Separation of the isochromatics-isopachics patterns by use of retarders in holographic photoelasticity

By double passing the object beam in photoelastic-holographic interferometry, separation of the isochromatic-isopachic patterns can be achieved. The object beam must then interact with a suitable polarizing element between the first and second pass. This problem is analyzed using Jones' matrices. This analysis shows that, apart from active and passive rotators, half-wave and quarter-wave retarders can also be used as polarizing elements. Possible experimental arrangements of the method are reviewed and experimental verifications are presented.     

API stepsize control for the numerical solution of ordinary differential equations

A control-theoretic approach is used to design a new automatic stepsize control algorithm for the numerical integration of ODE's. The new control algorithm is more robust at little extra expense. Its improved performance is particularly evident when the stepsize is limited by numerical stability. Comparative numerical tests are presented.     

A reinvestigation of the thermal rearrangements of naphthvalene

The previously reported thermal transformation of naphthvalene to benzofulvene has been shown to be a catalyzed process; naphthvalene rearranges to naphthalene under flow pyrolysis conditions.     

Studies of hydrogen bonding: Part XXIX. An experimental and theoretical approach to the structure of nitriles and of hydrogen-bonded complexes with phenol

Dipole moments, μ_a, of four nitriles, have been determined experimentally and calculated by the CNDO/2 method. The results obtained can be accounted for in terms of a planar trimer parallel-antiparallel model held together in clusters. Experimental and CNDO/2 calculated dipole moments of hydrogen-bonded complexes between nitriles and phenol indicate strongly that the O-H proton in phenol is located perpendicular to the triple bond.     

The surface tension of concentrated aqueous solutions of 1.1-electrolytes measured by means of Wilhelmy and laser light scattering methods

Surface tension measurements were made on concentrated (<4 moles/kg) aqueous solutions of the following 1.1-electrolytes: KF, KCl, KI, HCl, and HNO₃. Two different measurement techniques were used: the Wilhelmy slide method and a method based on the scattering of laser light by small amplitude liquid surface waves. The surface tension determined by the two methods agrees within ±0.5% and for each solution it is found to vary almost linearly with concentration. The shear viscosity was also measured for these solutions by means of the laser method and a standard flow viscosimeter. The measured values were found to agree within ±5%.     

On the relationship between fluorescence and molecular geometry. Formation of a luminescent intramolecular anthracene-ethylene exciplex by electronic excitation of lepidopterene

Electronic excitation of the bridged benzenoid hydrocarbon lepidoptene (L) in the crystalline state and in solution gives rise to an anomalous luminescence which is attributed to the radiative deactivation of an intramolecular anthraceneethylene exciplex E*. The formation of E* and the regeneration of L are discussed in terms of a geometry-dependent reversible [4 + 2] cycloaddition. Relevant quantum yield data are presented in an energy level diagram.     

Mass spectrometry of onium compounds—II. Carnitine and O-acyl derivatives

Carnitine and its O-acyl derivatives undergo two major pyrolytic reactions in the mass spectrometer. Firstly elimination of water from carnitine or acid from acylcarnitine takes place followed by intramolecular displacement and formation of crotonyl lactone and trimethylamine. Secondly intramolecular displacement occurs with formation of a substituted γ-lactone and trimethylamine. For the lower acid derivatives only the elimination pathway is important. For carnitine and higher derivatives both processes are important. The electron induced fragmentations of the major pyrolysis products are relatively simple. The most important pathways for the major components are discussed. The pyrolytic composition and mode of fragmentation are characteristic and can be used for identification purposes.     

Mass spectrometry of tropylium halides

The base peak and highest mass number in the spectra of tropylium iodide and bromide corresponds to the mass of the cation. Both appearance potential (AP) measurements and the fragmentation pattern strongly indicate that the gaseous species present is the tropylium radical. Rediction to the corresponding volatile free radical thus takes place prior to evaporation.     

Defence and attack of systems with variable attacker system structure detection probability

A system consists of identical elements. The cumulative performance of these elements should meet a demand. The defender applies three types of defensive actions to reduce a damage associated with system performance reduction caused by an external attack: deploying separated redundant genuine system elements, deploying false elements, and protecting genuine elements. If the attacker cannot distinguish between genuine and false elements, he chooses a number of elements to attack and then selects the elements at random, distributing his resources equally across these elements. By obtaining intelligence data, the attacker can get full information about the system structure and identify false and unprotected genuine elements. The defender estimates the probability that the attacker can identify all system elements. This paper analyses the influence of this probability in a non-cooperative two-period minmax game between the defender and the attacker.