大面积染料敏化太阳电池的串联阻抗特性研究

在电子扩散微分方程的基础上,研究了染料敏化太阳电池光生电流和光生电压随光照强度不同的变化关系.提出敏化太阳电池串联阻抗功率损耗模型,理论模拟了大面积电池（有效面积>1 cm²）光电转换效率随多孔薄膜有效面积宽度变化的曲线、透明导电基底膜与银栅极的比接触电阻以及在不同入射光强下银栅极体电阻对大面积染料敏化太阳电池光伏性能的影响.结果表明透明导电基底膜的方块电阻和银栅极体电阻对大面积染料敏化太阳电池的性能有很大影响,而这种影响随光强的减弱逐渐减小. 关键词： 染料敏化 太阳电池 串联阻抗 光电转换效率     

Analysis of a combined mixed finite element and discontinuous Galerkin method for incompressible two‐phase flow in porous media

We analyze a combined method consisting of the mixed finite element method for pressure equation and the discontinuous Galerkin method for saturation equation for the coupled system of incompressible two‐phase flow in porous media. The existence and uniqueness of numerical solutions are established under proper conditions by using a constructive approach. Optimal error estimates in L²(H¹) for saturation and in L ^∞ (H(div)) for velocity are derived. Copyright © 2013 John Wiley & Sons, Ltd.     

Nd: YAG激光烧蚀裂解加工技术模拟分析与实验研究

激光裂解技术能够极大改善发动机缸体主轴承座的加工质量并显著提高加工效率. 为探寻Nd:YAG激光烧蚀球墨铸铁材料裂解槽的裂解性能, 本文基于有限元法成功构建了发动机缸体主轴承座激光裂解加工过程仿真模型, 针对QT500-7球墨铸铁主轴承座的裂解参数进行了仿真分析. 研究结果表明: 在影响裂解质量的三个裂解槽几何参数中, 槽深较张角及曲率半径对裂解载荷的影响效应更为明显; 裂解载荷随槽深的增加而迅速降低, 随槽张角和曲率半径的增加而升高; QT500-7球墨铸铁发动机缸体主轴承座激光裂解加工优化参数应为裂解槽深选为0.5 mm, 裂解槽张角选为60^o, 裂解槽半径选为0.2 mm. 有限元模拟分析结果得到了单向拉伸实验结果的验证. 本工作通过ABAQUS仿真模拟及大量裂解载荷试验确立了裂解槽几何形状的优化参数, 为显著降低裂解载荷和优化裂解工艺提供了数值参考, 有利于实现发动机缸体加工的快速发展, 从而促进汽车工业实现绿色制造.     

径向非均匀介质中圆形夹杂的动应力分析

基于复变函数理论,研究了径向非均匀弹性介质中均匀圆夹杂对弹性波的散射问题. 介质的非均匀性体现在介质密度沿着径向按幂函数形式变化且剪切模量是常数. 利用坐标变换法将变系数的非均匀波动方程转为标准亥姆霍兹(Helmholtz) 方程. 在复坐标系下求得非均匀基体和均匀夹杂同时存在的位移和应力表达式. 通过具体算例分析了圆夹杂周边的动应力集中系数(DSCF). 结果表明:基体与夹杂的波数比和剪切模量比,基体的参考波数和非均匀参数对动应力集中有较大的影响.      

The efficient in‐situ reduction and cyclization reaction of aromatic aldehyde, 1,3‐cyclopentanedione (tetronic acid), and nitro‐compound under SnCl2·2H2O‐THF medium

An efficient in‐situ reduction and cyclization reaction for the synthesis of pyrazolo[4,3‐f]quinoline, pyrazolo[3,4‐f]quinoline, and pyrazolo[3,2‐f]quinoline derivatives directly form 5‐nitroindazole, 6‐nitroindazole and 5‐nitroindole in the presence of SnCl₂·2H₂O was reported. Compared to traditional synthetic methods, this approach has the advantages of stable reagents, easy obtaining raw material, and high yields. In this research, SnCl₂·2H₂O is the efficient reducing agent for the in‐situ reduction and cyclization reaction of nitro‐compound. In addition, this process provided an alternative approach for the synthesis of target compounds.     

