Simulation and analysis of turbulent MHD channel flow with a streamwise magnetic field

We perform large-eddy simulations of turbulent MHD channel flow with a streamwise magnetic field using a pseudo spectral method. The streamwise magnetic field leads to turbulent drag reduction due to the selective Joule damping of certain flow structures. Near the walls, the turbulent mean velocity profile retains the logarithmic layer but the von Karman constant decreases with increasing magnetic field strength. In the outer region, the flow is characterized by persistent streaky structures of large streamwise extent, which lead to a rather flat mean velocity profile. In addition, the streamwise velocity fluctuations develop a pronounced second peak upon increasing the magnetic induction as well as a second logarithmic layer that increases in steepness. We find that Prandtl's classical mixing-length model with a variable Kármán constant can describe the modified logarithmic layer reasonably accurately in a wide range of Reynolds and Hartmann numbers. However, the flow modification near the center of the channel is not properly captured by this approach. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Substituent effect on the stereoselectivity of acylation of racemic heterocyclic amines with N-phthaloyl-3-aryl-(S)-alanyl chlorides

The acylative kinetic resolution of racemic 2-methyl-1,2,3,4-tetrahydroquinoline and 2,3-dihydro-3-methyl-4H-1,4-benzoxazine using acyl chlorides of N-phthaloyl-(S)-phenylalanine, N-phthaloyl-3-(4-nitrophenyl)-(S)-alanine and N-phthaloyl-O-methyl-(S)-tyrosine as chiral resolving agents has been carried out. It is shown that the effectiveness of an acylative kinetic resolution depends on the electronic effects of substituents in the phenyl fragment of the acylating agent and increases as the electron-donating properties of the para-substituent (OMe > H > NO₂) in phenyl fragment of N-phthaloyl-3-aryl-(S)-alanyl chlorides increase; conducting the process at a reduced temperature also contributes to an enhancement of the kinetic resolution.     

Theoretical study of the influence of vacancies on the electronic structure of a hexagonal boron nitride monolayer

The influence of boron and nitrogen vacancies and divacancies on the electronic structure of a hexagonal boron nitride h-BN monolayer is studied. In the presence of vacancies in the structure, the introduced states appear in the forbidden band. The position of an introduced state with respect to the upper occupied level and the lower vacant level depends on deformation. Calculations show that, depending on the defect type and the magnitude of the applied deformation, the introduced state can be both localized and not localized on atoms surrounding the defect. When the state is localized in the system, the inhomogeneous distribution of the spin density is observed, resulting in the appearance of the magnetic moment in the system.     

ΔE-E detector for proton registration in nonmesonic deuteron breakup at the Nuclotron internal target

A design for a ΔE-E detector to investigate deuteron breakup in the Nuclotron-M internal target in a deuteron energy interval of 300–500 MeV is presented. The high-voltage power supply system of the PMT-63, which is based on the computer-controlled Wenzel Electronik module, is briefly described. A light-emitting diode (LED) monitoring system for the ΔE-E detector is considered. The results of testing the ΔE-E detector using cosmic muons and deuteron beams of the Nuclotron are presented.     

Investigation of the angular dependence of the analyzing powers in the deuteron-proton elastic scattering at the nuclotron

New polarimeter based on the asymmetry measurement in dp-elastic scattering has been constructed at internal target at Nuclotron (JINR). The result on the deuteron analyzing powers A _y , A _yy and A _xx in the deuteron-proton (dp) elastic scattering at the energies of 880 and 2000 MeV are presented. They are compared with different theoretical approaches.     

Experiments on the study of the deuteron-proton interactions at intermediate energies at Internal Target at Nuclotron

The experimental program on the study of deuteron-proton interaction at Internal Target at Nuclotron is discussed. Recent results obtained for dp-elastic scattering and dp-breakup reactions at intermediate energies are presented. The status of the DSS setup upgrade is reported.     

Synthesis of Pyrimidine Conjugates with 4-(6-Amino-hexanoyl)-7,8-difluoro-3,4-dihydro-3-methyl-2H-[1,4]benzoxazine and Evaluation of Their Antiviral Activity

A series of pyrimidine conjugates containing a fragment of racemic 7,8-difluoro-3,4-dihydro-3-methyl-2H-[1,4]benzoxazine and its (S)-enantiomer attached via a 6-aminohexanoyl fragment were synthesized by the reaction of nucleophilic substitution of chlorine in various chloropyrimidines. The structures of the synthesized compounds were confirmed by ¹H, ¹⁹F, and ¹³C NMR spectral data. Enantiomeric purity of optically active derivatives was confirmed by chiral HPLC. Antiviral evaluation of the synthesized compounds has shown that the replacement of purine with a pyrimidine fragment leads to a decrease in the anti-herpesvirus activity compared to the lead compound, purine conjugate. The studied compounds did not exhibit significant activity against influenza A (H1N1) virus.