首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3650篇
  免费   60篇
  国内免费   11篇
化学   2774篇
晶体学   83篇
力学   53篇
数学   160篇
物理学   651篇
  2022年   16篇
  2021年   27篇
  2020年   30篇
  2019年   39篇
  2018年   31篇
  2016年   48篇
  2015年   64篇
  2014年   55篇
  2013年   180篇
  2012年   134篇
  2011年   167篇
  2010年   93篇
  2009年   105篇
  2008年   166篇
  2007年   197篇
  2006年   198篇
  2005年   180篇
  2004年   179篇
  2003年   165篇
  2002年   159篇
  2001年   118篇
  2000年   89篇
  1999年   53篇
  1998年   38篇
  1997年   36篇
  1996年   50篇
  1995年   50篇
  1994年   48篇
  1993年   42篇
  1992年   83篇
  1991年   50篇
  1990年   42篇
  1989年   42篇
  1988年   41篇
  1987年   45篇
  1986年   52篇
  1985年   48篇
  1984年   69篇
  1983年   28篇
  1982年   37篇
  1981年   36篇
  1980年   43篇
  1979年   56篇
  1978年   43篇
  1977年   27篇
  1976年   32篇
  1975年   31篇
  1974年   31篇
  1973年   17篇
  1972年   15篇
排序方式: 共有3721条查询结果,搜索用时 15 毫秒
31.
The behavior of zirconium atoms at the W(100) surface associated with oxygen adsorption at different sample temperatures has been studied by Auger electron spectroscopy (AES), ion scattering spectroscopy (ISS), and the relative change of the work function (Δф) measured by the onset of the secondary electron energy distribution. The results have revealed: (i) adsorption of zirconium onto the W(100) surface followed by the elevation of the sample temperature up to 1710 K in an oxygen partial pressure of 2.7 × 10−4 induces complete diffusion of zirconium atoms into the W(100) substrate; (ii) further exposure of oxygen induces co-existence of oxygen and tungsten on the surface at 1710 K, resulting in a work function of 4.37 eV; (iii) keeping the sample temperature at 1710 K, simple evacuation of the system has resulted in surface segregation of zirconium atoms to the surface to form a zirconium atomic layer on the top-most surface, reducing the work function to 2.7 eV. The results have revealed that this specific behavior of zirconium atoms at high temperature assures, with very good reproducibility, the highly stable performance and long service life of Zr---O/W(100)-emitters in practical use, even in a low vacuum of 10−6 Pa.  相似文献   
32.
In the present work we study the photonic band structure (PBS) and the polarization state of the Bloch eigenmodes of a two-dimensional magnetophotonic crystal (MPC) with square lattice formed from magneto-optically (MO) active cylinders. The refraction of light at the boundary of the MPC is analyzed. We found that both—the PBS and eigenmodes of the MPC—are most significantly altered by the MO activity in the vicinity of the degeneracies. For this case we demonstrated the possibility of an abrupt change in the propagation direction of light by the application of a magnetic field. For the Bloch wave vectors and frequencies corresponding to non-degenerate branches, the alteration of the PBS is shown to be negligible and eigenmodes almost completely coincide with linearly TE- and/or TM-polarized eigenmodes of the non-magnetic photonic crystal.  相似文献   
33.
Various topological properties of projective duality between real projective varieties and their duals are obtained by making use of the microlocal theory of (subanalytically) constructible sheaves developed by Kashiwara [M. Kashiwara, Index theorem for constructible sheaves, Astérisque 130 (1985) 193-209] and Kashiwara-Schapira [M. Kashiwara, P. Schapira, Sheaves on Manifolds, Grundlehren Math. Wiss., vol. 292, Springer, Berlin-Heidelberg-New York, 1990]. In particular, we prove in the real setting some results similar to the ones proved by Ernström in the complex case [L. Ernström, Topological Radon transforms and the local Euler obstruction, Duke Math. J. 76 (1994) 1-21]. For this purpose, we describe the characteristic cycles of topological Radon transforms of constructible functions in terms of curvatures of strata in real projective spaces.  相似文献   
34.
