Rietveld refinement, microstructure, conductivity and impedance properties of Ba[Zr0.25Ti0.75]O3 ceramic

In this work, we report the Rietveld refinement, microstructure, conductivity and impedance properties of Ba[Zr_0.25Ti_0.75]O₃ ceramic synthesized by solid state reaction. This ceramic was characterized by X-ray diffraction, Rietveld refinement, scanning electron microscopy and energy dispersive X-ray spectrometry. Impedance spectroscopy analyses reveals a non-Debye relaxation phenomenon being its relaxation frequency moving toward to positive side with increase of temperature. A significant shift in impedance loss peaks toward higher frequency side indicates conduction in material and favoring the long range motion of mobile charge carriers. The frequency dependent ac conductivity at different temperatures indicates that the conduction process is thermally activated. The variation of dc conductivity exhibited a negative temperature coefficient of resistance behavior. The ac conductivity data are used to evaluate the density of states at Fermi level and activation energy of this ceramic. The dc electrical and thermal conductivities of grain and grain boundary have been discussed.     

0+ analogue state in 118Sb from 117Sn(p,nγ) reaction

The analogue of the 0⁺ ground state in ¹¹⁸Sn has been observed in the compound nucleus ¹¹⁸Sb through ¹¹⁷Sn(p,n γ) ¹¹⁷Sb reaction. The neutron decays of this analogue resonance have been studied from the deexciting γ-rays of the residual nucleus ¹¹⁷Sb. From off resonance excitation functions, spin assignments have been made to states in ¹¹⁷Sb, on the basis of Hauser-Feshbach formalism. The resonance parameters of the isobaric analogue resonance have been determined, including the total, proton and neutron decay widths.     

An investigation of FeCoCrO4 by Mossbauer spectroscopy

The spinel FeCoCrO₄ has been studied between 4.2 and 538°K. Characteristic Mossbauer spectra of paramagnetic, magnetic and electronic relaxation types have been observed. The Mossbauer parameters for Fe³⁺ ions situated at tetrahedral (A) and octahedral (B) sites have been calculated. The cation distribution in magnetic and paramagnetic phases is found to be approximately Fe_0.5³⁺Co_0.5²⁺[Co_0.5²⁺Fe_0.5³⁺Cr³⁺]O₄. The Neel temperature been determined by the temperature scanning method to be 310±5°K.     

Studies in inorganic polyelectrolytes — Part II

Viscosity behaviour of several samples ofGraham's salt with varying molecular weight has been studied. Reduced viscosity (η _sp /c) versus concentration curves were found to be characteristic of polyelectrolytes. They are dependent on the molecular weight and can be reduced to straight lines by plotting the reciprocal of the reduced viscosity against the square root of concentration. The intrinsic viscosities obtained by extrapolation were found to be proportional to the square of molecular weights. The value of reduced viscosity at any particular concentration in the concentration range between 0.25% and 4.0% was linearly related to the molecular weight. Reduced viscosities were found to decrease considerably on addition of electrolytes. Reduced viscosity versus added salt concentration curves were remarkably molecular weight dependent. The p_H of the medium seemed to have no effect at all. Bivalent salts reduce the viscosity to a much greater extent than monovalent ones. By keeping the concentration of the added salt constant and varying that ofGraham's salt, curves showing hump which disappeared at higher concentration of the added salt, were obtained. In the action of electrolytes the more important factor is the valency of cation rather than the ionic strength of the medium. Most observations confirm the already well-establishedFolding-Chain Theory of polyelectrolytes developed byKatchalsky, Fuoss and others.     

