Optical Characterization of rf-Magnetron Sputtered Nanostructured SnO2 Thin Films

Tin oxide （Sn02 ） thin films are deposited by rf-magnetron sputtering and annealed at various temperatures in the range of 100-500 ℃ for 15 min. Raman spectra of the annealed films depict the formation of a small amount of SnO phase in the tetragonal Sn02 matrix, which is verified by x-ray diffraction. The average particle size is found to be about 20-30 nm, as calculated from x-ray peak broadening and SEM images. Various optical parameters such as optical band gap energy, refractive index, optical conductivity, carrier mobility, carrier concentration etc. are determined from the optical transmittance and reflectance data recorded in the wavelength range 250-2500 nm. The results are analyzed and compared with the data in the literature.     

In vitro analysis of immersed human tissues by Raman microspectroscopy

Raman microspectroscopy is a powerful tool for the analysis of tissue sections, providing a molecular map of the investigated samples. Nevertheless, data pre‐processing and, particularly, the removal of the broad background to the spectra remain problematic. Indeed, the physical origin of the background has not been satisfactorily determined. Using 785 nm as source in a confocal geometry, it is demonstrated for the example of the protein kappa‐elastin that the background and resulting quality of the recorded spectrum are dependent on the morphology of the sample. Whereas a fine powder yields a dominant broad background, compressed pellets and solution‐cast thin films produce, respectively, improved quality spectra and significantly reduced spectral background. As the chemical composition of the samples is identical, the background is ascribed to stray light due to diffuse scattering rather than an intrinsic photoluminescence. The recorded spectra from a tissue sample exhibit a large and spatially variable background, resulting in poorly defined spectral features. A significant reduction of the background signal as well as improvement of the spectral quality is achieved by immersion of the sample in water and measurement with an immersion objective. The significant improvement in signal to background is attributed to a reduction of the diffuse scattering due to a change in the effective morphology as a result of an improved index matching at the water/tissue interface compared to the air/tissue interface. Compared to sections measured in air, the background is reduced to that of the water, and pre‐processing is reduced to the subtraction of the substrate and water signal and correction for the instrument response, both of which are highly reproducible. Data pre‐processing is thus greatly simplified and the results significantly more reliable. Copyright © 2010 John Wiley & Sons, Ltd.     

An Orbital-Overlap Complement to Atomic Partial Charge

Atomic partial charges are widely used to predict reactivity. Partial charge alone is often insufficient: the carbons of benzene and cyclobutadiene, or those of diamond, graphene, and C₆₀, possess nearly identical partial charges and very different reactivities. Our atomic overlap distance complements computed partial charges by measuring the size of orbital lobes that best overlap with the wavefunction around an atom. Compact, chemically stable atoms tend to have overlap distances smaller than chemically soft, unstable atoms. We show here how combining atomic charges and overlap distances captures trends in aromaticity, nucleophilicity, allotrope stability, and substituent effects. Applications to recent experiments in organic chemistry (counterintuitive Lewis base stabilization of alkenyl anions in anionic cyclization) and nanomaterials chemistry (facile doping of the central atom in Au₇ hexagons) illustrate this combination's predictive power.     

On the onset of bifurcation and nonlinear characterization of vortex-induced vibrations under varying initial conditions

Nonlinear Dynamics - We perform numerical simulations to investigate the hysteresis phenomenon near the bifurcation points of the synchronization region leading to vortex-induced vibrations. We...     

The diversity in the applications of partial least squares: an overview

Advances in technology make it happen to have massive amount of information in the form of multiple variables per object. The use of multivariate approaches for modeling the real‐life phenomena is natural in such situation. There are numerous multivariate approaches in the literature, and its a challenge to stay updated on the possibilities. Partial least squares (PLSs) are one of the many modeling approaches for high‐throughput data, and its use in different fields to address the variety of problems has been increased in recent years. We therefore present an overview of PLS's applications. The objective of this paper is to give a comprehensive overview on the advances in PLS algorithm together with its applications for regression, classification, variable selection, and survival analysis problems covering genomics, chemometrics, neuroinformatics, process control, computer vision, econometric, environmental studies, and so on. We have mainly presented different PLS approaches and their applications, so that the reader can easily get an understanding of possibility to use PLS for their own field. For further reading, literature references together with software availability are provided. Copyright © 2015 John Wiley & Sons, Ltd.     

Entropy production in the flow over a swirling stretchable cylinder

In the present work, the entropy generation due to the heat transfer and fluid friction irreversibility is investigated numerically for a three-dimensional flow induced by rotating and stretching motion of a cylinder. The isothermal boundary conditions are taken into account for the heat transfer analysis. The similarity transformations are utilized to convert the governing partial differential equations to ordinary differential equations. Resulting nonlinear differential equations are solved using a numerical scheme. Expressions for the entropy generation number, the Nusselt number and the Bejan number are obtained and discussed through graphs for various physical parameters. An analysis has been made to compare the heat transfer irreversibility with fluid friction irreversibility using the expression of the Bejan number. It is found that the surface is a durable source of irreversibility and the curvature of cylinder is to enhance the fluid friction irreversibility.     

Measurement of neutron fluence with CR-39 using a UV spectrophotometer

Measurement of the correct neutron fluence in various energy intervals in and around the neutron sources is important for the purpose of personnel and environmental neutron dosimetry. In the present paper we present a method for the measurement of neutron fluence using a CR-39 plastic track detector. The samples exposed to fission neutrons from a reactor with 10¹²– fluence and to fast neutrons from a ²⁴¹Am–Be source with a fluence of were etched for 14 time intervals starting from 10 to 570 min in 6 N NaOH at . The etched samples were exposed to the monochromatic light signal from an iodine–tungsten lamp and the transmittance was measured after each etching time interval using a UV Spectrophotometer. An exponential decay of the transmittance has been observed with increasing etching time. The behaviour of the fission neutrons having four different values of fluence has been observed to be distinctly different from that of the fast neutrons. It has also been observed that there is a linear relationship between the transmittance decay constant and fission neutron fluence.