GC-MS分析氧化亚铁硫杆菌培养液的挥发性成分

GC- MS联用技术对耐强辐射微生物氧化亚铁硫杆菌 [Thiobacillus ferroxidans(T.f) ]的挥发性代谢产物进行了研究 ,发现 4 3种代谢物 ,由标准谱图鉴定了其中 2 3种化合物。     

吸气式高超声速飞行器气动力气动热的数值模拟方法及应用

对吸气式高超声速飞行器而言,物面热流和摩阻的准确预测对飞行器设计及安全十分关键.介绍采用CFD准确预测气动力和气动热的方法,包括流动的控制方程、湍流模型及湍流的先进壁面函数边界条件,介绍流动的数值求解方法.对典型超声速层流和湍流流动的摩擦阻力和热流进行详细的验证与确认,考察CFD工具在使用先进壁面函数边界条件后,湍流计算的法向网格无关性能力.对设计的一种吸气式高超声速飞行器的气动力和气动热进行数值模拟,为飞行器的气动设计及热防护提供了可靠的数据.     

Tm3+掺杂Ge-Ga-Se玻璃中红外发光特性与多声子弛豫分析

用熔融急冷法制备了系列不同Tm3+掺杂浓度的Ge30Ga5Se65玻璃样品,测试了样品折射率、拉曼光谱、吸收光谱以及800nm激光泵浦下的近红外及中红外波段荧光光谱和荧光寿命。用Judd-Ofelt理论计算了Tm3+在Ge30Ga5Se65玻璃中的强度参数Ωi(i=2,4,6)、自发辐射跃迁概率A、荧光分支比β和辐射寿命τrad等光谱参数。讨论了800nm激光泵浦下掺杂1Wt%Tm3+样品在近红外1.23,1.48和1.8μm处的发光特性及各量子效率,研究了800nm激光泵浦下的样品中红外荧光特性与掺杂浓度之间的关系,计算了常温下该基质玻璃中Tm3+:3H5→3F4跃迁对于3.8μm处的多声子弛豫速率Wmp和Ge30Ga5Se65玻璃基质中多声子弛豫常数W(0)和电子-声子结合常数α值。结果表明Ge30Ga5Se65硒基玻璃较低的声子能量可以大大降低稀土离子能级间跃迁的多声子弛豫概率,从而提高中红外荧光发光效率,因此硒基玻璃作为稀土离子的掺杂基质材料对实现中红外荧光输出是非常有利的。     

非晶态(Fe1-xWx)84.5B15.5合金的低温电阻率反常

研究了(Fe_1-xW_x)_84.5B_15.5(x=0—0.1)非晶态合金的电阻率ρ与温度T(4.2—300K)的关系。实验结果表明,在所研究浓度区域内均出现电阻率与温度关系的极小值,电阻率极小值的温度T_min在x=0.06时出现峰值。用x=0.02—0.1浓度区域内,当Tmin时,又出现了电阻率与温度关系的极大值,电阻率极大值的温度T_max在26—35K之间。低温电阻率反常现象与类Kondo效应及局域磁矩之间RKKY相互作用有关。 关键词：     

Synthesis, Characterization, Crystal Structure and Stability of a Ternary Cu（Ⅱ） complex with 1, 10-Phenanthroline and L-Valinate

It is important to research the mixed-ligand copper complexes containing bioligands, such as amino acids, nucleic acids and proteins, in exploring the functional mechanism of microelement copper in organism because the reaction of any micronutrient with two or more bioligands in the concentrated bioligands background gives mixed-ligand ternary complexes, which are more stable and related with storage of substance and transportationof metal ions in the life process.     

EESI-MS监测ZrOCl2·8H2O催化的Paal-Knorr反应

用电喷雾萃取电离质谱（EESI-MS）离线监测甲醇中,ZrOCl₂·8H₂O催化的苯胺和2,5-己二酮的Paal-Knorr反应,检测到中间体m/z 204和m/z 208,产物m/z 172和产物二聚体m/z 343的准分子离子信号,并对其进行了结构分析。     

DAIP改性环氧树脂研究

采用共固化的方法,得到酚醛环氧树脂(F-51)和间苯二甲酸二烯丙基酯(DAIP)的共固化树脂。实验结果表明:DAIP的加入降低了F-51环氧树脂的粘度[体系粘度为150～350mPa·s(25℃)],利于工艺操作;提高了F-51环氧树脂的耐热性,热变形温度达200℃。研究了F-51环氧树脂和DAIP共固化的固化行为、不同配比对共固化物形态结构的影响;并研究了不同配比对固化物耐热性的影响。     

Organic Reactions in Ionic Liquids： An Efficient Method for the Synthesis of Phenacyl Esters by Reaction of Carboxylic Acids with α-Bromoacetophenone Promoted by Potassium Fluoride

An efficient method is reported for the synthesis of phenacyl esters by reaction of carboxylic acids with a-bromoacetophenone promoted by potassium fluoride in ionic liquid [Bmim]PF6, the yield of the reaction is almost quantitative and the products are essentially pure.     

1,10-邻菲咯啉-铜(Ⅱ)-L-蛋氨酸配合物的合成、表征及其分子结构

The complex [Cu(L-met)(phen)(H₂O)]NO₃·H₂O has been synthesized and investigated by elemental analysis, molar conductivity, spectroscopic and X-ray diffraction methods, where phen=1,10-phenanthroline and L-met=L-methioninate group. The complex crystallized in the monoclinic space group P2₁ with a=12.053(2)?, b=6.886(1)?, c=13.385(3)?, β=113.59(3)°, V=1018.1(3)?³, Z=2,D_c=1.598g·cm^-3, μ=1.223mm^-1, F(000)=506, R₁=0.0306, and wR₂=0.0742. The copper(Ⅱ) atom is ligated in a distorted square-pyramidal geometry by two nitrogen atoms of one phen and the amino nitrogen atom , one carboxylate oxygen atom of L-met in the base plane, and an aqua at the apical position. A one-dimensional chain configuration formed by the hydrogen-bonding and weak Cu-O (the uncoordinated carboxyl oxygen atom) coordination interactions be-tween neighboring [Cu(L-met)(phen)(H₂O)]⁺ cations. CCDC: 183368.     

Synthesis, molecular structure and intramolecular aromatic-ring stacking interaction of a novel binuclear Cu(Ⅱ) complex with 1, 10-phenanthroline and phenylacetate

The complex [Cu(phen)2(POAc)3]ClO·4H2O has been synthesized and investigated by elemental analysis, IR spec-troscopy and X-ray diffraction methods, where phen = 1,10-phenanthroline, POAc = phenylacetate group). The complex crystallizes in the triclinic space group PI with two molecules in a unit cell of dimensions a = 1.0579(2) nm, b = 1.2423(3) nm, c = 1.9190(4) nm, α = 71.84(1)°, β = 80.50(2)°, γ = 88.60(1)°, V = 2.3625(9) nm3, R = 0.0407 and Rw = 0.0656. The complex results from bridging of two Cu(phen)2 units by three carboxylate groups, and each Cu2 ion is in a distorted square pyramidal geometry with two nitrogen atoms of phen and three carboxylate oxygen atoms of POAc. It has been showed that intramolecular stacking interactions occur between the phenyl moieties of POAc and aromatic rings of phen, leading to a novel molecule structure with two coordinating modes of carboxylate ligands, of which two phenylacetates are μ2-carboxylate-O-bridging ligands, and the other is a μ2-carboxylate-