全文获取类型
收费全文 | 374篇 |
免费 | 26篇 |
国内免费 | 1篇 |
专业分类
化学 | 291篇 |
力学 | 5篇 |
数学 | 16篇 |
物理学 | 89篇 |
出版年
2023年 | 4篇 |
2022年 | 11篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2017年 | 7篇 |
2016年 | 25篇 |
2015年 | 10篇 |
2014年 | 4篇 |
2013年 | 16篇 |
2012年 | 21篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 8篇 |
2008年 | 13篇 |
2007年 | 16篇 |
2006年 | 23篇 |
2005年 | 13篇 |
2004年 | 13篇 |
2003年 | 17篇 |
2002年 | 11篇 |
2001年 | 10篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1997年 | 5篇 |
1995年 | 3篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1986年 | 8篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1977年 | 3篇 |
1972年 | 2篇 |
1970年 | 2篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1967年 | 5篇 |
1966年 | 3篇 |
1965年 | 4篇 |
1963年 | 2篇 |
1962年 | 4篇 |
1961年 | 4篇 |
1959年 | 2篇 |
排序方式: 共有401条查询结果,搜索用时 15 毫秒
311.
C. Gemmel W. Heil S. Karpuk K. Lenz Ch. Ludwig Yu. Sobolev K. Tullney M. Burghoff W. Kilian S. Knappe-Grüneberg W. Müller A. Schnabel F. Seifert L. Trahms St. Bae?ler 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2010,57(3):303-320
We discuss the design and performance of a very sensitive low-field magnetometer based on the detection of free spin precession of gaseous, nuclear polarized 3He or 129Xe samples with a SQUID as magnetic flux detector. The device will be employed to control fluctuating magnetic fields and gradients in a new experiment searching for a permanent electric dipole moment of the neutron. Furthermore, with the detection of the free precession of co-located 3He/129Xe nuclear spins it can be used as ultra-sensitive probe for non-magnetic spin interactions, since the magnetic dipole interaction (Zeeman-term) drops out. Characteristic spin precession times T2 * of up to 60 h were measured. The achieved signal-to-noise ratio of more than 5000:1 leads to an expected sensitivity level (Cramer-Rao lower bound) of δB≈1 fT after an integration time of 220 s and of δB≈10-4 fT after one day. By means of a co-located 3He/129Xe magnetometer, noise sources inherent in the magnetometer could be investigated, showing that CRLB is fulfilled, at least down to δB≈10-2 fT. The reason for such a high sensitivity is that free precessing 3He (129Xe) nuclear spins are almost completely decoupled from the environment. Therefore, this type of magnetometer is particularly attractive for precision field measurements where long-term stability is required. 相似文献
312.
S. Abd El-Samad R. Bilger K. -Th. Brinkmann H. Clement M. Dietrich E. Doroshkevich S. Dshemuchadse K. Ehrhardt A. Erhardt W. Eyrich A. Filippi H. Freiesleben M. Fritsch R. Geyer A. Gillitzer J. Hauffe D. Hesselbarth R. Jaekel B. Jakob L. Karsch K. Kilian J. Kress E. Kuhlmann S. Marcello S. Marwinski R. Meier K. M?ller H. P. Morsch L. Naumann J. Ritman E. Roderburg P. Sch?nmeier M. Schulte-Wissermann W. Schroeder F. Stinzing G. Y. Sun J. W?chter G. J. Wagner M. Wagner U. Weidlich A. Wilms S. Wirth G. Zhang P. Zupranski 《The European Physical Journal A - Hadrons and Nuclei》2009,42(2):159-161
Data accumulated recently for the exclusive measurement of the pp $ \rightarrow$ pp $ \pi^{+}_{}$ $ \pi^{-}_{}$ reaction at a beam energy of 0.793GeV using the COSY-TOF spectrometer have been analyzed with respect to possible events from the pp $ \rightarrow$ nn $ \pi^{+}_{}$ $ \pi^{+}_{}$ reaction channel. The latter is expected to be the only $ \pi$ $ \pi$ production channel, which contains no major contributions from resonance excitation close to threshold and hence should be a good testing ground for chiral dynamics in the $ \pi$ $ \pi$ production process. No single event has been found, which meets all conditions for being a candidate for the pp $ \rightarrow$ nn $ \pi^{+}_{}$ $ \pi^{+}_{}$ reaction. This gives an upper limit for the cross-section of 0.16μb (90% C.L.), which is more than an order of magnitude smaller than the cross-sections of the other two-pion production channels at the same incident energy. 相似文献
313.
