catalyst of CrCl3/SNS (SNS = bis-(2-pentylsulfanyl-ethyl)-amine) (Cat 1) and the copolymerization catalyst Cat 2 of Cr/SiO2 (Grace 643) has been prepared and used to the synthesis of branched polyethylene. The optimum polymerization conditions were found to be as follows: chromium concentration 0.2 wt %, ethylene pressure 23 bar, solvent hexane, polymerization temperature 90°C, co-catalyst triethylaluminum. The optimally prepared polyethylene was characterized thermally and morphologically. Appearance of α and γ hydrogens in ethylene-1-hexene copolymer confirms the presence of branches in polyethylene backbone. 相似文献
102.
A convenient and efficient procedure for the Friedel-Crafts acylation of aromatic compounds with carboxylic acids in the presence of P2O5/SiO2 is described. Both aromatic and aliphatic carboxylic acids reacted easily to afford the corresponding aromatic ketones. The use of non-toxic and inexpensive materials, simple and clean work-up, short reaction times and good yields of the products are the advantages of this method. 相似文献
103.
Rebecca Wiesner Holger Zagst Wenkui Lan Stewart Bigelow Peter Holper Göran Hübner Leila Josefsson Claire Lancaster Lili Lo Christopher Lößner Huixin Lu Christian Neusüß Carolin Rüttiger Johannes Schlecht Philipp Schürrle Alexander Selsam Debbie van der Burg Shao-Chun Wang Yunxiao Zhu Hermann Wätzig Cari Sänger-van de Griend 《Electrophoresis》2023,44(15-16):1247-1257
Capillary zone electrophoresis ultraviolet (CZE-UV) has become increasingly popular for the charge heterogeneity determination of mAbs and vaccines. The ε-aminocaproic acid (eACA) CZE-UV method has been used as a rapid platform method. However, in the last years, several issues have been observed, for example, loss in electrophoretic resolution or baseline drifts. Evaluating the role of eACA on the reported issues, various laboratories were requested to provide their routinely used eACA CZE-UV methods, and background electrolyte compositions. Although every laboratory claimed to use the He et al. eACA CZE-UV method, most methods actually deviate from He's. Subsequently, a detailed interlaboratory study was designed wherein two commercially available mAbs (Waters’ Mass Check Standard mAb [pI 7] and NISTmAb [pI 9]) were provided to each laboratory, along with two detailed eACA CZE-UV protocols for a short-end, high-speed, and a long-end, high-resolution method. Ten laboratories participated each using their own instruments, and commodities, showing excellence method performance (relative standard deviations [RSDs] of percent time-corrected main peak areas from 0.2% to 1.9%, and RSDs of migration times from 0.7% to 1.8% [n = 50 per laboratory], analysis times in some cases as short as 2.5 min). This study clarified that eACA is not the main reason for the abovementioned variations. 相似文献
104.
Motiei L Altman M Gupta T Lupo F Gulino A Evmenenko G Dutta P van der Boom ME 《Journal of the American Chemical Society》2008,130(28):8913-8915
Accelerated growth of a molecular-based material that is an active participant in its continuing self-propagated assembly has been demonstrated. This nonlinear growth process involves diffusion of palladium into a network consisting of metal-based chromophores linked via palladium. 相似文献
105.
Maleknejad Khosrow Nouri Kazem Torkzadeh Leila 《Mediterranean Journal of Mathematics》2016,13(3):1377-1390
This paper is devoted to studying a computational method for solving multi-term differential equations based on new operational matrix of shifted second kind Chebyshev polynomials. The properties of the operational matrix of fractional integration are exploited to reduce the main problem to an algebraic equation. We present an upper bound for the error in our estimation that leads to achieve the convergence rate of O(M −κ). Numerical experiments are reported to demonstrate the applicability and efficiency of the proposed method.
相似文献106.
107.
