全文获取类型
收费全文 | 371篇 |
免费 | 26篇 |
国内免费 | 1篇 |
专业分类
化学 | 288篇 |
力学 | 5篇 |
数学 | 16篇 |
物理学 | 89篇 |
出版年
2023年 | 4篇 |
2022年 | 8篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2017年 | 7篇 |
2016年 | 25篇 |
2015年 | 10篇 |
2014年 | 4篇 |
2013年 | 16篇 |
2012年 | 21篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 8篇 |
2008年 | 13篇 |
2007年 | 16篇 |
2006年 | 23篇 |
2005年 | 13篇 |
2004年 | 13篇 |
2003年 | 17篇 |
2002年 | 11篇 |
2001年 | 10篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1997年 | 5篇 |
1995年 | 3篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1977年 | 3篇 |
1972年 | 2篇 |
1970年 | 2篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1967年 | 5篇 |
1966年 | 3篇 |
1965年 | 4篇 |
1963年 | 2篇 |
1962年 | 4篇 |
1961年 | 4篇 |
1959年 | 2篇 |
排序方式: 共有398条查询结果,搜索用时 15 毫秒
51.
52.
53.
54.
55.
H. -G. Kilian 《Colloid and polymer science》1985,263(1):30-34
It is known that the stress-strain behavior of real networks is quantitatively described by a van der Waals equation of state: the strain-energy function of these systems can be shown to depend upon the first strain-invariant only. With adequate deliberation, the second strain-invariant is identified as being related to “non-permanently crosslinked” elastic bodies. 相似文献
56.
Several metallocomplexes of tetrakis-carboxyphenylporphyrin (TCPP) were separated on fused-silica capillary using CZE with UV-VIS detection. Metalloporphyrins of Co(II), Cu(II), Mn(II), Ni(II), and Zn(II) were formed directly in TCPP solution with addition of Cd(II) to increase the formation reaction rate. The composition of BGE, its concentration, and pH were optimized to ensure the stability of complexes and proper resolution. In particular, the problem of signals' shape was investigated and discussed. The presence of beta-CD in borate buffer significantly improved separation efficiency and signal shapes due to formation of inclusion complexes. Under the best separation conditions (50 mM borate running buffer at pH 9 with addition of 2 mM beta-CD, 30 kV applied voltage) a separation of metal complexes with TCPP was accomplished in 16 min. 相似文献
57.
Brauer CS Craddock MB Kilian J Grumstrup EM Orilall MC Mo Y Gao J Leopold KR 《The journal of physical chemistry. A》2006,110(33):10025-10034
The Stark effect has been observed in the rotational spectra of several gas-phase amine-hydrogen halide complexes and the following electric dipole moments have been determined: H(3)(15)N-H(35)Cl (4.05865 +/- 0.00095 D), (CH(3))(3)(15)N-H(35)Cl (7.128 +/- 0.012 D), H(3)(15)N-H(79)Br (4.2577 +/- 0.0022 D), and (CH(3))(3)(15)N-H(79)Br (8.397 +/- 0.014 D). Calculations of the binding energies and electric dipole moments for the full set of complexes R(n)()(CH(3))(3)(-)(n)()N-HX (n = 0-3; X = F, Cl, Br) at the MP2/aug-cc-pVDZ level are also reported. The block localized wave function (BLW) energy decomposition method has been used to partition the binding energies into contributions from electrostatic, exchange, distortion, polarization, and charge-transfer terms. Similarly, the calculated dipole moments have been decomposed into distortion, polarization, and charge-transfer components. The complexes studied range from hydrogen-bonded systems to proton-transferred ion pairs, and the total interaction energies vary from 7 to 17 kcal/mol across the series. The individual energy components show a much wider variation than this, but cancellation of terms accounts for the relatively narrow range of net binding energies. For both the hydrogen-bonded complexes and the proton-transferred ion pairs, the electrostatic and exchange terms have magnitudes that increase with the degree of proton transfer but are of opposite sign, leaving most of the net stabilization to arise from polarization and charge transfer. In all of the systems studied, the polarization terms contribute the most to the induced dipole moment, followed by smaller but still significant contributions from charge transfer. A significant contribution to the induced moment of the ion pairs also arises from distortion of the HX monomer. 相似文献
58.
59.
P. Winter M. Wolke H.-H. Adam A. Budzanowski R. Czyżykiewicz D. Grzonka M. Janusz L. Jarczyk B. Kamys A. Khoukaz K. Kilian P. Klaja P. Moskal W. Oelert C. Piskor-Ignatowicz J. Przerwa J. Ritman T. Rożek T. Sefzick M. Siemaszko J. Smyrski A. Täschner P. Wüstner Z. Zhang W. Zipper 《Physics letters. [Part B]》2006
The total cross section of the reaction pp→ppK+K− has been measured at excess energies Q=10 MeV and 28 MeV with the magnetic spectrometer COSY-11. The new data show a significant enhancement of the total cross section compared to pure phase space expectations or calculations within a one boson exchange model. In addition, we present invariant mass spectra of two particle subsystems. While the K+K− system is rather constant for different invariant masses, there is an enhancement in the pK− system towards lower masses which could at least be partially connected to the influence of the Λ(1405) resonance. 相似文献
60.
M. Abdel-Bary K. -Th. Brinkmann H. Clement E. Doroshkevich S. Dshemuchadse A. Erhardt W. Eyrich H. Freiesleben A. Gillitzer R. Jäkel L. Karsch K. Kilian E. Kuhlmann K. Möller H. P. Morsch L. Naumann N. Paul C. Pizzolotto J. Ritman E. Roderburg P. Schönmeier W. Schroeder M. Schulte-Wissermann G. Y. Sun A. Teufel A. Ucar G. J. Wagner M. Wagner P. Wintz P. Wüstner P. Zupranski 《The European Physical Journal A - Hadrons and Nuclei》2006,29(3):353-361
The reaction
has been studied in a kinematically complete experiment at a single beam momentum
GeV/c (T = 759MeV). All four ejectiles have been detected in the large-acceptance time-of-flight spectrometer COSY-TOF. We analyzed
the data along the lines of the spectator model as a means to isolate the quasi-free
reaction. The spectator proton was identified by its momentum and flight direction thus yielding access to the associated
Fermi motion of the bound neutron. A comparison is carried out with Monte Carlo simulations based on two different parameterizations
of the deuteron wave function. Up to a Fermi momentum of roughly 150MeV/c no significant deviations between experimental and simulated data of various observables were found from which we conclude
that the deuteron can indeed be taken as a valid substitute for the neutron. 相似文献