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851.
Zhao J Tian S Wang Q Liu X Jiang S Ji X An L Jiang B 《The European physical journal. E, Soft matter》2005,16(1):49-56
The surface topography of thin diblock copolymer films is studied by atomic
force microscopy (AFM). With AFM an island-to-ribbon transition is observed
for symmetric polystyrene-b-poly (4-vinylpyridine) (PS-b-P4VP) on mica with
increasing solution concentration. Our study also demonstrates how the
formation of the pattern strongly depends on the copolymer composition based
on the volume fraction. The substrate and solvent used both have great
effects on the morphology of the thin films. Only by using highly polar
substrate (mica), can we gain regular pattern. The reason why the regular
islands cannot be obtained with symmetric PS-b-P4VP on graphite is also
explained. On mica using nonselective and selective solvents, a rather
regular pattern can be obtained. The difference is only in the solution
concentration for forming regular patterns. 相似文献
852.
Le Foulon FX Braud E Fabis F Lancelot JC Rault S 《Journal of combinatorial chemistry》2005,7(2):253-257
A 1140-library of thiophene ureidoacids was synthesized by the reaction of a set of 60 primary or secondary amines with a number of 19 thieno[3,2-d]- or thieno[2,3-d][1,3]oxazine-2,4-diones. All compounds were obtained by a simple solution-phase combinatorial strategy on a 200-400-mg scale with over 70% yields and purities over 80%. Sixty library members chosen at random were successfully characterized by standard 1H NMR, HPLC/MS, and IR studies. Analgesic, antalgic, and antiinflammatory potential were investigated. The 1140-member ureidothiophene carboxylic acid library will be used in high-throughput screening assays. 相似文献
853.
Trzaskowski B Leonarski F Leś A Adamowicz L 《The journal of physical chemistry. B》2005,109(37):17734-17742
A theoretical study of protein docking to self-assembled monolayers using a new approach is presented. Docking experiments based on space complementarity implemented in FTDock software were performed for three different proteins: tubulin dimer, cytochrome c, and lysozyme. The proteins were adsorbed on alkanethiol surfaces with different terminating groups and 50,000 best orientations of each protein were analyzed. For all systems three filters based on different chemical and biological approaches were applied. Correctly docked proteins for the cytochrome c and lysozyme systems were found in a list of the first 12 results after applying the geometrical and grouping filter and in a list of the first 3 results after applying the biological filter. We have found that alkanethiol monolayers with odd and even numbers of -CH2- groups have similar properties in terms of interactions with the two proteins. Docking of the tubulin dimer revealed that the orientation favored from the applicational point of view can be found in a list of the first 14 results for monolayers with different terminating groups and that there may be a noticeable difference in tubulin dimer interactions with alkanethiol chains of various length. The results for tubulin dimer docking combined with microtubules ability of reversible assembly suggest that these biological structures may become good candidates to serve as templates for fabrication of nanowires and other nanoscale electronic devices. The new method of theoretical docking presented may be used as a fast and reliable tool complementing other theoretical and experimental techniques of exploring other protein-surface interfaces. 相似文献
854.
Patrick Le Barz 《Comptes Rendus Mathematique》2005,340(10):743-746
We give a general new algorithm to find formulas for the number of k-secant d-planes to a smooth curve in , for any k, d, N. Partial results were given by Castelnuovo [Rend. Palermo 3 (1889) 27–37] and Tanturri [Ann. Mat. 4 (1900) 67–122]. See also E. Arbarello et al. [Geometry of Algebraic Curves, vol. 1, Grundlehren Math. Wiss., vol. 267, Springer-Verlag, 1985]. To cite this article: P. Le Barz, C. R. Acad. Sci. Paris, Ser. I 340 (2005). 相似文献
855.
Glinec Y Faure J Dain LL Darbon S Hosokai T Santos JJ Lefebvre E Rousseau JP Burgy F Mercier B Malka V 《Physical review letters》2005,94(2):025003
An electron beam from a laser-plasma accelerator is converted into a gamma-ray source using bremsstrahlung radiation in a dense material. The gamma-ray beam has a pointlike source size because it is generated by a high quality electron beam with a small source size and a low divergence. Using this gamma-ray source, the radiography of complex and dense objects with submillimeter resolution is performed. It is the first evidence of a gamma-ray source size of a few hundreds micrometers produced with laser-driven accelerators. This size is consistent with results from Monte Carlo simulations. 相似文献
856.
Current optical interferometers are affected by unknown turbulent phases on each telescope. We account for this lack of phase information by introducing system aberration parameters, and we solve the image reconstruction problem by minimizing an original joint criterion in the aberrations and in the object. We validate this method by means of simulations. Tests on experimental data are under way. 相似文献
857.
We present a numerical method capable of reproducing the densification process from the so-called random loose to dense packing of uniform spheres under vertical vibration. The effects of vibration amplitude and frequency are quantified, and the random close packing is shown to be achieved only if both parameters are properly controlled. Two densification mechanisms are identified: pushing filling by which the contact between spheres is maintained and jumping filling by which the contact between particles is periodically broken. In general, pushing filling occurs when the vibration intensity is low and jumping filling becomes dominant when the vibration intensity is high. 相似文献
858.
Le Bolloc'h D Ravy S Dumas J Marcus J Livet F Detlefs C Yakhou F Paolasini L 《Physical review letters》2005,95(11):116401
Coherent x-ray diffraction experiments have been performed on high quality crystals of the charge density wave (CDW) system K0.3MoO3. The satellite reflections associated with the CDW have been measured as a function of the 20-microm-diameter beam position. For some positions, regular fringes have been observed. We show that this observation is consistent with the presence of a single CDW dislocation. Beyond charge density wave systems, this experiment shows that coherent x-ray diffraction is a suitable tool to probe topological defects embedded in the bulk. 相似文献
859.
We show how the low-frequency dependence of the proton spin-lattice relaxation time T1(nu) of octylcyanobiphenyl liquid crystals confined in high-density silica gels evidences a long-range order nematic phase in spite of the strong confinement and random disorder of the gels. The universal value and frequency dependence observed, T1(nu) proportional, variant nu(2/3), is interpreted within a relaxation model due to director fluctuations in nematic liquid crystals confined to mass fractal porous media. The model provides a relation T1(nu) proportional, variant nu(2-d/2), giving a reliable value of the structural fractal dimension d(f)=2.67 for all the host silica gels. 相似文献
860.
The cyclization of 1,3-bis-silyl enol ethers or (2,4-dioxobutylidene)triphenylphosphoranes with phthalic dialdehyde allowed a convenient synthesis of a variety of 4,5-benzotropones. The hydrogenation of benzotropones afforded functionalized benzocycloheptanones which were transformed into tricyclic butenolides. 相似文献