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21.
Donna C Arnold Olga Kazakova Guillaume Audoit Joseph M Tobin Jaideep S Kulkarni Sergey Nikitenko Michael A Morris Justin D Holmes 《Chemphyschem》2007,8(11):1694-1700
The synthesis of marokite CaMn(2)O(4) nanowires using a hydrothermal method is reported. Transmission electron microscopy and electron diffraction measurements show that the nanowires are polycrystalline in nature with diameters between 10 and 20 nm and lengths ranging from approximately 100 to 500 nm. Most interestingly, in contrast with the bulk material, magnetization measurements show that these nanowires exhibit ferromagnetic ordering with a Curie temperature (T(C)) of approximately 40 K. 相似文献
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R. K. Kulkarni D. E. Bartak F. Leonard 《Journal of polymer science. Part A, Polymer chemistry》1971,9(10):2977-2981
The polymerization of methyl 2-cyanoacrylate and heptyl 2-cyanoacrylate was carried out with the use of aqueous solutions of 14C-tagged glycine, methyl glycine, and acetyl glycine as initiators. When glycine and methyl glycine were used, radioactive polymers were formed. When acetyl glycine was used, the polymer formed was not radioactive. The data seem to indicate that free NH2 groups appear to be necessary for the incorporation of the glycine initiator in the polymer. A possible mechanism for the polymerization is presented. 相似文献
24.
B. K. Jha B. D. Kulkarni M. P. Vinod K. Vijayamohanan 《Chemical physics letters》1995,240(5-6):442-448
The electrochemical behavior of ferrocene in an aqueous microemulsion (pentan-1-ol/sodium dodecyl sulfate (SDS)/aq. H2SO4) has been studied using an ultramicroelectrode. Contrary to the generally expected reversible peak, the experiments show the presence of a second oxidation peak during the reverse scan at low scan rates where the peak corresponding to ferricinium ion reduction is nearly absent along with the unanticipated appearance of a current dip. These observations are rationalized using a novel type of coupling between heterogeneous (electrochemical) and homogeneous (chemical) electron transfer processes. The composition of the medium, especially the acid concentration, affects the electron transfer of the solubilized probe and there exists a threshold acid concentration for achieving maximum anodic peak current. 相似文献
25.
Comparative molecular similarity indices analysis (CoMSIA), a three-dimensional quantitative structure activity relationship (3D QSAR) paradigm, was used to examine the correlations between the calculated physicochemical properties and the in vitro activities (3'-processing and 3'-strand transfer inhibition) of a series of human immunodeficiency virus type 1 (HIV-1) integrase inhibitors. The training set consisted of 34 molecules from five structurally diverse classes: salicylpyrazolinones, dioxepinones, coumarins, quinones, and benzoic hydrazides. The data set was aligned using extrema of molecular electrostatic potentials (MEPs). The predictive ability of the resultant model was evaluated using a test set comprised of 7 molecules belonging to a different structural class of thiazepinediones. A CoMSIA model using an MEP-based alignment showed considerable internal as well external predictive ability (r2(cv) = 0.821, r2(pred) = 0.608 for 3'-processing; and r2(cv) = 0.759, r2(pred.) = 0.660 for 3'-strand transfer). 相似文献
26.
Kuriakose J Ghosh A Ravi Kumar V Kulkarni BD 《The Journal of chemical physics》2004,120(11):5432-5443
Heterogeneous surface reactions exhibiting complex spatiotemporal dynamics and patterns can be studied as processes involving reaction-diffusion mechanisms. In many realistic situations, the surface has fractal characteristics. This situation is studied by isometric graphing and multidimensional scaling (IGMDS) of fractal surfaces for extracting geodesic distances (i.e., shortest scaled distances that obtain edges of neighboring surface nodes and their interconnections) and the results obtained used to model effects of surface diffusion with nonlinear reactions. Further analysis of evolved spatiotemporal patterns may be carried out by IGMDS because high-dimensional snapshot data can be efficiently projected to a transformed subspace with reduced dimensions. Validation of the IGMDS methodology is carried out by comparing results with reduction capabilities of conventional principal component analysis for simple situations of reaction and diffusion on surfaces. The usefulness of the IGMDS methodology is shown for analysis of complex patterns formed on both regular and fractal surfaces, and using generic nonlinear reaction-diffusion systems following FitzHugh Nagumo and cubic reaction kinetics. The studies of these systems with nonlinear kinetics and noise show that effects of surface disorder due to fractality can become very relevant. The relevance is shown by studying properties of dynamical invariants in IGMDS component space, viz., the Lyapunov exponents and the KS entropy for interesting situations of spiral formation and turbulent patterns. 相似文献
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28.
