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41.
Kouichi Sugihara Hiroshi Kamiya Mieko Yamaguchi Takahiro Kaneda Soichi Misumi 《Tetrahedron letters》1981,22(17):1619-1622
Two quinones bridged with a polyether chain and the corresponding hydroquinones were synthesized, and their redox reaction and complexations with sodium and potassium ions were observed. 相似文献
42.
43.
[reaction: see text] Concise synthesis of defucogilvocarcin M was achieved via the [2 + 2 + 2] approach to beta-phenylnaphthalene structure. 相似文献
44.
Nakano H Takahashi K Okuyama Y Senoo C Tsugawa N Suzuki Y Fujita R Sasaki K Kabuto C 《The Journal of organic chemistry》2004,69(21):7092-7100
Cationic palladium (Pd)- and platinum (Pt)-phosphinooxazolidine catalysts 13a-c, 15a-d, 17a-c, and 19a-c were prepared from phosphinooxazolidine ligands 1-3, MCl(2) (M = Pd and Pt), and counterions, and the activities of the catalysts in the asymmetric Diels-Alder (DA) reactions of cyclic or acyclic dienes with imide dienophiles were investigated. These catalysts demonstrated high levels of catalytic activity. The cationic Pd-POZ complex 13c provided particularly excellent enantioselectivity (98% ee) in the DA reactions of cyclopentadiene with acryloyl-, crotonyl-, and fumaroyl-1,3-oxazolidin-2-ones (20a-c). 相似文献
45.
Some Geometry of the Cone of Nonnegative Definite Matrices and Weights of Associated X2 Distribution
Satoshi Kuriki Akimichi Takemura 《Annals of the Institute of Statistical Mathematics》2000,52(1):1-14
Consider the test problem about matrix normal mean M with the null hypothesis M = O against the alternative that M is nonnegative definite. In our previous paper (Kuriki (1993, Ann. Statist., 21, 1379–1384)), the null distribution of the likelihood ratio statistic has been given in the form of a finite mixture of 2 distributions referred to as X2 distribution. In this paper, we investigate differential-geometric structure such as second fundamental form and volume element of the boundary of the cone formed by real nonnegative definite matrices, and give a geometric derivation of this null distribution by virtue of the general theory on the X2 distribution for piecewise smooth convex cone alternatives developed by Takemura and Kuriki (1997, Ann. Statist., 25, 2368–2387). 相似文献
46.
It is known that the trigonometric Calogero–Sutherland model is obtained by the trigonometric limit (–1) of the elliptic Calogero–Moser model, where (1, ) is a basic period of the elliptic function. We show that for all square-integrable eigenstates and eigenvalues of the Hamiltonian of the Calogero–Sutherland model, if exp(2–1) is small enough then there exist square-integrable eigenstates and eigenvalues of the Hamiltonian of the elliptic Calogero–Moser model which converge to the ones of the Calogero–Sutherland model for the 2-particle and the coupling constant l is positive integer cases and the 3-particle and l=1 case. In other words, we justify the regular perturbation with respect to the parameter exp(2–1). With some assumptions, we show analogous results for N-particle and l is positive integer cases. 相似文献
47.
We have applied a time‐resolved means of measurement for studying living plants. The intake of mineral nutrients in a living plant such as stevia has been observed by this measuring instrument. A solution containing K, Ca, Mn, Fe, Cu, and Zn compounds was used as the mineral nutrient solution. The concentrations of the standard solutions were specifically chosen to obtain optimal intensities of the x‐ray peaks. The time dependence of the x‐ray fluorescence (XRF) intensity showed specific intake processes depending on the type of element. In addition, the experimental results suggest differences in the translocation of each element in the stevia stem. We conclude that time‐resolved XRF is a powerful technique for studying living plants. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
48.
Theoretical calculations of ESR parameters for aminoxyl radicals have been widely studied using the density functional theory (DFT) calculations. However, the isomer N‐alkoxyaminyl radicals have been limitedly studied. With the use of experimental data for 46 N‐alkoxyaminyl and 38 aminoxyl radicals, the isotropic 14N hyperfine coupling constants (aN) and g‐factors have been theoretically estimated by several DFT calculations. The best calculation scheme of aN for N‐alkoxyaminyl radicals was PCM/B3LYP/6‐31 + + G(d,p) (R2 = 0.9519, MAE = 0.034 mT), and that for aminoxyl radicals was PCM/BHandHLYP/6‐31 + + G(3df,3pd) (R2 = 0.9336, MAE = 0.057 mT). For aminoxyl radicals, the solvation models in calculations enhanced the accuracy of reproducibility. In contrast, for N‐alkoxyaminyl radicals the calculations with solvation models provided no improvement. The differences in the best functionals between two types of radicals were thought to come from the contribution ratios of neutral and dipolar canonical structures in resonance forms. The aN for N‐alkoxyaminyl radicals that were stabilized by small contribution of dipolar canonical structures could be precisely reproduced by B3LYP with only 20% HF exact exchange. In contrast, the aN for aminoxyl radicals stabilized by large contribution of dipolar canonical structures was well reproduced by BHandHLYP with 50% HF exchange. The best calculation scheme of g‐factors was IEFPCM/B3LYP/6‐31 + G(d,p) (R2 = 0.9767, MAE = 0.0001) for not only aminoxyl but also N‐alkoxyaminyl radicals. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
49.
We propose a perturbation method for determining the (largest) group of invariance of a toric ideal defined in [S. Aoki, A. Takemura, The largest group of invariance for Markov bases and toric ideals, J. Symbolic Comput. 43 (5) (2008) 342–358]. In the perturbation method, we investigate how a generic element in the row space of the configuration defining a toric ideal is mapped by a permutation of the indeterminates. Compared to the proof by Aoki and Takemura which was based on stabilizers of a subset of indeterminates, the perturbation method gives a much simpler proof of the group of invariance. In particular, we determine the group of invariance for a general hierarchical model of contingency tables in statistics, under the assumption that the numbers of the levels of the factors are generic. We prove that it is a wreath product indexed by a poset related to the intersection poset of the maximal interaction effects of the model. 相似文献
50.
Thermal properties of organoindium thiolates were investigated by means of thermogravimetric (TG) and differential thermal (DT) analysis. Dibutyl-indium propylthiolates (Bun2InSPrn, Bun2InSPri, Bui2InSPrn and Bui2InSPri) decomposed up to 280°C along with an exothermic DT peak and gave indium(I) sulfide (InS) powders. Although the arylthiolate Bun2InSPh also afforded InS powders, it decomposed at a slightly higher temperature. In contrast, the dithiolate and the dithiocarbamate complexes [BunIn(SPri)2 and In (S2CNBu2)3] gave indium(III) sulfide (In2S3) powders. 相似文献