Er,Yb：(LaLu)2O3透明陶瓷制备及上转换发光性能

采用柠檬酸燃烧法制备Er,Yb：（LaLu）₂O₃陶瓷粉体,用X射线衍射对其进行了物相鉴定,研究表明1 000℃时已经得到纯相的（LaLu）₂O₃。采用冷等静压-真空烧结法制备了Er,Yb：（LaLu）₂O₃和Er：（LaLu）₂O₃陶瓷,对陶瓷的结构和光谱性能进行了详细的研究,研究发现掺杂5% Yb³⁺和10% La³⁺样品的上转换发光强度与未掺Yb³⁺、La³⁺样品相比明显增大,根据上转换光谱显示较强发射峰位于564 nm和661 nm处,对应Er³⁺的⁴S_3/2（²H_11/2）→⁴I_15/2能级跃迁和⁴F_9/2→⁴I_15/2能级跃迁,并讨论了Er³⁺-Yb³⁺的能量传递过程及其上转换发光机制。     

Determination of the time resolution for neutron scintillation detectors by multi-coincidence measurement

Based on the multi-coincidence measurement, the time resolution of three liquid scintillation detectors (BC501A) were determined strictly by solving the coincidence equations, where the influence from electronics estimated by self coincidence measurement as well as the background had been considered. The result of this work agreed well with the result that was deduced from the traditional method, and it will be helpful to analyze the energy resolution of neutron time of flight spectra measured by using such detectors at CIAE (China Institute of Atomic Energy).     

The relationship between acoustic radiation modes and structural modes and its applications

Both acoustic radiation modes and structural modes play an important role in the field of structure-borne sound, however, little work has been done for inherent relations between these two kinds of modes. This paper is focused on the relationship between the radiation modes and structural modes and its physical mechanisms. First, a governing equation for relating the radiation mode and structural mode is given based on the characteristics of the modes. Then, using the symmetric or anti-symmetric properties of two kinds of modes, the corresponding relations are presented. And then, numerical examples are given to verify the theoretical investigations, and it has been shown that, for a simply supported rectangular panel vibrating at low frequencies, the first radiation mode is dominant corresponding to (odd, odd) structural modes; the following radiation modes are respectively dominant corresponding to (even, odd), (odd, even), and (even, even) structural modes. Finally, such relations are applied to active acoustic structural control and provide a direct help for the design of active control strategy and arrangement of the secondary forces.     

Blind estimation of shallow water acoustic channel

This paper proposed a method for blind estimation of underwater channels in shallow water environment by using received data at a single hydrophone or from single beam. First,the received signal is used for source signal reconstruction by means of signal-dependent TF(Time-Frequency)distribution,in association with instantaneous frequency estimation and TF inversion.Then the shallow-water channel estimation is achieved via WRELAX technique by use of the received signal and the estimated source signal.Finally,the results of numerical simulation and experimental test from real data taken in South China Sea trial have proved satisfactory.It is shown that the proposed method is useful for underwater channel estimation.     

流动注射原子吸收光谱法测定大白口蘑中的微量硒

探讨了流动注射氢化物发生-原子吸收光谱法测定微量硒时的最佳条件,建立了大白口蘑(Tricholoma giganteum Massee)中微量硒的流动注射氢化物发生-原子吸收光谱分析方法。本法操作简便、快速,灵敏度高,测定硒的线性范围为0～50μg·L-1,相对标准偏差小于3%,加标回收率为96%～105%。应用于大白口蘑样品中微量硒的测定,获得满意结果。     

宽视场长焦距离轴三反射镜光学系统的设计

分析了离轴三反射镜系统成像特性．根据共轴三反射镜光学系统像差理论，确定结构参数的基本计算公式．设计了长焦宽视场的离轴三反射镜光学系统，分析了系统结构参量对像差的影响．结果表明，该系统视角较大，地面复益范围较宽，成像质量接近衍射极限．     

片状h-CN化合物的高温高压化学合成与表征

 以高温烧结三聚氰胺制得的CNH化合物为C、N源，与分析纯单质硼粉以一定比例混合，在5.0～5.5 GPa、1 400~1 500 ℃高温高压条件下，经化学反应合成了六角硼碳氮（h-BCN）晶体。用傅立叶变换红外光谱（FTIR）和X射线光电子能谱（XPS）对产物进行了表征，结果表明，得到了含碳量较高的六方结构B_0.18C_0.66N_0.16化合物，成分接近于BC₄N，硼、碳、氮是以原子化合的形式存在；XRD分析确定该合成产物具有六角网状结构；SEM测量结果表明，B-C-N晶体具有片状六角形貌，尺寸在1 μm左右。     

基于Fisher判别分析的有监督特征提取和星系光谱分类

随着天文观测技术的进步、数据获取能力的提高和大型光谱巡天计划的相继实施,光谱数据的自动处理研究越来越受到重视和关注。文章在分析了文献中光谱自动分类研究的特点和无监督特征提取方法所固有的一些不足的基础上指出了光谱有监督特征提取研究的必要性。并重点研究了Fisher判别分析(FDA)有监督特征提取方法在星系光谱自动分类中的应用。该方法： (1) 具有突出的维数约减能力; (2) 能有效地融合训练数据的类别信息,并按照分类能力提取特征。实验表明,将FDA方法用于某些星系细分类不仅明显地提高了分类器的速度,而且具有良好的分类性能。因此,对于较大的光谱识别系统更能体现出该方法的优越性。     

丙酮CO键在溶剂中频移变化的几种理论模型比较

测量了丙酮在16种溶剂中CO键的伸缩振动拉曼光谱,并且在Gaussian03程序下采用自恰反应场方法(SCRF)对丙酮在各种溶剂中的拉曼光谱进行了理论计算。用三种溶剂模型的电子给体-受体模型、Kirkwood模型和自恰反应场模型对实验结果进行了分析比较,结果表明Gutmann提出的电子给体-受体模型与实验结果符合的最好,而自恰反应场理论结果要好于Kirkwood模型。通过对三种模型的机理进行分析,得出给体-受体模型在解释电负性比较强的分子键振动光谱比较好,自恰反应场模型不但考虑了介电常数ε,而且考虑了分子大小、构型等因素的影响,模型复杂,计算量比较大,但是因为考虑的因素比较多,所以与实验结果也符合的比较好,而Kirkwood模型的主要参数为ε,模型简单,计算简便,能大致反映频移的趋势,说明介电常数是影响频移的一个主要因素。