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131.
Klaus Tauer Hugo F. Hernández Steffen Kozempel Olga Lazareva Pantea Nazaran 《Macromolecular Symposia》2007,259(1):253-263
Summary: New experimental investigations of the 'classical' batch ab-initio emulsion polymerization of styrene reveal the important role of monomer droplets for the whole process. Monomer droplets with a size between a few and some hundreds of nanometers, which are formed by spontaneous emulsification as soon as styrene and water are brought into contact, have a strong influence on the particle nucleation, the particle morphology, and the swelling of the particles. Experimental results confirm that micelles of low molecular weight surfactants are not a major locus of particle nucleation. Brownian dynamics simulations show that the capture of matter by the particles (monomer or radicals) strongly depends on the polymer volume fraction and the size of the captured species (primary free radicals, oligomers, single monomer molecules, or clusters). 相似文献
132.
I. M. Lyapkalo M. I. Lazareva A. D. Dil'man S. L. Ioffe W. A. Smit 《Russian Chemical Bulletin》1999,48(3):488-494
Trimethylsilyl and DBU nitronates derived from nitromethane and nitropropanes do not undergoC-alkylation by episulfonium (ESI) or thiophanium (TPI) cationic intermediates. The above-mentioned derivatives of 1-nitropropane
react with ESI and TPI to give the corresponding products ofO-alkylation of 1-chloro-1-oxyiminopropane. The reactions of DBU nitronates derived from nitromethane and 2-nitropropane with
ESI or TPI proceed asO-alkylation followed by standard fragmentation of the initially formed nitronate intermediates to give methyl (4-tolylthio)acetate
or methyl 2,2-dimethyl-3-methyloxy-(4-tolylthio)butanoate respectively.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 492–498, March, 1999. 相似文献
133.
M. G. Voronkov N. F. Lazareva G. G. Efremova V. P. Baryshok 《Russian Chemical Bulletin》1995,44(2):375-377
The reactions of aminoalkylethoxysilanes and 2,2-dimethyl-1,3-dioxa-6-aza-2-silacyclooctane with 2-(chlormethyl)thiophene and its 5-chloroderivative lead to the correspondingN-(2-thenyl) derivatives. TheN-methyl-N-(2-thenyl)aminomethyltriethoxysilane and 5-chlorothyenyl derivative formed are converted by triethanolamine into silatranes.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 384–386, February, 1995. 相似文献
134.
135.
Yu. N. Lazareva M. N. Vidyakin A. Yu. Alentiev M. Yu. Yablokova A. A. Kuznetsov I. A. Ronova 《Polymer Science Series A》2009,51(10):1068-1074
Gas-separating membrane characteristics of polyimide films composed of the common fragment of benzophenone-3,3′,4,4′-tetracarboxylic
dianhydride and diamines of varying structure were studied. Permeability coefficient P, diffusion coefficient D, and solubility coefficient S for H2, CO, CO2, and CH4 were determined. The polyimide derived from m-phenylenediamine exhibited the best gas-separating properties. A relationship between the chain rigidity, free volume, and
transport parameters (P, D, S, and selectivity) of polyimide was established on the basis of the data. It was shown that there is an optimal chain rigidity
for the studied polyimides that results in polymer structurization during film preparation and corresponds to high separation
selectivity. 相似文献
136.
N. F. Lazareva 《Russian Chemical Bulletin》2011,60(4):615-632
The data on biological activity of the compounds with the geminal fragment N-C-Si are systematized. The examples of using
N-(silylmethyl)amines and related compounds in syntheses of biologically active substances, including natural compounds, are
considered. 相似文献
137.
138.
139.
V. I. Zherebchevsky I. E. Alekseev K. A. Gridnev E. B. Krymov T. V. Lazareva N. A. Maltsev R. B. Panin N. A. Prokofyev S. Yu. Torilov A. I. Shtamburg 《Bulletin of the Russian Academy of Sciences: Physics》2016,80(8):888-893
Nuclear reactions using proton beams and tin targets are studied in order to obtain antimony radionuclides. A new target system that includes on-line monitoring of target heating is used. To determine the parameters of proton beams, experimental studies on nuclear reactions are performed using Ti, Cu and stainless steel targets. Using modern model approximations, cross sections are determined for the formation of radionuclides 119Sb and 117Sb in the investigated nuclear reactions. 相似文献
140.
Rheological and magneto-rheological properties of magnetite dispersions in transformer oil were studied as influenced by the concentration of a modifying solution of water-soluble polymers (polyvinyl alcohol and carboxymethyl cellulose) and by the magnetic field strength. 相似文献