Bifunctional compounds from reaction of alkoxy hydroperoxides with metal salts

Alkoxy hydroperoxides, obtained by ozonizing olefins in alcoholic solution, were treated with ferrous sulfate. C-C bond scission and radical formation was followed by dimerization of the radicals formed. Ozonides reacted similarly. Acyclic and cyclic olefins, including a cyclic enol ether, gave rise to a range of ,ω-disubstituted products in modest yields. By using ferric chloride, ω-chloro esters were obtained from the alkoxy hydroperoxides derived from olefinic esters.     

On Morita Equivalence of Partially Ordered Monoids

We show that there is one-to-one correspondence between certain algebraically and categorically defined subobjects, congruences and admissible preorders of S-posets. Using preservation properties of Pos-equivalence functors between Pos-categories we deduce that if S and T are Morita equivalent partially ordered monoids and F:Pos _S →Pos _T is a Pos-equivalence functor then an S-poset A _S and the T-poset F(A _S ) have isomorphic lattices of (regular, downwards closed) subobjects, congruences and admissible preorders. We also prove that if A _S has some flatness property then F(A _S ) has the same property.     

Coherent THz synchrotron radiation from a storage ring with high-frequency RF system

The generation of brilliant, stable, and broadband coherent synchrotron radiation (CSR) in electron storage rings depends strongly on ring rf system properties such as frequency and gap voltage. We have observed intense coherent radiation at frequencies approaching the THz regime produced by the MIT-Bates South Hall Ring, which employs a high-frequency S-band rf system. The measured CSR spectral intensity enhancement with 2 mA stored current was up to 10,000 times above background for wave numbers near 3 cm(-1). The measurements also uncovered strong beam instabilities that must be suppressed if such a very high rf frequency electron storage ring is to become a viable coherent THz source.     

NO Conversion by Dielectric Barrier Discharge and TiO2 Catalyst: Effect of Oxygen

Present study was carried out to investigate the conversion of NO by simultaneous action of the dielectric barrier discharge (DBD) and TiO₂ catalyst. NO conversion was recorded as a function of the input energy density by varying the percentage of NO and O₂. NO conversion efficiency increased at higher content of O₂. The presence of a TiO₂ coating inside the reactor resulted in initially enhanced NO conversion but in few minutes the positive effect of TiO₂ diminished. The increased conversion of NO in initial stage of the process was more pronounced at higher densities of input energy (higher than 100 J/l) and at lower O₂ concentrations, but without O₂ the TiO₂ coating had no effect on the conversion of NO. The results indicate that the conversion of NO during first few minutes is related to the surface reactions with adsorbed atomic oxygen.     

How itinerant are 3d electrons in transition metals? A study of magnetic circular dichroism in 2p photoemission

We show how the spectral structure of the magnetic circular dichroism (MCD) in photoemission (PE) can be analysed using a sum rule for the sublevel orbital moment. For itinerant 3d metals, such as Co, Fe and Ni, the MCD in the 2p PE does not agree with a single-particle model. On the other hand, a final-state impurity model calculation gives an excellent agreement with the experimental results for the Ni 2p PE of nickel metal. This indicates that inter-configurational mixing must be taken into account to understand the detailed MCD structure in metallic systems. Vice versa, MCD-PE can help to explain the complicated behavior of electrons in correlated materials. Received: 23 May 2001 / Accepted: 4 July 2001 / Published online: 5 October 2001     

Finding Quantitative Trait Loci Genes with Collaborative Targeted Maximum Likelihood Learning

Quantitative trait loci mapping is focused on identifying the positions and effect of genes underlying an observed trait. We present a collaborative targeted maximum likelihood estimator in a semi-parametric model using a newly proposed 2-part super learning algorithm to find quantitative trait loci genes in listeria data. Results are compared to the parametric composite interval mapping approach.     

Identification of different electron screening behavior between the bulk and surface of (Ga,Mn)As

We report x-ray photoemission spectroscopy results on (Ga,Mn)As films as a function of both temperature and Mn doping. Analysis of Mn 2p core level spectra reveals the presence of a distinct electronic screening channel in the bulk, hitherto undetected in more surface sensitive analysis. Comparison with model calculations identifies the character of the Mn 3d electronic states and clarifies the role, and the difference between surface and bulk, of hybridization in mediating the ferromagnetic coupling in (Ga,Mn)As.     

Magnetic linear dichroism in the angular dependence of core-level photoemission from (Ga,Mn)As using hard x rays

We report a study of the electronic properties of the ferromagnetic semiconductor (Ga,Mn)As using magnetic linear dichroism in the angular dependence of Mn 2p photoemission under hard x-ray excitation. Bulk plasmon loss satellites demonstrate that the probed Mn ions are incorporated deep within the GaAs lattice, while the observed large dichroism indicates that the spectra originate from ferromagnetic substitutional Mn. Simulations of the spectra using an Anderson impurity model show that the ferromagnetic Mn 3d electrons of substitutional Mn in (Ga,Mn)As are intermediate between localized and delocalized.     

Flipper: A new instrument for xmcd at the srs

We propose to build at SOLEIL a facility for the accurate measurement of the properties of optical elements and detectors from the extreme ultraviolet (EUV), soft X-ray spectral regions up to the hard X-rays. The beamline will serve as a standard for such measurements and hence we call it a calibration and standards beamline, or alternatively, a metrology beamline. This beamline will also be valuable as a general-purpose beamline to prepare, test and set up a wide range of experiments. A complementary important aspect of this installation is the realization of a primary standard (as in BESSY II) [1 Ulm, G. 2003. Radiometry with synchrotron radiation. Metrologia, 40: S101–S106. [Crossref], [Web of Science ®] , [Google Scholar]]: in this case, the metrology beamline of SOLEIL could become the national primary standard source in collaboration with the Laboratoire National d'Essais (LNE) partner of this project. In another field, this installation will be used in the design and characterization of several diagnostics for the Megajoule Laser in Bordeaux in collaboration with the CEA DIF, also a partner of this project.