314.
Cover Picture: Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions (Angew. Chem. Int. Ed. 1/2016)
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
315.
Solving the Hydrogen and Lithium Substructure of Poly(triazine imide)/LiCl Using NMR Crystallography
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Maria B. Mesch Kilian Bärwinkel Yaşar Krysiak Dr. Charlotte Martineau Prof. Dr. Francis Taulelle Prof. Dr. Reinhard B. Neder Priv.‐Doz. Dr. Ute Kolb Prof. Dr. Jürgen Senker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(47):16878-16890
Poly(triazine imide) with incorporated lithium chloride has recently attracted substantial attention due to its photocatalytic activity for water splitting. However, an apparent H/Li disorder prevents the delineation of structure–property relationships, for example, with respect to band‐gap tuning. Herein, we show that through a combination of one‐ and two‐dimensional, multinuclear solid‐state NMR spectroscopy, chemical modelling, automated electron diffraction tomography, and an analysis based on X‐ray pair distribution functions, it is finally possible to resolve the H/Li substructure. In each cavity, one hydrogen atom is bound to a bridging nitrogen atom, while a second one protonates a triazine ring. The two lithium ions within each cavity are positioned between two nitrogen atoms of neighbouring triazine rings. The thereby induced local dipole moments cause slight buckling of the framework and lateral displacements of the Cl? ions at a coherence length below 2 nm. Nevertheless, the average structure conforms to space group P212121. In this way, we demonstrate that, in particular, the above‐mentioned techniques allow for smart interplay in delineating the real structure of PTI/LiCl. 相似文献
316.
317.
318.
Dr. José A. Souto Yolanda González Dr. Alvaro Iglesias Debora Zian Anton Lishchynskyi Prof. Dr. Kilian Muñiz 《化学:亚洲杂志》2012,7(5):1103-1111
A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups. 相似文献
319.
Dr. Claudio Martínez Prof. Dr. Kilian Muñiz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(22):7367-7370
New palladium(II)–phthalimidato complexes have been synthesized, isolated, and structurally characterized. As demonstrated from over 30 examples, they constitute superior catalysts for oxidative amination reactions of alkenes with phthalimide as the nitrogen source. This work streamlines vicinal difunctionalization of alkenes and provides access to significantly improved and experimentally simplified synthetic protocols. 相似文献
320.
Julia Schneider Kilian M. Krebs Dr. Sarah Freitag Dr. Klaus Eichele Dr. Hartmut Schubert Prof. Dr. Lars Wesemann 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(28):9812-9826
A series of benzyl(diphenylphosphino) and o‐phenyl(diphenlyphosphino) substituted germylenes and plumbylenes were synthesized by nucleophilic substitution between the respective lithium reagent and tetrylene halide. The Lewis pairs were characterized by X‐ray crystallography and NMR spectroscopy. The reactivity of the tetrylenes was investigated with respect to azide addition. In the germylene case, the germaniumimide was formed as the kinetically controlled product, which rearranges upon heating to give the phosphinimide. The stannylene and plumbylene derivatives react with adamantylazide to give the azide adducts. 1‐Pentene reacts diastereoselectively with the phosphagermirane to give a cyclic addition product. Trimethysilylacetylene shows an addition with the benzylphosphino‐substituted germylene and plumbylene to give the cycloheteropentene molecules. The addition product between phenylacetylene and the four membered Ge‐P adduct shows after addition at room temperature a 1,4‐phenylmigration to give a cyclic phosphine. Alkylnitrene insertion into a Ge?C bond of the alkyne addition product of the phosphagermirane was found in reaction with adamantylazide. 相似文献