全文获取类型
收费全文 | 44697篇 |
免费 | 3191篇 |
国内免费 | 2938篇 |
专业分类
化学 | 22586篇 |
晶体学 | 579篇 |
力学 | 2282篇 |
综合类 | 214篇 |
数学 | 10445篇 |
物理学 | 14720篇 |
出版年
2024年 | 43篇 |
2023年 | 342篇 |
2022年 | 611篇 |
2021年 | 748篇 |
2020年 | 855篇 |
2019年 | 805篇 |
2018年 | 1859篇 |
2017年 | 2113篇 |
2016年 | 1579篇 |
2015年 | 1458篇 |
2014年 | 1615篇 |
2013年 | 2064篇 |
2012年 | 4687篇 |
2011年 | 3977篇 |
2010年 | 3011篇 |
2009年 | 2645篇 |
2008年 | 1792篇 |
2007年 | 1605篇 |
2006年 | 1466篇 |
2005年 | 5068篇 |
2004年 | 4424篇 |
2003年 | 2671篇 |
2002年 | 806篇 |
2001年 | 559篇 |
2000年 | 331篇 |
1999年 | 416篇 |
1998年 | 290篇 |
1997年 | 204篇 |
1996年 | 201篇 |
1995年 | 163篇 |
1994年 | 166篇 |
1993年 | 134篇 |
1992年 | 265篇 |
1991年 | 240篇 |
1990年 | 204篇 |
1989年 | 170篇 |
1988年 | 141篇 |
1987年 | 101篇 |
1986年 | 91篇 |
1985年 | 67篇 |
1984年 | 40篇 |
1983年 | 41篇 |
1976年 | 83篇 |
1975年 | 41篇 |
1974年 | 42篇 |
1973年 | 48篇 |
1972年 | 39篇 |
1969年 | 39篇 |
1968年 | 36篇 |
1966年 | 37篇 |
排序方式: 共有10000条查询结果,搜索用时 609 毫秒
81.
对以本征Si及重掺杂p型和n型Si作为中间层的Fe/Si多层膜的层间耦合进行研究,并通过退火,增大Fe,Si之间的扩散,分析界面扩散对层间耦合的影响. 实验结果表明,层状结构良好的制备态的多层膜,Fe,Si之间也存在一定程度的扩散,它是影响层间耦合的 主要因素,远远超过了半导体意义上的重掺杂,使不同种类的Si作为中间层的层间耦合基本 一致.进一步还发现,在一定范围内增大Fe,Si之间的扩散,即使多层膜的层状结构已经有了相当的退化,Fe/Si多层膜的反铁磁耦合强度基本保持不变.
关键词:
Fe/Si多层膜
层间耦合
界面扩散 相似文献
82.
Hamid R. Memarian Mohammad Bagheri Dietrich D?pp 《Monatshefte für Chemie / Chemical Monthly》2004,42(3):833-838
In continuation of previous work some novel 3,5-diacetyl-1,4-dihydropyridine derivatives were synthesized and their photochemical behavior was studied under oxygen and argon atmosphere. Oxidation of the dihydropyridine ring and formation of pyridine derivatives was the result of the reaction. The presence of oxygen affects not only on the rate of oxidation, but also the formation of some unidentified by-products was observed on irradiation under this atmosphere. 相似文献
83.
Jianhu Yang Shixun Dai Nengli Dai Lei Wen Lili Hu Zhonghong Jiang 《Journal of luminescence》2004,106(1):9-14
Nonradiative decay of 4I13/2→4I15/2 transition of Er3+ has been investigated in a series of oxide glasses. For Er3+-doped glass samples, the Judd-Ofelt analysis on absorption spectra was performed and the fluorescence lifetime was determined by extrapolating to zero Er3+ concentration limit. Infrared spectra were measured in order to investigate the influence of OH− groups in different glasses. The effects of glass matrix on the decay rate were discussed from the viewpoint of phonon energy, variations of effective fields, and OH− groups. Compared to other glasses, phosphate glass presents low quantum efficiency and large nonradiative decay rate due to its high phonon energy and hygroscopic behavior. 相似文献
84.
