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61.
Brauer CS Craddock MB Kilian J Grumstrup EM Orilall MC Mo Y Gao J Leopold KR 《The journal of physical chemistry. A》2006,110(33):10025-10034
The Stark effect has been observed in the rotational spectra of several gas-phase amine-hydrogen halide complexes and the following electric dipole moments have been determined: H(3)(15)N-H(35)Cl (4.05865 +/- 0.00095 D), (CH(3))(3)(15)N-H(35)Cl (7.128 +/- 0.012 D), H(3)(15)N-H(79)Br (4.2577 +/- 0.0022 D), and (CH(3))(3)(15)N-H(79)Br (8.397 +/- 0.014 D). Calculations of the binding energies and electric dipole moments for the full set of complexes R(n)()(CH(3))(3)(-)(n)()N-HX (n = 0-3; X = F, Cl, Br) at the MP2/aug-cc-pVDZ level are also reported. The block localized wave function (BLW) energy decomposition method has been used to partition the binding energies into contributions from electrostatic, exchange, distortion, polarization, and charge-transfer terms. Similarly, the calculated dipole moments have been decomposed into distortion, polarization, and charge-transfer components. The complexes studied range from hydrogen-bonded systems to proton-transferred ion pairs, and the total interaction energies vary from 7 to 17 kcal/mol across the series. The individual energy components show a much wider variation than this, but cancellation of terms accounts for the relatively narrow range of net binding energies. For both the hydrogen-bonded complexes and the proton-transferred ion pairs, the electrostatic and exchange terms have magnitudes that increase with the degree of proton transfer but are of opposite sign, leaving most of the net stabilization to arise from polarization and charge transfer. In all of the systems studied, the polarization terms contribute the most to the induced dipole moment, followed by smaller but still significant contributions from charge transfer. A significant contribution to the induced moment of the ion pairs also arises from distortion of the HX monomer. 相似文献
62.
63.
P. Winter M. Wolke H.-H. Adam A. Budzanowski R. Czyżykiewicz D. Grzonka M. Janusz L. Jarczyk B. Kamys A. Khoukaz K. Kilian P. Klaja P. Moskal W. Oelert C. Piskor-Ignatowicz J. Przerwa J. Ritman T. Rożek T. Sefzick M. Siemaszko J. Smyrski A. Täschner P. Wüstner Z. Zhang W. Zipper 《Physics letters. [Part B]》2006
The total cross section of the reaction pp→ppK+K− has been measured at excess energies Q=10 MeV and 28 MeV with the magnetic spectrometer COSY-11. The new data show a significant enhancement of the total cross section compared to pure phase space expectations or calculations within a one boson exchange model. In addition, we present invariant mass spectra of two particle subsystems. While the K+K− system is rather constant for different invariant masses, there is an enhancement in the pK− system towards lower masses which could at least be partially connected to the influence of the Λ(1405) resonance. 相似文献
64.
M. Abdel-Bary K. -Th. Brinkmann H. Clement E. Doroshkevich S. Dshemuchadse A. Erhardt W. Eyrich H. Freiesleben A. Gillitzer R. Jäkel L. Karsch K. Kilian E. Kuhlmann K. Möller H. P. Morsch L. Naumann N. Paul C. Pizzolotto J. Ritman E. Roderburg P. Schönmeier W. Schroeder M. Schulte-Wissermann G. Y. Sun A. Teufel A. Ucar G. J. Wagner M. Wagner P. Wintz P. Wüstner P. Zupranski 《The European Physical Journal A - Hadrons and Nuclei》2006,29(3):353-361
The reaction
has been studied in a kinematically complete experiment at a single beam momentum
GeV/c (T = 759MeV). All four ejectiles have been detected in the large-acceptance time-of-flight spectrometer COSY-TOF. We analyzed
the data along the lines of the spectator model as a means to isolate the quasi-free
reaction. The spectator proton was identified by its momentum and flight direction thus yielding access to the associated
Fermi motion of the bound neutron. A comparison is carried out with Monte Carlo simulations based on two different parameterizations
of the deuteron wave function. Up to a Fermi momentum of roughly 150MeV/c no significant deviations between experimental and simulated data of various observables were found from which we conclude
that the deuteron can indeed be taken as a valid substitute for the neutron. 相似文献
65.
