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441.
George Zapsas Dimitrios Moschovas Konstantinos Ntetsikas Sofia Rangou Jae‐Hwang Lee Edwin L. Thomas Nikolaos E. Zafeiropoulos Apostolos Avgeropoulos 《Journal of Polymer Science.Polymer Physics》2015,53(17):1238-1246
Synthesis, molecular, and morphological characterization of two linear diblock copolymers consisting of two polydienes with specific geometric isomerisms and two triblock terpolymers with a combination of the same polydienes with polystyrene are investigated for both lower and very high molecular weights. This work is inspired from a previous research study which demonstrated that linear ABC terpolymers consisting of polystyrene, poly(butadiene), and poly(isoprene), with specific geometric isomerisms for the polydienes, lead to 3‐phase microphase separated systems. We report also the coexistence of the core‐shell double gyroid and the 3‐phase 4‐layer alternating lamellae morphologies with the majority fraction being the lamellar structure. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1238–1246 相似文献
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A fully implicit scheme for simulating ionized gas flows using the gas dynamics electrodynamics coupled system
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The flow of ionized gases under the influence of electromagnetic fields is governed by the coupled system of the compressible flow equations and the Maxwell equations. In this system, coupling of the flow with the electromagnetic field is obtained through nonlinear and stiff source terms, which may cause difficulties with the numerical solution of the coupled system. The discontinuous Galerkin finite element method is used for the numerical solution of this system. For the magnetic field vector, discontinuous Galerkin discretization is performed using a divergence‐free vector base for the magnetic field to preserve zero divergence in the element and retain the implicit constraint of a divergence‐free magnetic field vector down to very low level both globally and locally. To circumvent difficulties resulting from the presence of the stiff source terms, implicit time marching is used for the fully coupled system to avoid wrong wave shapes and propagation speeds that are obtained when the coupling source terms are lagged in time or by using splitting iterative schemes. Numerical solutions for benchmark problems computed on collocated meshes for the flow and electromagnetic field variables with this fully coupled monolithic approach showed good agreement with other numerical solutions and exact results. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
446.
Konstantinos Moutzouris Myrtia Papamichael Sokratis C. Betsis Ilias Stavrakas George Hloupis Dimos Triantis 《Applied physics. B, Lasers and optics》2014,116(3):617-622
We report on experimental measurements of the refractive index of twelve organic solvents at five different wavelengths (450, 532, 632.8, 964 and 1,551 nm) and a temperature of 300 K. Based on these new data visible to near-infrared dispersion relations are constructed. Group-velocity dispersion (GVD) is theoretically calculated. Zero- and negative-GVD situations are identified for two common solvents in near-infrared wavelengths. Via comparison with refractive index data available in bibliography, estimated values of thermo-optic coefficients are also presented. 相似文献
447.
Konstantinos Makridis 《复变函数与椭圆型方程》2019,64(6):899-908
We prove the generic existence of universal Laurent series in domains of infinite connectivity. The universal approximation is valid on a part of the boundary, while on another disjoint part of the boundary the universal function is smooth. 相似文献
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Dr. Senthil Subramaniam Dr. Mond F. Guo Tanmayi Bathena Michel Gray Dr. Xiao Zhang Abraham Martinez Dr. Libor Kovarik Dr. Konstantinos A. Goulas Dr. Karthikeyan K. Ramasamy 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(34):14658-14665
Ethanol can be used as a platform molecule for synthesizing valuable chemicals and fuel precursors. Direct synthesis of C5+ ketones, building blocks for lubricants and hydrocarbon fuels, from ethanol was achieved over a stable Pd-promoted ZnO-ZrO2 catalyst. The sequence of reaction steps involved in the C5+ ketone formation from ethanol was determined. The key reaction steps were found to be the in situ generation of the acetone intermediate and the cross-aldol condensation between the reaction intermediates acetaldehyde and acetone. The formation of a Pd–Zn alloy in situ was identified to be the critical factor in maintaining high yield to the C5+ ketones and the stability of the catalyst. A yield of >70 % to C5+ ketones was achieved over a 0.1 % Pd-ZnO-ZrO2 mixed oxide catalyst, and the catalyst was demonstrated to be stable beyond 2000 hours on stream without any catalyst deactivation. 相似文献
449.
Cassandra T. Eagle Konstantinos Kavallieratos Jeffrey C. Bryan 《Journal of chemical crystallography》2002,32(7):165-170
The structure of N,N-diphenyl-1,3-benzenedisulfonamide (1) was determined by single crystal X-ray diffraction. It crystallizes in P21/n with cell dimensions: a = 11.8390(6) Å, b = 12.3950(10) Å, c = 12.1184(10) Å, = 94.388(6)°, and V = 1773.1(2) Å3. Its di-t-butyl derivative, N,N-bis(4-t-butylphenyl)-1,3-benzenedisulfonamide (2), was prepared and structurally characterized as two solvated structures. Both crystallize in P
with cell dimensions: 2 CF3CH2OH, a = 9.469(2) Å, b = 10.0039(18) Å, c = 16.385(3) Å, = 85.561(16)°, = 83.035(18)°, = 72.459(16), and V = 1467.7(5) Å3; 2 ClCH2CH2Cl, a = 9.559(2) Å, b = 9.8125(12) Å, c = 17.100(6) Å, = 82.495(19)°, = 83.47(2)°, = 70.100(15), and V = 1491.1(6) Å3. The structures exhibit hydrogen-bonding, and are evaluated in terms of preorganization for anion binding. 相似文献
450.
Michele Bolla Daniele Farrace Yuri M. Wright Konstantinos Boulouchos Epaminondas Mastorakos 《Combustion Theory and Modelling》2013,17(2):330-360
The influence of the turbulence–chemistry interaction (TCI) for n-heptane sprays under diesel engine conditions has been investigated by means of computational fluid dynamics (CFD) simulations. The conditional moment closure approach, which has been previously validated thoroughly for such flows, and the homogeneous reactor (i.e. no turbulent combustion model) approach have been compared, in view of the recent resurgence of the latter approaches for diesel engine CFD. Experimental data available from a constant-volume combustion chamber have been used for model validation purposes for a broad range of conditions including variations in ambient oxygen (8?21% by vol.), ambient temperature (900 and 1000 K) and ambient density (14.8 and 30 kg/m3). The results from both numerical approaches have been compared to the experimental values of ignition delay (ID), flame lift-off length (LOL), and soot volume fraction distributions. TCI was found to have a weak influence on ignition delay for the conditions simulated, attributed to the low values of the scalar dissipation relative to the critical value above which auto-ignition does not occur. In contrast, the flame LOL was considerably affected, in particular at low oxygen concentrations. Quasi-steady soot formation was similar; however, pronounced differences in soot oxidation behaviour are reported. The differences were further emphasised for a case with short injection duration: in such conditions, TCI was found to play a major role concerning the soot oxidation behaviour because of the importance of soot-oxidiser structure in mixture fraction space. Neglecting TCI leads to a strong over-estimation of soot oxidation after the end of injection. The results suggest that for some engines, and for some phenomena, the neglect of turbulent fluctuations may lead to predictions of acceptable engineering accuracy, but that a proper turbulent combustion model is needed for more reliable results. 相似文献