S. Sivasanker S. G. Hegde S. V. Awate S. R. Padalkar S. B. Kulkarni 《Reaction Kinetics and Catalysis Letters》1988,36(1):173-176
The creation of strong acid sites in alkaline K-L-zeolites on ion-exchanging with La-ions is reported. Acidity measurements have been carried out by temperature programmed desorption of adsorbed ammonia. Reaction data which confirm the creation of acid sites are also reported.
- K-L La. - . , .相似文献
29.
S. Sampath N. K. Kulkarni N. C. Jayadevan 《Journal of Thermal Analysis and Calorimetry》1989,35(4):1089-1095
Thermal decomposition of metal uranyl acetates is one of the best ways of preparation of uranates in crystalline form at low temperatures. Acetates of the type M(UO2)2(OAc)6·7H2O (M=Zn(II), Mg(II) and Ni(II) were prepared and characterised. Their X-ray powder diffraction analysis showed that they all belong to the orthorhombic crystal class.The thermal decomposition of acetates in air goes through the reduction of uranium(VI) to uranium(IV) during acetate decomposition followed by reoxidation by oxygen. Zinc uranylacetate gave on thermal decomposition ZnU3O10, the nickel salt gave NiU3O10 and the magnesium salt gave a mixture of MgUO4 and MgU3O10. The thermal decomposition of acetates in helium led to reduction of uranium(VI) to uranium(IV) with the formation of UO2. No lower valent uranates could be identified.
The authors thank Dr. D. D. Sood, Head, Fuel Chemistry Division, for his encouragement during the course of this work. 相似文献
Zusammenfassung Thermische Zersetzung von Metalluranylazetaten ist eine der geeignetsten Methoden zur Darstellung kristalliner Uranate bei niedrigen Temperaturen. Azetate des Types M(UO2)2(OAc)6·7H2O mitM=Zn(II), Mg(II) und Ni(II) wurden hergestellt und beschrieben. Eine Pulverdiffraktionsanalyse zeigte, daß alle der orthorhombischen Kristallklasse angehören. Der thermische Zerfall der Azetate in Luft vollzieht sich während des Azetatzerfalls über die Reduktion von Uran(VI) zu Uran(IV) bis zu einer anschließenden Reoxydation durch Sauerstoff. Bei der thermischen Zersetzung liefert Zinkuranylazetat ZnU3O10, das Nickelsalz liefert NiU3O10 und das Magnesiumsalz ein Gemisch aus MgUO4 und MgU3O10. Der thermische Zerfall der Azetate in Helium führt zur Reduktion von Uran(VI) zu Uran(IV) unter Bildung von UO3. Uranate mit niedrigerer Wertigkeit konnten nicht identifiziert werden.
. M(UO2)2(OAc)6 · 7H2O, M = , . , . , . ZnU3O10, — NiU3O10, MgUO4 MgU3O10. . .
The authors thank Dr. D. D. Sood, Head, Fuel Chemistry Division, for his encouragement during the course of this work. 相似文献
30.
Milind V Kulkarni 《European Polymer Journal》2004,40(2):379-384
Polyaniline and poly(o-toluidine) doped with p-toluene sulphonic acid (p-TSA) were synthesized by in situ chemical polymerization method using ammonium per sulphate as an oxidizing agent. This is a novel polymerization process for the direct synthesis of emeraldine salt phase of the polymer. The polymers were characterized by using UV-Vis and FT-IR spectroscopy, SEM, elemental analyzer, TGA/DSC and conductivity measurements. Thermal analysis shows that poly(o-toluidine) is less thermally stable compared to polyaniline. The less conductivity in poly(o-toluidine) is due to the cumulative steric as well as electronic effect of the bulky methyl substituent present on the benzene ring. High temperature conductivity measurements show ‘thermal activated behavior’. 相似文献