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21.
[structure: see text] It is shown that the pK(a) values of strong neutral organic (super)bases in acetonitrile are well described by the density functional theory (DFT) employing the isodensity polarization continuum model (IPCM) for treating solvent-solute interactions. High pK(a) values are predicted for two model compounds, and their synthesis is strongly recommended. 相似文献
22.
Dmitar Zori? Du?an Lazar Ognjen Rudi? Miroslava Radeka Jonjaua Ranogajec Helena Hir?enberger 《Journal of Thermal Analysis and Calorimetry》2012,110(1):489-495
The article presents the results of physical and chemical properties of lightweight aggregates (LWA) obtained by the thermal treatments of raw composition based on fly ash, supplied by electric plants from Serbia. The production process of LWA consists of raw material preparation, plastic shaping?Cextrusion, granulation, and thermal treatment at three temperatures: 1100, 1150, and 1200?°C. The final firing temperature (T?=?1150?°C) is chosen based on the mechanical and physical properties of the designed aggregates. The particle-size distribution of the LWAs is unimodal (d????16?mm) while the density value varies from 0.98 to 1.99?g/cm3. The water absorption values are determined by use of two methods: 24?h of soaking in cold water and 5?h of boiling. The thermal conductivity of unbound, fired LWA particles is determined by measuring the amount of axially transferred heat in the stationary state. The obtained value of the LWA thermal conductivity (???=?0.0872?W/mK, T?=?1150?°C) is suitable for the production of structural concrete blocks with improved thermal insulating properties. Because of their high-porosity and -compressive strength values, the designed LWA could be used instead of the conventional aggregates in the production of concrete blocks. Consequently, a real valorization of the waste material such as fly ash in Serbia was established. 相似文献
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G. C. Boskovic A. R. Zarubica M. N. Kovacevic P. S. Putanov 《Journal of Thermal Analysis and Calorimetry》2008,91(3):849-854
Properties of two catalysts tailored in the laboratory conditions by sulfation of commercial Zr-hydroxide and Zr-hydroxide
of nitrate origin were compared with those of commercial SO4-Zr-hydroxide. Equally thermally treated samples in the temperature interval 500–700°C, and having the same amount of sulfur,
show different properties indicating memory effect of their solid parent materials. The catalyst obtained by sulfation of
commercial Zr-hydroxide differs in amount of residual sulfates upon calcination from other two catalysts. The instability
of sulfates in the previous case might be connected to the lowest surface area values of catalyst and the highest fraction
of monoclinic phase observed at all applied calcination temperatures. 相似文献
25.
α,α′-Bis(substituted benzylidene)cycloalkanones were efficiently prepared from cycloalkanones and benzaldehydes in water by using animal bone meal (ABM) or ABM modified as a catalyst. It is shown that ABM modified can be quantitatively recovered and be reused effectively for many times. A comparison of catalytic activity of these catalysts is discussed. 相似文献
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We study a coarsening process of one-dimensional cell complexes. We show that if cell boundaries move with velocities proportional to the difference in size of neighboring cells, then the average cell size grows at a prescribed exponential rate and the Poisson distribution is precisely invariant for the distribution of the whole process, rescaled in space by its average growth rate. We present numerical evidence toward the following universality conjecture: starting from any finite mean stationary renewal process, the system when rescaled by e ?2t converges to a Poisson point process. For a limited case, this makes precise what has been observed previously in experiments and simulations, and lays the foundation for a theory of universal asymptotic states of dynamical cell complexes. 相似文献
30.
A note on line forces in gradient elasticity 总被引:2,自引:1,他引:2
The theory of gradient elasticity is applied to line forces. Line forces acting on a point within the body and a concentrated normal force (Flamant problem) which acts on a half plane are studied. Closed analytical solutions which have a simple form are obtained for displacement fields of these forces. The gradient elasticity solutions are free from undesirable displacement singularities predicted by classical elasticity. 相似文献