Short-range part of the NN interaction: Lowest-order relativistic corrections to equivalent local potentials from quark exchange kernels

The full Breit hamiltonian, including the Darwin term and relativistic kinetic-energy correction, has been used to construct resonating group kernels in analytic form for the six-quark NN system. The nonlocal kernels have been converted to equivalent local potentials using the WKB approximation based on their Wigner transforms. The equivalent local potentials have been confirmed to be rather insensitive to a choice of parameters and to be fairly accurate by comparing with the phase shifts and the wave functions obtained with the RGM equation. The results indicate the importance of the Darwin term. The term leads to a large reduction of the strong repulsive cores given by the color magnetic interaction and makes the resulting potentials less repulsive than those which neglect this term. The relative importance of the various components in the Breit interaction and of the quark-gluon exchange diagrams is made clear.     

Synthetic studies on β-lactam antibiotics. 15. conversion of 7-epicephems into 1-oxacephems

7-Epi-1-oxacephem was obtained by stereospecific, intramolecular etherification of alcohol prepared from 7-epicephems via aldehyde or formate. Synthesis of the 3-acetoxymethyl analogwas unsuccessful. Biologically active 1-oxacephems were derived from by known processes.     

Stereoselective synthesis of (±)-phomenone,a phytotoxic metabolite of phoma exigua, and (±)-3-epiphomenone

Stereoselective synthesis of (±)-phomenone, a phytotoxic metabolite from the fungus Phoma exigua, and (±)-3-epiphomenone is described.     

The synthesis of possible hydroxylated metabolites of 2-chlorophenothiazine derivatives

The synthesis of 7-hydroxy, 8-hydroxy and 7,8-dihydroxy prochlorperazines (3a) and per-phenazines (3b) is reported. The parent ehlorophenothiazines were prepared analogously to previously reported chlorpromazine (3e) metabolite syntheses. The prochlorperazine side chain was introduced in one step using 1-(3-chloropropyl)-4-methylpiperazine and the perphenazine side chain in two steps, first reaction with 1-bromo-3-chloropropane followed by reaction with 1-piperazineethanol. The methoxymethyleneoxy O-proteetive groups were removed under mild conditions using methanolic hydrogen chloride. The preparations of 7-hydroxydesmethylprochlorperazine and 7-hydroxychlorpromazine quaternary methyl iodide are also reported.     

Thermal evidences for successive CDW phase transitions in 1T-TaS2

The heat capacity of 1T-TaS₂ has been measured over the temperature range including the successive phase transitions (140 K–370 K) by an adiabatic calorimeter. There are three transitions in the measured temperature range, two first-order transitions (at about 226 K (T₁) and about 353.5 K (T₃)) and one small anomaly at about 283 K (T₂) with a broad peak. The transition enthalpies are as follows; ΔH₁=52±5 cal·mol^-1, ΔH₂=7.5±2 cal· mol^-1 and ΔH₃=122±8cal·mol^-1.     

A new method for the synthesis of α-arylalkanoic acids by the use of 1,2-rearrangement of the aryl group

A simple synthetic method of α-arylalkanoic acids was accomplished by the use of a novel 1,2-rearrangement of the aryl group and this method was applied to the syntheses of some biologically important substances.