66.
Kilian Muñiz Prof. Dr. Claas H. Hövelmann Esther Campos‐Gómez José Barluenga Prof. Dr. José M. González Prof. Dr. Jan Streuff Martin Nieger Dr. 《化学:亚洲杂志》2008,3(4):776-788
The oxidative intramolecular diamination of alkenes with tethered ureas and related groups as the nitrogen source has been investigated both with the iodonium reagent IPy2BF4 (Py=pyridine) and under palladium catalysis in the presence of copper(II) bromide as a reoxidant. For terminal alkenes, the two procedures enable selective and high‐yielding transformations. Studies with deuterated material led to the conclusion that the reactions proceed through different stereochemical pathways. An advanced protocol for palladium‐catalyzed diamination through six‐membered‐ring annulation was also developed, and the first examples of the intramolecular diamination of internal alkenes are described. In this case, the same stereochemical outcome was observed for the iodonium‐promoted and palladium‐catalyzed transformations. On this basis, it was possible to determine the importance of aminohalogenated intermediates in both diamination reactions. Overall, the disclosed procedures broaden significantly the synthetic applicability of the oxidative intramolecular diamination of alkenes. 相似文献
67.
Hövelmann CH Streuff J Brelot L Muñiz K 《Chemical communications (Cambridge, England)》2008,(20):2334-2336
Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields. 相似文献
68.
Kilian A. Müller Carolin H. Nagel Prof. Dr. Alexander Breder 《European journal of organic chemistry》2023,26(2):e202201180
An expedient method for the synthesis of cyclic carbonates from homoallylic carbonic acid esters by means of photo-aerobic selenium-π-acid multicatalysis is reported. Until now, conceptually related methods commonly relied either on the stoichiometric addition of electrophiles onto the substrate's alkene moiety or the presence of pre-installed leaving groups in allylic position of said alkene to – in part, catalytically – initiate an intramolecular attack by an adjacent carbonic acid ester group. In sharp contrast, the current study shows that the C−C double bond of homoallylic carbonic acid esters can be directly activated by the catalytic interplay of a pyrylium dye and a diselane using ambient air as the sole oxidant and visible light as an energy source. 相似文献
69.
F. Kuchler E. Babcock M. Burghoff T. Chupp S. Degenkolb I. Fan P. Fierlinger F. Gong E. Kraegeloh W. Kilian S. Knappe-Grüneberg T. Lins M. Marino J. Meinel B. Niessen N. Sachdeva Z. Salhi A. Schnabel F. Seifert J. Singh S. Stuiber L. Trahms J. Voigt 《Hyperfine Interactions》2016,237(1):95
Permanent electric dipole moments (EDMs) arise due to the breaking of time-reversal or, equivalently, CP-symmetry. Although EDM searches have so far only set upper limits, which are many orders of magnitude larger than Standard Model (SM) predictions, the motivation for more sensitive searches is stronger than ever. A new effort at FRM-II incorporating 129Xe and 3He as a co-magnetometer can potentially improve the current limit. The noble gas mixture of 129Xe and 3He is simultanously polarized by spin-exchange optical pumping and then transferred into a high-performance magnetically shielded room. Inside, both species can freely precess in the presence of applied magnetic and electric fields. The precession signals are detected by LTc SQUID sensors. In EDM cells with silicon electrodes we observed spin lifetimes in excess of 2500 s without and with high-voltage applied. This meets one requirement to achieve our goal of improving the EDM limit on 129Xe by several orders of magnitude. 相似文献
70.
The COSY-TOF Collaboration S.?Jowzaee E.?Borodina H.?Clement E.?Doroshkevich R.?Dzhygadlo K.?Ehrhardt W.?Eyrich W.?Gast A.?Gillitzer D.?Grzonka F.?Hauenstein P.?Klaja L.?Kober K.?Kilian M.?Krapp M.?Mertens P.?Moskal J.?Ritman E.?RoderburgEmail author M.?R?der W.?Schroeder T.?Sefzick J.?Smyrski P.?Wintz P.?Wüstner 《The European Physical Journal A - Hadrons and Nuclei》2016,52(1):7