The Kα to Lα and Kβ to Lβ intensity ratios of seven elements have been measured following photoionization at 59.5 keV by using a Si (Li) detector
(FWHM=155 eV at 5.96 keV). The intensity ratios were determined by measuring K and L x-rays emitted from a standard target of a given element. The theoretical values of the Kα to Lα and Kβ to Lβ intensity ratios were calculated using theoretically tabulated values of shell/subshell photoionization cross sections,
fluorescence yields, Coster-Kronig transition probabilities, and radiative decay rates for ηKLi≠ and ηKLi=0. The measured values are in good agreement with theoretical results.
From Optika i Spektroskopiya, Vol. 97, No. 2, 2004, pp. 186–189.
Original English Text Copyright ? 2004 by A. Kü?ük?nder, S?ğüt, E. Kü?ük?nder, Büyükkasap.
This article was submitted by the authors in English. 相似文献
85.
稀磁半导体Zn1-xMnxTe吸收光谱压力红移的理论研究 总被引:1,自引:1,他引:0
以自由Mn2+离子的径向波函数为基础,通过引入电子云延伸效应系数κ来修正这一径向波函数,得到了稀磁半导体Zn1-xMnxTe晶体中Mn2+离子的径向波函数.以此波函数为基础,研究了Zn1-xMnxTe晶体吸收光谱的高压谱移特性,并且得到了吸收谱中四条谱线随压力的红移规律. 相似文献
86.
The reaction of a new fluorinated unsymmetrical allenylazine with dimethyl acetylenedicarboxylate and phenylacetylene affords the combined intra-intermolecular criss-cross cycloaddition products, 2,3-disubstituted-1,10-diazatricyclo[5.2.1.04,10]deca-2,6-diene derivatives. The products contain three fused five-membered rings with two nitrogen atoms within an unsaturated heterocyclic system. The structures were assigned using 2D NMR correlations and in the case of the phenylacetylene adduct by X-ray structure analysis. 相似文献
87.
The problem of generating a matrix A with specified eigen‐pair, where A is a symmetric and anti‐persymmetric matrix, is presented. An existence theorem is given and proved. A general expression of such a matrix is provided. We denote the set of such matrices by ??????En. The optimal approximation problem associated with ??????En is discussed, that is: to find the nearest matrix to a given matrix A* by A∈??????En. The existence and uniqueness of the optimal approximation problem is proved and the expression is provided for this nearest matrix. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
88.
Ewa Stró?yna 《Journal of Differential Equations》2003,193(1):239-259
We solve completely the problem of classification of germs of complex planar vector fields with nilpotent singularity with respect to formal orbital equivalence. 相似文献
89.
Parameters of Gaussian multivariate models are often estimated using the maximum likelihood approach. In spite of its merits, this methodology is not practical when the sample size is very large, as, for example, in the case of massive georeferenced data sets. In this paper, we study the asymptotic properties of the estimators that minimize three alternatives to the likelihood function, designed to increase the computational efficiency. This is achieved by applying the information sandwich technique to expansions of the pseudo-likelihood functions as quadratic forms of independent normal random variables. Theoretical calculations are given for a first-order autoregressive time series and then extended to a two-dimensional autoregressive process on a lattice. We compare the efficiency of the three estimators to that of the maximum likelihood estimator as well as among themselves, using numerical calculations of the theoretical results and simulations. 相似文献
90.
In this paper, by using elementary analysis, we establish some new Lyapunov-type inequalities for nonlinear systems of differential equations, special cases of which contain the well-known equations such as Emden-Fowler-type and half-linear equations. The inequalities obtained here can be used as handy tools in the study of qualitative behaviour of solutions of the associated equations. 相似文献