Sorption of Arsenic Oxyanions from Aqueous Solution on Goethite: a Study of Process Modelling

In the course of researching methods of sampling and monitoring toxic metals (as arsenic ions) in water and wastewaters, we selected the use of sorption for in-depth examination. Among other things, sorption modelling was investigated by the mechanism of surface complexation in order to describe the process or even predict the outcome for the expected rate, and in general, to develop this detection technique for pollutants. This investigation will include the application of goethite mineral as the suitable metal ion sorbent and the use of appropriate computer software. The relative thermodynamic aqueous speciation of the solution, in similar experimental conditions, was also studied.     

Greek football clubs’ efficiency before and after Euro 2004 Victory: a bootstrap approach

This paper examines the technical efficiency of Greek football clubs, taking into account the period before the Euro 2004 victory and the period thereafter. The first stage of analysis is based on a bootstrapped data envelopment analysis approach so as to determine Greek clubs’ efficiency scores during these two distinct time periods. The second stage of analysis investigates possible factors that may have affected the efficiency scores during the examined periods. Our findings reveal that Greek football clubs exhibit surprisingly lower efficiency scores after Euro victory. In effect and explained in the context of the Resource Based Theory, there appears to be no classification of types of football clubs into various divisions, viz. laggards, followers and champions. Finally, it is also found that clubs’ financial health appears to be a crucial factor for their performance in both periods.     

A model for the shear viscosity of non-colloidal suspensions with Newtonian matrix fluids

We present a model for the shear viscosity of non-colloidal suspensions with Newtonian matrix fluids. The model is based on the original idea first presented by Brinkman (Applied Sci Research A1:27-34. 1947) for the viscous force exerted by a flowing fluid on a dense swarm of spherical particles. In particular, we consider an inertialess suspension in which the mean flow is driven by a pressure difference, and simultaneously, the suspension is subject to simple shear. Assuming steady state, incompressibility and taking into account a resistance force which is generated due to the presence of the particles in the flow, the three-dimensional governing equations for the mean flow around a single spherical particle are solved analytically. Self-consistency of the model provides a relationship between the resistance parameter and the volume fraction of the solid phase. A volume, or an ensemble, averaging of the total stress gives the bulk properties and an expression for the relative (bulk) viscosity of the suspension. The viscosity expression reduces to the Einstein limit for dilute suspensions and agrees well with empirical formulas from the literature in the semi-dilute and concentrated regimes. Since the model is based on a single particle and its average interaction with the other particles is isotropic, no normal stress differences can be predicted. A possible method of addressing this problem is provided in the paper.     

Use of holography in particle image velocimetry measurements of a swirling flow

 Particle Image Velocimetry (PIV) is now a well established experimental technique to measure two components of the velocity in a planar region of a flow field. This paper shows how its proven capabilities can be further extended by using holographic recording to register the particle displacements. Among other unique characteristics, holography enables the acquisition of multiple images on a single plate, and the recording of three dimensional images. These features are used to circumvent some of the limitations of conventional PIV. Some of these possibilities are demonstrated in this study by applying the technique to a high Reynolds number swirling flow using a lens-less off-axis orthogonal recording geometry. Received: 25 February 1998/ Accepted: 2 September 1998     

Complex potential formalisms for bending of inhomogeneous monoclinic plates including transverse shear deformation

This paper develops complex potential formalisms for the solution of the bending problem of inhomogenoeus anisotropic plates, on the basis of the most commonly used refined plate theories. Being an initial step in that direction, it works out such formalisms only in connection with the bending problem of shear deformable homogeneous plates as well as plates having a special type of inhomogeneity along their thickness direction. The adopted type of inhomogeneity is however still general enough to include certain classes of plates made of functionally graded material as well as the classes of cross- and angle-ply symmetric laminates as particular cases. The basic formalism, similar to that developed by Stroh in plane strain elasticity, is detailed in relation with the equilibrium equations of a generalized plate theory that accounts for the effects of transverse shear deformation and includes conventional, refined theories as particular cases. Some interesting specializations, related to the most important of those conventional plate theories, are then presented and discussed separately. Hence, the outlined formalisms provide, for the first time in analytical form, the general solution of the partial differential equations associated with the most commonly used refined, elastic plate theories.     

Velocity and conformation statistics based on reduced Karhunen–Loeve projection data from DNS of viscoelastic turbulent channel flow

To investigate the effectiveness of the Karhunen–Loeve (K–L) method as a data reduction approach, we study here its effect on the velocity and conformation statistics in a drag reducing turbulent polymer flow. The K–L method has been used to construct a set of basis velocity eigenfunctions from a large number of independent realizations of the velocity. Those were obtained from direct numerical simulation (DNS) of a viscoelastic turbulent channel flow using the Giesekus model. A subset of the K–L eigenfunctions, large enough to contain more than 90% of the fluctuating kinetic energy of the flow on the average, has then been subsequently used to obtain time series of projection coefficients of the velocity fields generated further from DNS. In a post-processing step, velocity fields were reconstructed using selected subsets of the projection coefficients. Those reconstructed velocity fields were then used to evaluate turbulent statistics as well as to integrate the constitutive equation. The turbulent statistics (r.m.s. velocities, Reynolds stress etc.) thus constructed showed good agreement with the full results from DNS. The Reynolds stress anisotropy was also calculated in this work for the first time. It was found to increase with viscoelasticity that was well reproduced in the reduced K–L data except near the channel centerline where the K–L data showed some loss of anisotropy. The biggest differences however between the K–L reduced data and the full DNS results were seen in the conformation statistics. The average polymer conformation extracted from the K–L reduced data was significantly less than that corresponding to the full DNS results anywhere except in the shear-dominated wall region. A further comparison of the energy and dissipation spectra between the full DNS and the K–L reconstructed data illustrated the impact of the K–L process in resulting to a significant damping of small turbulent scales even those contributing to the maximum in turbulent dissipation. This may also be the principal reason behind the poor quality of the K–L reconstructed conformation data.     

On the rheology of a dilute suspension of rigid spheres in a weakly viscoelastic matrix fluid

The complete solution for the pressure and the velocity field up to O(De) of a dilute suspension of neutrally buoyant, non-Brownian rigid spheres suspended in an unbounded, weakly viscoelastic matrix fluid, where is the solid volume fraction and De is the Deborah number of the matrix fluid, is presented. The spheres are subjected to an arbitrary linear velocity profile at infinity. The analytical solution is used for the prediction of the bulk stress, and specifically for the calculation of the first and the second normal stress differences in simple shear and uniaxial elongational flows. A comparison of the results with available values reported in the literature is also offered. The final expressions for the bulk normal stress differences in shear and uniaxial elongational flow fully agree with those reported earlier by Greco et al., J. Non-Newton. Fluid Mech., 147 (2007) 1–10.     

Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3′-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks

A tris(bromo-methylphenylene)triazine and its corresponding phosphine oxide derivative have been synthesized; the latter compound was found to be a potent ligand for the hydroformylation reaction. Suzuki coupling of the mono-pinacolboronate derivative of the former compound with a tris(iodo-methylphenylene)triazine was possible at two of the three iodine atoms, yielding a bromo- and iodo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3′-dimethyl-biphenyl linker.