The complex Young's modulus, E*(ω), and the complex strain-optical coefficient, O*(ω), which is the ratio of the birefringence to the strain, were measured for polyisoprene (PIP) over a frequency range of 1 ~ 130 Hz and a temperature range of 22 ~ ?100°C. The imaginary part of O*, O″, was positive at low frequencies and negative at high frequencies. The real part, O′, was always positive and showed a maximum. The complicated behavior of O* could be understood by the assumption that E* = ER* + EG* and O* = CRER* + CGEG*, where ER* and EG* were complex quantities and CR and CG were constants. The CR value, equal to the ordinary stress-optical coefficient measured in the rubbery plateau zone, was 2.0 × 10?9 Pa?1. The CG value, defined as the ratio O″/E″ in the glassy zone, was ?1.1 × 10?11 Pa?1. The EG*, which was the major component of E* in the glassy zone, showed almost the same frequency dependence as that of polystyrene and polycarbonate. The ER*, which was dominant in the rubbery zone, was described well by the bead-spring theory. The temperature dependence of the EG* was stronger than that of the ER*. This difference caused the breakdown of the thermorheological simplicity for E* and O* around the glass-to-rubber transition zone. © 1995 John Wiley & Sons, Inc.  相似文献   
35.
The limiting molar conductances ° of deuterium chloride DCl in D2O were determined as a function of pressure and temperature in order to examine the proton-jump mechanism in detail. The excess deuteron conductances °E(D +), as estimated by the equation [°E(D +) = °(DCl/D 2 O) – °(KCl/D 2 O)], increases with an increase in the pressure and temperature as well as the excess proton conductance [°E(H +) = °(HCl/H 2 O) – °(KCl/H 2 O)]. The isotope effect on the excess conductances, however, depends on the pressure and temperature contrary to the model proposed by Conway et al.: °E(H +)/°E(D +) decreases with increasing pressure and temperature. The magnitude of the decrease with pressure becomes more prominent at lower temperature. These results are discussed in terms of the pre-rotation of adjacent water molecules, the bending of hydrogen bonds with pressure, and the difference in strength of hydrogen bonds between D2O and H2O.  相似文献   
36.
37.
Gas-stirred propylene carbonate (PC) extraction can be performed by bubbling nitrogen without loss of volume. This extraction technique has proved to be highly useful for the separation and subsequent direct polarographic estimation of Tl(III) in the recovered PC phase. Tl(III) can be determined by differential-pulse polarography over the concentration range of 0.4 10 g ml–1 without any interferences due to most metal ions such as Pb(II), Bi(III), Cu(II), Sb(III) and As(III). This proposed technique would be possible to use as a simple extraction step prior to the final estimation by instrumental method of analysis such as atomic absorption spectrometry or spectrophtometry.  相似文献   
38.
Hoshi S  Yamada M  Inoue S  Matsubara M 《Talanta》1989,36(5):606-608
Preconcentration by collection of metal complexes on chitin has been applied to the spectrophotometric determination of iron in water. The iron is collected as its 1,10-phenanthroline (phen) complex on a column of chitin in the presence of tetraphenylborate as counter-ion. The iron(II)-phen complex retained on the chitin is eluted with an acetone-1M acetic acid mixture (8:2 v/v), and the absorbance of the eluate is measured at 512 nm. Beer's law is obeyed over the concentration range 1.1-11.2 mug of iron in 10 ml of eluate. In the presence of EDTA as masking agent, Ca, Mg, Al, Mn, Zn, Cd and Pb do not interfere in concentrations up to 100 times that of iron(II) and Co, Ni and Cu do not interfere in concentrations up to 20 times that of iron(II). Common inorganic anions do not interfere in concentrations up to 10,000 times that of iron(II). The proposed method has been applied to determination of iron in tap water.  相似文献   
39.
Cell suspension cultures of Lithospermum erythrorhizon produced a large amount of lithospermic acid B, a caffeic acid tetramer, as well as shikonin derivatives (each ca. 10% of dry wt.) when cultured in shikonin production medium M-9. Various culture factors for increasing the production of lithospermic acid B were investigated. Lithospermic acid B production was inhibited by 2, 4-D or NH4+, whereas it was stimulated by Cu2+. These regulatory patterns were similar to those for the production of shikonin derivatives in these cell cultures, suggestive of close relations and similar metabolic regulation between the production of these compounds. Cultivation under light illumination, however, showed that these metabolisms were independently regulated. In particular, blue light showed a stimulatory effect on lithospermic acid B production, while shikonin production was strongly inhibited, indicative of an effective condition for lithospermic acid B production.  相似文献   
40.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号