A novel frequency encoded all optical logic gates exploiting polarization insesensitive four wave mixing in semiconductor optical amplifier, filtering property of ADD/DROP multiplexer and non-linearity of reflective semiconductor amplifier

All optical logic gates exploiting polarization independent four wave mixing in semiconductor optical amplifier (SOA), filtering property of ADD/DROP multiplexer (ADM) and non-linearity in reflective semiconductor optical amplifier (RSOA) have been proposed. The logic gates proposed are polarization independent which ensures hardware simplicity and greater speed. The all optical frequency encoded logic gates NOT, OR, NOR, AND, NAND, X-OR, X-NOR are implemented which are very useful in optical computing ad signal processing, cryptography, etc. The logic gates proposed have the advantages that there is no intensity loss dependent problem, and are polarization and temperature insensitive.     

Method of implementation of frequency encoded all optical half adder, half subtractor and full adder based on semiconductor optical amplifiers and add drop multiplexers

A novel frequency encoded all optical half adder, half subtractor and full adder are proposed. The implementation is ultrafast one and the frequency encoding makes it intensity loss dependent problem free. The use of polarization insensitive four-wave mixing makes the design polarization independent and the hardware simple. The frequency conversion by the reflective semiconductor optical amplifiers (RSOA) makes the design faster compared to other semiconductor optical amplifiers (SOA) based design.     

Enhancement of the Nuclear Spin Noise Signal Using Wavelet Transform

Spin noise spectroscopy has attracted considerable attention recently owing partly to intrinsic interest in the phenomenon and partly to its significant application potential. Here, we address the inherent problem of low sensitivity of nuclear spin noise and examine the utility of wavelet transform to mitigate this problem by distinguishing real peaks from the noise contaminated data. Suppression of the random circuit noise and the consequent enhancement of the correlated nuclear spin noise signal have been demonstrated with discrete wavelet transform. Spectra of both ¹H and ¹³C nuclear spins have been considered and significant signal enhancements in both the cases have been observed. A detailed analysis of several possible wavelet, thresholding and decomposition solutions have been made to obtain the optimum condition for signal enhancement. It is observed that the application of wavelet transform leaves the spin noise signal line shape essentially unchanged, which is an advantage for several applications involving spin noise spectra.     

A method of implementation of frequency encoded all optical encryption decryption using four wave mixing

All optical encryption decryption method using frequency encoding is proposed based on semiconductor optical amplifiers. The plain text and key are encoded in frequency encoding format i.e. the states of information ‘0’ and ‘1’ are represented by two different frequencies in the c-band. The ultra fast speed of operation of the devices used for the implementation of this system makes it very attractive for future all optical secure communication network. A simple method of conversion of frequency encoded data stream and intensity encoded data stream is also described, which enables us to use same technology of production and detection of intensity encoded data signals until new techniques based on frequency encoding comes out.     

Projected quasiparticle theory for molecular electronic structure

We derive and implement symmetry-projected Hartree-Fock-Bogoliubov (HFB) equations and apply them to the molecular electronic structure problem. All symmetries (particle number, spin, spatial, and complex conjugation) are deliberately broken and restored in a self-consistent variation-after-projection approach. We show that the resulting method yields a comprehensive black-box treatment of static correlations with effective one-electron (mean-field) computational cost. The ensuing wave function is of multireference character and permeates the entire Hilbert space of the problem. The energy expression is different from regular HFB theory but remains a functional of an independent quasiparticle density matrix. All reduced density matrices are expressible as an integration of transition density matrices over a gauge grid. We present several proof-of-principle examples demonstrating the compelling power of projected quasiparticle theory for quantum chemistry.     