A sum-over-histories account of an EPR(B) experiment

We analyze a variant of the EPRB experiment within a framework for quantum mechanics that rests on a radical interpretation of the sum over histories. Within this framework, reality is (just as classically) a single history, e.g. a definite collection of particles undergoing definite motions; and quantum dynamics appears as a kind of stochastic law of motion for that history, a law formulated in terms of non-classical probability-amplitudes. No state vectors enter this framework, and their attendant nonlocality is therefore absent as well.1. That is, before pair creations and annihilations were discovered. (The electronic and nuclear spins might also be regarded as new aspects of their kinematics. But perhaps spin is better construed, within the sum-over-histories framework, as a quality of a more dynamical character, namely as a generalized sort of probability-amplitude.)2. A possible escape would be the so-called Everett interpretation, in which the collapse never occurs, but its effects are supposed to be recovered via a more careful analysis of closed systems in which measurement-like processes take place. Among other things, this approach tends to lead either to the view that nothing really happens [1] or to the view that everything really happens [2] (which perhaps is not that different from the former view).3. For example, the rule, collapse occurs along the past light cone (in the Heisenberg picture), appears to be consistent.4. And Bell's inequality shows thatany theory formulated in terms of an instantaneous state evolving in time would encounter the same trouble. Indeed, the trouble shows up even more glaringly if one adapts Bell's argument to spin-1 systems, using the results of Kochen and Specker[10]. In order to use the Kochen-Specker results in the EPR manner one needs a scheme for measuring the relevant observables, but this can be accomplished by means of suitably concatenated Stern-Gerlach analyzers with recombining beams [13]. Then, as Allen Stairs has pointed out [14], even the perfect correlations become impossible to reproduce, and no reference to probability theory is needed to establish a contradiction with locality. Recently, an analogous experiment using three spin 1/2 particles instead of two spin 1 particles has also been given [15].5. No technical problem obstructs an extension to fermionic fields (indeed the functional integral formalism for Quantum Field Theory is probably the most popular at present), but the realistic interpretation of the individual histories seems to get lost. One way out would be if all fermions were composites or collective excitations of fields quantized according to bosonic commutation relations. Another would be if the particle formulation were taken as basic, with the complementary field formulation being merely a mathematical artifice (at least for fermions).6. In the approach of Gell-Mann-Hartle and Griffiths for example, only a small subset of the possible partitions is granted meaning, in such a way that all interference terms are suppressed and quantum probabilities reduce to classical ones.7. In stating these rules we consider an idealized situation in which the spatio-temporal indeterminacy of particle-locationwithin a given one of our trajectories is ignored; or if you prefer, you can take the experiment as only a Gedanken one affording a simplified illustration of how EPR-like correlations are understood within the sum-over-histories framework. In this connection recall also that the semiclassical propagator is in fact exact for a free particle.8. This can be interpreted either as part of the specification of the initial conditions, or (as suggested by a referee) merely as an example of relativization of probabilities.9. Thus a state vector may be defined as an equivalence-class of sets of partial histories.10. One such generalization applies to open systems, for example to a particle in contact with a heat reservoir. For this example see [11], wherein the two-way path formalism of §5 above is used, and the influence of the reservoir results in an effective dynamics for the particle in which the forward and backward portions of its world-line are coupled to each other by a certain interaction term in the amplitude. In this type of situation a density-operator (though not a state vector ) can still be introduced, but it no longer summarizes all the relevant information about the past (and correspondingly its evolution lacks the Markov property that(t + dt) is determined by(t) alone). For quantum gravity, it may be that not even such a non-Markov will be exactly definable, and only the global probabilities themselves will make sense.11. Ironically it is just this property of the amplitudes which, as mentioned above, makes possible the introduction of the state vectors whose collapse then introduces such a strong appearance ofnonlocality into the theory.     

Determination of the orientation of the electric field gradient at the Cu(1) site from the Mössbauer spectra of textured pellets made of YBa2Cu3O7−δ superconductor

A textured pellet of YBa₂Cu₃O_7?δ was prepared and doped with⁵⁷Co. After subsequent heat treatments the cobalt was found at the two copper sites. The degree of alignment of individual crystallites (about 40%) was determined from the Mössbauer spectrum by using a method developed by the authors [1]. The same method showed that the most characteristic doublet component of such spectra (δ=0.08 mm/s; |ΔE _Q|=1.96 mm/s) is associated with a site, most probably a Cu(1) site, where the EFG is parallel to thec direction of the unit cell. The sign ofV _zz turned out to be negative, giving a negative quadrupole splitting (ΔE _Q=?1.96 mm/s) for that component.     

Model for γγ→VV reactions near threshold

We propose a Veneziano-like model for VV reactions near threshold involving exchanges of 0^– trajectories int- andu-channels. The model is applied to , , , and processes. The model in its simplest form cannot account for the disparities in the cross sections for andK ^*+ K ^*– and for ⁰⁰ and ^+–. Further refinements of the model are suggested.     

Theoretical analysis of the multi-rotational line TEA CO2 laser

A theoretical model for the multiline TEA CO₂ laser has been developed which takes into account the overlap of the P(20) line of (00⁰1) (10⁰0) regular band transition with the R(23) line of (01¹1) (11¹0) hot band transition. The model is used for the study of the influence of different parameters like laser gas temperature, gas mixture and pump rates on laser intensities of different rotational lines. This study explains the experimental results of the high power multiline TEA CO₂ laser very well.