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11.
We characterize monoids over which all S-acts are CC-injective and find conditions under which CC-injectivity of all acts implies that all acts are C-injective.
Research of X. Zhang supported by the China Scholarship Council No. 2006101056.
Research of Y. Chen supported by the NNSF of China (No. 10771077) and the NSF of Guangdong Province (No. 06025062). 相似文献
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Endomorphisms of graphs II. Various unretractive graphs 总被引:2,自引:0,他引:2
Ulrich Knauer 《Archiv der Mathematik》1990,55(2):193-203
In this part of the article we investigate graphs for which different endomorphism monoids coincide. We consider endomorphisms, strong endomorphisms and automorphisms. Coincidences are investigated for joins of graphs and some lexicographic products. In an additional section the graphs with the respective properties are listed up to 8 vertices in two cases and up to 5 vertices in the remaining case. 相似文献
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Thermal Stability and Molecular Ordering of Organic Semiconductor Monolayers: Effect of an Anchor Group
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Dr. Andrew O. F. Jones Philipp Knauer Prof. Roland Resel Dr. Andreas Ringk Prof. Peter Strohriegl Dr. Oliver Werzer Prof. Michele Sferrazza 《Chemphyschem》2015,16(8):1712-1718
The thermal stability and molecular order in monolayers of two organic semiconductors, PBI‐PA and PBI‐alkyl, based on perylene derivatives with an identical molecular structure except for an anchor group for attachment to the substrate in PBI‐PA, are reported. In situ X‐ray reflectivity measurements are used to follow the stability of these monolayers in terms of order and thickness as temperature is increased. Films have thicknesses corresponding approximately to the length of one molecule; molecules stand upright on the substrate with a defined structure. PBI‐PA monolayers have a high degree of order at room temperature and a stable film exists up to 250 °C, but decomposes rapidly above 300 °C. In contrast, stable physisorbed PBI‐alkyl monolayers only exist up to 100 °C. Above the bulk melting point at 200 °C no more order exists. The results encourage using anchor groups in monolayers for various applications as it allows enhanced stability at the interface with the substrate. 相似文献
18.
The radical enzyme (R)-2-hydroxyisocaproyl-CoA dehydratase catalyzes the dehydration of (R)-2-hydroxyisocaproyl-CoA in the fermentation of l-leucine by the human pathogenic bacterium Clostridium difficile. In contrast to other radical enzymes, such as bacterial class II ribonucleotide reductase or biotin synthase, the Fe/S cluster containing (R)-2-hydroxyisocaproyl-CoA dehydratase requires no special cofactors such as coenzyme B(12) or S-adenosylmethionine for radical generation. Instead it uses a single high-energy electron that is recycled after each turnover. The catalyzed reaction, an atypical α/β-dehydration, depends on the reductive formation of ketyl radicals on the substrate generated by injection of a single electron from the ATP-dependent activator protein. So far, it is unknown how the active electron is recycled and how unwanted side reactions are prevented, allowing for up to 10,000 turnovers. The crystal structure reveals that the heterodimeric protein contains two [4Fe-4S] clusters at a distance of 12 ?, each coordinated by three cysteines and one terminal ligand. The cluster in the α-subunit is part of the active site. In the absence of substrate, a water/hydroxide ion acts as the fourth ligand. The substrate replaces this ligand and coordinates the cluster via the carbonyl-oxygen of the thioester group. The cluster in the β-subunit has a terminal sulfhydryl/sulfido ligand and can act as a reservoir to protect the electron from unwanted side reactions via a recycling mechanism. The crystal structure of (R)-2-hydroxyisocaproyl-CoA dehydratase serves as a model for the reductively radical-generating metalloenzymes of the (R)-2-hydroxyacyl-CoA dehydratase and benzoyl-CoA reductase families. 相似文献
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Theilacker K Arbuznikov AV Bahmann H Kaupp M 《The journal of physical chemistry. A》2011,115(32):8990-8996
Due to their position-dependent exact exchange admixture, local hybrid functionals offer a higher flexibility and thus the potential for more universal and accurate exchange correlation functionals compared to global hybrids with a constant admixture, as has been demonstrated in previous work. Yet, the local hybrid constructions used so far do not account for the inclusion of dispersion-type interactions. As a first exploratory step toward a more general approach that includes van der Waals-type interactions with local hybrids, the present work has added DFT-D3-type corrections to a number of simple local hybrid functionals. Optimization of only the s(8) and s(r,6) parameters for the S22 set provides good results for weak interaction energies but deteriorates the excellent performance of the local hybrids for G3 atomization energies and for classical reaction barriers. A combined optimization of the two DFT-D3 parameters with one of the two parameters of the spin-polarized local mixing function (LMF) of a local hybrid for a more general optimization set provides simultaneously accurate dispersion energies, improved atomization energies, and accurate reaction barriers, as well as excellent alkane protobranching ratios. For other LMFs, the improvements of such a combined optimization for the S22 energies have been less satisfactory. The most notable advantage of the dispersion-corrected local hybrids over, for example, a B3LYP-D3 approach, is in the much more accurate reaction barriers. 相似文献
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M.B. Goldberg E. Konejung W. Knauer G.J. Kumbartzki P. Meyer K.-H. Speidel J. Gerber 《Physics letters. A》1976,58(4):269-271
PAC measurements on the 4.43 MeV 12C(2+) state on recoil in magnetized iron at velocities υion = 0.058c, 0.071c yield integral nuclear precession angles of Φ = ?0.18 (30), +0.17 (39) mrad respectively. Evidently, the high electron-spin-polarization transfer to the innermost carbon orbits implied by a previous measurement (υion = 0.03c, Φ = +0.85 (14) mrad) is suppressed at higher ion velocities. 相似文献