In this work, the ionic liquid (IL)[C6mim][PF6] was used as IL-based extractant for dispersive liquid–liquid microextraction, followed by back-extraction and HPLC/UV–Vis determination of 3-indole acetic acid (IAA) in pea plant. The effects of some crucial factors such as chemical structure and volume of IL, pH adjustment, dissolution temperature, extraction time, centrifugation time, and ionic strength of aqueous sample were studied. The linear range of the HPLC method for IAA quantification was 17.5 × 10?2–36.8 mg L?1. LOD, LOQ, method recovery, and preconcentration factor values were 0.170 mg L?1, 0.175 mg L?1, 98.3, and 40 %, respectively. The RSD for the suggested method was calculated as 0.93 % at 35.04 mg L?1 of IAA and each IL phase was able to be reused for at least four DLLME/back-extraction cycles. To evaluate the applicability of the suggested method, IAA was determined in pea plant samples. 相似文献
108.
Alexander V. Evteev Elena V. Levchenko Leila Momenzadeh Irina V. Belova Graeme E. Murch 《哲学杂志》2016,96(6):596-619
Using results of equilibrium molecular dynamics simulation in conjunction with the Green–Kubo formalism, we present a general treatment of thermal impedance of a crystal lattice with a monatomic unit cell. The treatment is based on an analytical expression for the heat current autocorrelation function which reveals, in a monatomic lattice, an energy gap between the origin of the phonon states and the beginning of the energy spectrum of the so-called acoustic short-range phonon modes. Although, we consider here the f.c.c. Al model as a case example, the analytical expression is shown to be consistent for different models of elemental f.c.c. crystals over a wide temperature range. Furthermore, we predict a frequency ‘window’ where the thermal waves can be generated in a monatomic lattice by an external periodic temperature perturbation. 相似文献
109.
Shamsipur M Dastjerdi LS Haghgoo S Armspach D Matt D Aboul-Enein HY 《Analytica chimica acta》2007,601(1):130-138
19F NMR spectroscopy was applied to the quantitative determination of fluoxetine enantiomers using different chiral recognition agents in pharmaceutical formulations. Several parameters affecting the enantioresolution including the type and concentration of chiral selector, concentration of fluoxetine and temperature were studied. The chiral selectors investigated are the cyclic oligosaccharides α-, β- and γ-cyclodextrin and a diamino derivative of methylated α-cyclodextrin (DAM-α-CD), linear polysaccharides (maltodextrin with dextrose equivalents of 4.0-7.0, 13.0-17.0 and 16.5-19.5) and the macrocyclic antibiotic vancomycin. Among the chiral selectors used, DAM-α-CD turned out to give the best resolution of the 19F NMR signals of (R)- and (S)-fluoxetine. The calibration curve was linear for (R)- and (S)-fluoxetine over the range 0.10-1.35 mg mL−1, the detection limits (S/N = 3) being 5.9 and 7.5 μg mL−1 for the pure solutions of (R)- and (S)-fluoxetine, respectively. The recovery studies performed on pharmaceutical samples ranged from about 90 to 110% with relative standard deviations of <8%. The results showed that the proposed method is rapid, precise and accurate. Applying statistical Student's t-test revealed insignificant difference between the real and measured contents at the 95% confidence level. 相似文献
110.
Quality of botanical products is a great uncertainty that consumers, clinicians, regulators, and researchers face. Definitions
of quality abound, and include specifications for sanitation, adventitious agents (pesticides, metals, weeds), and content
of natural chemicals. Because dietary supplements (DS) are often complex mixtures, they pose analytical challenges and method
validation may be difficult. In response to product quality concerns and the need for validated and publicly available methods
for DS analysis, the US Congress directed the Office of Dietary Supplements (ODS) at the National Institutes of Health (NIH)
to accelerate an ongoing methods validation process, and the Dietary Supplements Methods and Reference Materials Program was
created. The program was constructed from stakeholder input and incorporates several federal procurement and granting mechanisms
in a coordinated and interlocking framework. The framework facilitates validation of analytical methods, analytical standards,
and reference materials. 相似文献