Processes and properties of electric arc stabilized by water vortex

Experimental investigation of an electric arc stabilized by a water vortex was carried out in a DC arc plasma torch for the power range 90-200 kW. Volt-ampere characteristics of the arc as well as the power balance were determined separately for the part of the arc column stabilized by water and for the remaining part between the nozzle exit and the external anode. The temperature of arc plasma close to the nozzle exit was determined by emission spectroscopy. Negatively biased electric probes in the ion collecting regime were used for determination of the plasma flow velocity. The measured temperatures up to 27000 K, and velocities up to 7 km/s are higher than the values commonly reported for plasma torches with DC arcs stabilized by a gas flow. Mass and energy balances within the arc chamber were determined from the experimental results. The radial transport of the energy by radiation was identified as a decisive process controlling the arc and plasma properties. The balance of radial energy transport was studied. The ratio of energy spent for evaporation of the water to the energy absorbed in the evaporated mass is very low in the water stabilized arc. This is the principal cause of high plasma temperatures and velocities found by the measurements     

Anomalous dispersion in the Belousov-Zhabotinsky reaction: Experiments and modeling

We report results on dispersion relations and instabilities of traveling waves in excitable systems. Experiments employ solutions of the 1,4-cyclohexanedione Belousov-Zhabotinsky reaction confined to thin capillary tubes which create a pseudo-one-dimensional system. Theoretical analyses focus on a three-variable reaction-diffusion model that is known to reproduce qualitatively many of the experimentally observed dynamics. Using continuation methods, we show that the transition from normal, monotonic to anomalous, single-overshoot dispersion curves is due to an orbit flip bifurcation of the solitary pulse homoclinics. In the case of “wave stacking”, this anomaly induces attractive pulse interaction, slow solitary pulses, and faster wave trains. For “wave merging”, wave trains break up in the wake of the slow solitary pulse due to an instability of wave trains at small wavelength. A third case, “wave tracking” is characterized by the non-existence of solitary waves but existence of periodic wave trains. The corresponding dispersion curve is a closed curve covering a finite band of wavelengths.     

Correlations in hypernuclear matter

We investigate short-range correlations in nuclear and hypernuclear matter. Self-energies due to short-range correlations and their influence on the nucleon and Λ -hyperon spectral functions are described in an approach accounting for a realistic treatment of mean-field dynamics and a self-consistently derived quasi-particle interaction. Landau-Migdal theory is used to derived the short-range interaction from a phenomenological Skyrme energy density functional, subtracting the long-range pionic contributions to the nucleonic spectral functions. We discuss our results for different hyperon-baryon ratios to show the influence of strangeness on the correlations in hypernuclear matter.     

Direct measurement of the spatial Wigner function with area-integrated detection

We demonstrate experimentally a novel technique for characterizing transverse spatial coherence by using the Wigner distribution function. The method is based on the measurement of interference between a pair of rotated and displaced replicas of the input beam with an area-integrating detector, and it provides an optimal signal-to-noise ratio in regimes when array detectors are not available. We analyze the quantum-optical picture of the presented measurement for single-photon signals and discuss possible applications in quantum information processing.     

Self-assembly of monatomic complex crystals and quasicrystals with a double-well interaction potential

For the study of crystal formation and dynamics, we introduce a simple two-dimensional monatomic model system with a parametrized interaction potential. We find in molecular dynamics simulations that a surprising variety of crystals, a decagonal, and a dodecagonal quasicrystal are self-assembled. In the case of the quasicrystals, the particles reorder by phason flips at elevated temperatures. During annealing, the entropically stabilized decagonal quasicrystal undergoes a reversible phase transition at 65% of the melting temperature into an approximant, which is monitored by the rotation of the de Bruijn surface in hyperspace.     

Nuclear shadowing in Glauber–Gribov theory with Q 2-evolution

We consider deep inelastic scattering off nuclei in the Regge limit within the Glauber–Gribov model. Using unitarized parton distribution functions for the proton, we find sizeable shadowing effects on the nuclear total and longitudinal structure functions, $F_{2}^{A}$ and $F_{L}^{A}$ , in the low-x limit. Extending a fan-diagram analysis for the large-mass region of coherent diffraction off nuclei to high Q ², we also find significant shadowing effects in this kinematical regime. Finally, we discuss the shortcomings of our approach and possible extensions of the model to other kinematical regimes.     

Functionalization of Metal–Organic Frameworks through the Postsynthetic Transformation of Olefin Side Groups

For the first time, the adaptability of the C?C double bond as a versatile precursor for the postsynthetic modification (PSM) of microporous materials was extensively investigated and evaluated. Therefore, an olefin‐tagged 4,4′‐bipyridine linker was synthesized and successfully introduced as pillar linker within a 9,10‐triptycenedicarboxylate (TDC) zinc paddle‐wheel metal–organic framework (MOF) through microwave‐assisted synthesis. Different reactions, predominately used in organic chemistry, were tested, leading to the development of new postsynthetic reactions for the functionalization of solid materials. The postsynthetic oxidation of the olefin side groups applying osmium tetroxide (OsO₄) as a catalyst led to the formation of a microporous material with free vicinal diol functionalities. The epoxidation with dimethyldioxirane (DMDO) enabled the synthesis of epoxy‐functionalized MOFs. In addition to that, reaction procedures for a postsynthetic hydroboration with borane dimethyl sulfide as well as a photoinduced thiol–ene click reaction with ethyl mercaptan were developed. For all of these PSMs, yields of more than 90 % were obtained, entirely maintaining the crystallinity of the MOFs. Since the direct introduction of the corresponding groups by means of pre‐synthetic approaches is hardly possible, these new PSMs are useful tools for the functionalization of porous solids towards applications such as selective adsorption, separation, and catalysis.     

Organozinc Pivalate Reagents: Segregation,Solubility, Stabilization,and Structural Insights

The pivalates RZnOPiv?Mg(OPiv)X?n LiCl (OPiv=pivalate; R=aryl; X=Cl, Br, I) stand out amongst salt‐supported organometallic reagents, because apart from their effectiveness in Negishi cross‐coupling reactions, they show more resistance to attack by moist air than conventional organometallic compounds. Herein a combination of synthesis, coupling applications, X‐ray crystallographic studies, NMR (including DOSY) studies, and ESI mass spectrometric studies provide details of these pivalate reagents in their own right. A p‐tolyl case system shows that in [D₈]THF solution these reagents exist as separated Me(p‐C₆H₄)ZnCl and Mg(OPiv)₂ species. Air exposure tests and X‐ray crystallographic studies indicate that Mg(OPiv)₂ enhances the air stability of aryl zinc species by sequestering H₂O contaminants. Coupling reactions of Me(p‐C₆H₄)ZnX (where X=different salts) with 4‐bromoanisole highlight the importance of the presence of Mg(OPiv)₂. Insight into the role of LiCl in these multicomponent mixtures is provided by the molecular structure of [(THF)₂Li₂(Cl)₂(OPiv)₂Zn].