Study of three rotating radio transients with FAST

Rotating radio transients(RRATs) are peculiar astronomical objects whose emission mechanism remains under investigation.In this paper, we present observations of three RRATs, J1538+2345, J1854+0306 and J1913+1330, carried out with the Fivehundred-meter Aperture Spherical radio Telescope(FAST). Specifically, we analyze the mean pulse profiles and temporal flux density evolutions of the RRATs. Owing to the high sensitivity of FAST, the derived burst rates of the three RRATs are higher than those in previous reports. RRAT J1854+0306 exhibited a time-dynamic mean pulse profile, whereas RRAT J1913+1330 showed distinct radiation and nulling segments on its pulse intensity trains. The mean pulse profile variation with frequency is also studied for RRAT J1538+2345 and RRAT J1913+1330, and the profiles at different frequencies could be well fitted with a cone-core model and a conal-beam model, respectively.     

PGAI瞬发伽玛射线活化成像技术理想化模型的模拟

为了讨论PGAI技术分析的准确性,并验证冷中子和热中子应用于PGAI技术的可行性,通过蒙特卡罗模拟计算软件对PGAI技术理想化模型进行了研究,采用高准直的冷中子及热中子束和高纯锗探测器,对一块5 cm× 5 cm×1 cm均匀铁单质样品进行了模拟计算及图像重建,选取的等效体积大小为1 cm×1 cm×1 cm。结果显示：两种能量中子可以用于PGAI技术实现元素分布测量,但无论使用何种能量中子,由于物料体效应带来的中子自屏效应、中子散射效应以及伽马射线自吸收作用,即便在对均匀单质样品进行测量时,图像重建结果也无法保证各位置元素响应的一致性。因此,在后续工作中,需理清PGAI物理机制,建立相应的修正模型。     

In-band pumped Er:YAG ceramic laser with 11 W of output power at 1645 nm

We report on a high power polycrystalline Er:YAG ceramic laser in-band pumped by a cladding-pumped Er, Yb fiber laser wavelength locked at 1532 nm with a volume Bragg grating. Using 1.0 at % Er³⁺-doped ceramic as the gain medium and an output coupler of 10% transmission, the laser had a threshold pump power of ∼1.5 W and generated 11 W of continuous-wave output at 1645 nm for 23.3 W of incident pump power at 1532 nm, corresponding to a slope efficiency with respect to incident pump power of 51%.     

Photonic bandgap via nonlinear modulation assisted by spontaneously generated coherence

A four-level double-ladder atomic system with two upper states coupled to the excited state by a standing-wave trigger field is explored to generate photonic bandgap (PBG) structure. With the assistance of spontaneously generated coherence (SGC) from the two decay pathways, we can obtain single or double fully developed PBG when the trigger field is far away from resonance or resonant. While in the absence of SGC, the atomic medium becomes strong absorptive to the probe field, and therefore the resulting PBGs are severely malformed or even cannot be opened up. Numerical results show that the PBG structure is originated from the third-order cross Kerr nonlinear modulation between the probe and trigger fields. This mechanism differs from the recent schemes based on linear modulation.     

The characters of self-assembly core/shell nanoparticles of amphiphilic hyperbranched polyethers as drug carriers

The characters of self-assembly core/shell nanoparticles of amphiphilic hyperbranched polyethers (HP-g-PEO) as drug carriers were investigated. The HP-g-PEO consisting of hydrophobic HP-g-PEO core and hydrophilic poly(ethylene glycol) arms was prepared by the cation ring-opening polymerization. A series of HP-g-PEO samples with different degree of branching (DB) were synthesized under various reaction temperatures. Nanoparticles (NP) were obtained by self-assembly of HP-g-PEO in aqueous media. The structure of resulting HP-g-PEO was characterized by IR, ¹³CNMR and GPC. Dynamic light scattering and transmission electron microscopy were applied to characterize the sizes and size distributions of NP. The results demonstrated that the mean diameters of NP were less than 100 nm, which exhibited uniform spherical formations and narrow size distributions. Using hydrophobic drug Probucol (PRO) as model drug, the particle sizes of drug loaded NP were larger than relative blank NP. The drug loading efficiency (LE) and incorporation efficiency (IE) of these NP were achieved to 35 and 89%, respectively. The in vitro release of PRO from the NP exhibited a sustained release and the cumulative drugs released for more than 600 h. The most important factor to affect drug release was the value of DB of HP-g-PEO. With the DB of HP-g-PEO increasing, the size and size distribution of NP decreased as well as the release rate. However, the small DB was beneficial to the LE of NP. Nanoparticle size and size distribution, LE, IE, and drug release rate were slightly affected by the initial solution concentration of polyethers. The co-incorporated hydrophilic drug had influence slightly on the release of drug from drug loaded NP. The results of in vitro drug release suggested that the core/shell NP performed good controlled release behaviors with potential practice as novelty drug delivery vehicles.