Condensed matter effects on nuclear fusion rates in laboratory and astrophysical environments

Previously overlooked condensed matter effects (CME) can significantly influence nuclear fusion rates in both laboratory and astrophysical environments. In dense plasmas, the ensemble of fusing particles has a significant exchange of kinetic and potential energies. Thus, there are diminished effective flux velocities resulting in a significant selective reduction of fusion rates. Our CME predictions are testable in laboratory experiments and have broad-ranging implications on the fusion rates for stellar media in general. By calculating reaction rates forp(p, e ⁺ v _e ) D and⁷Be(p, )⁸B in the sun, we show that CME help to solve the solar neutrino problem.     

Zirconocene-mediated route to enantiopure 9-oxabicyclononanes functionalized on both carbon bridges

[reaction: see text] A zirconocene-mediated ring contraction of 4-vinylfuranosides generated either from d-arabinose or d-glucose is followed by sequential oxidation to the ketone and alkynyl Grignard addition. The resulting cis-cyclobutanediols are subjected in turn to thermal rearrangement and intramolecular oxymercuration-demercuration. The regiochemistry of the final ring closure is controlled by the nature of R.