A full-dimensional coupled-surface study of the photodissociation dynamics of ammonia using the multiconfiguration time-dependent Hartree method

Full-dimensional quantum mechanical computations are carried out to investigate the photodissociation dynamics of A? state NH(3) and ND(3) using the multiconfiguration time-dependent Hartree (MCTDH) method with recently developed coupled ab initio potential energy surfaces (PESs) [Z. H. Li, R. Valero, and D. G. Truhlar, Theor. Chim. Acc. 118, 9 (2007)]. To use the MCTDH method efficiently the PESs are represented as based on the high-dimensional model representation. The A? ← X? absorption spectra for both isotopomers were calculated for the zeroth vibrational state of the ground electronic state. With a view to treating larger systems, Jacobi coordinates are used. Computations on the coupled PES are carried out for two-, three-, five-, and six-dimensional model systems to understand the validity of reduced-dimensional calculations. In addition to the fully coupled calculations, the effect of nonadiabatic coupling on absorption spectra is shown by propagating the initial wavepacket only in the A? electronic state. The calculated absorption spectra are shown to be in good agreement with available theoretical and experimental observations. Comparisons with calculations using Radau and valence coordinates show the effect of including the symmetry of the system explicitly. Finally, branching ratios for loss of a hydrogen atom via the two available channels are calculated. These predict that the nonadiabatic product increases with the dimension of the calculations and confirm the importance of the full-dimensional calculations.     

A method of optical implementation of frequency encoded all optical logic gates based on multiphoton processes in non linear material

A novel frequency encoded all optical logic gates are proposed exploiting multiphoton processes in non linear optical medium. In the frequency encoding of the information the ‘0’ is represented by a frequency ω and ‘1’ is represented by another frequency 2ω. The gates proposed are NOT, OR, AND, NAND and NOR among which NAND and NOR are universal. Using these gates one can generate other important gates and logical function generating all optical devices. Two main three-photon processes, second harmonic generation (SHG) and parametric light generation (PLG) are used to implement the gates and the corresponding appropriate non linear material is LiB₃O₅ (LBO) which has wide operating and transparency range in the wavelength 350–3,200 nm. The source of optical frequency encoded signal may be derived from an external cavity diode laser generating a wavelength 1,560 nm for ω (‘0’ state of information) and its second harmonic 780 nm for 2ω (‘1’ state of information).     

A Scalable Chemical Approach for the Synthesis of a Highly Tolerant and Efficient Oil Absorbent

In the past, bio‐inspired extreme water repellent property has been strategically embedded on commercially available sponges for developing selective oil absorbents. However, most of the reported materials lack physical and chemical durability, limiting their applicability at practically harsh settings. Herein, a stable dispersion of polymeric nanocomplexes was exploited to achieve a chemically reactive coating on the highly compressible melamine foam. A superhydrophobic melamine foam (SMF) was achieved after post‐covalent modification of the reactive coating through 1,4‐conjugate addition reaction at ambient conditions. The durability of the embedded extreme water repellent property in the as‐modified melamine foam has been elaborately demonstrated through exposing it to severe physical manipulations, chemically harsh aqueous media including pH 1, pH 12, surfactant contaminated water, river water, seawater and prolonged UV irradiation. Thus, the highly tolerant SMF was utilized as an efficient oil absorbent wherein oils of varying densities could be selectively recovered from an oil/water interface with high (e.g., 137 g g^?1 for chloroform and 83 g g^?1 for diesel) oil absorption capacity. Moreover, the selective oil absorption capacity of the as‐synthesized material remained unaffected at practically relevant severe chemical and physical settings, and the extreme water repellency of the material remained unaltered even after repetitive (at least 50 cycles) use for oil/water separation.     

A readily prepared neutral heterobimetallic titanium(IV)-rhodium(I) catalyst for intramolecular hydroacylation

The combination of HOCMe2CH2PPh2, Ti(OiPr)4, and [Rh(cod)Cl]2 (3:1:1) in either benzene or dichloromethane produces a discrete species (tentatively formulated as complex) that is an active catalyst for intramolecular hydroacylation reactions of 3-substituted pentenals.