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1.
An admissible minimax estimator of a bounded scale-parameter in a subclass of the exponential family under scale-invariant squared-error loss 总被引:3,自引:0,他引:3
Mohammad Jafari Jozani Nader Nematollahi Khalil Shafie 《Statistics & probability letters》2002,60(4):437-444
A subclass of the scale-parameter exponential family is considered and for the rth power of the scale parameter, which is lower bounded, an admissible minimax estimator under scale-invariant squared-error loss is presented. Also, an admissible minimax estimator of a lower-bounded parameter in the family of transformed chi-square distributions is given. These estimators are the pointwise limits of a sequence of Bayes estimators. Some examples are given. 相似文献
2.
Khalil Farhadi Ramin Maleki Rouhollah Hosseinzadeh Yamchi Hashem Sharghi Mojtaba Shamsipur 《Analytical sciences》2004,20(5):805-809
[5,10,15,20-Tetrakis(4-N,N-dimethylaminobenzene)porphyrinato]Mn(III) acetate (MnTDPAc) was applied as an ionophore for an iodide-selective PVC membrane electrode. The influences of the membrane composition, pH of the test solution and foreign ions on the electrode performance were investigated. The sensor exhibited not only excellent selectivity to iodide ion compared to Cl- and lipophilic anions such as ClO4- and salicylate, but also a Nernstian response with a slope of -59.4 +/- 1.2 mV per decade for iodide ions over a wide concentration range from 1.0 x 10(-2) to 7.5 x 10(-6) M at 25 degrees C. The potentiometric response was independent of the pH of the solution in the pH range of 2 - 8. The electrode could be used for at least 2 months without any considerable divergence in the potential. Good selectivity for iodide ion, a very short response time, simple preparation and relatively long-term stability were the silent characteristics of this electrode. It was successfully used as an indicator electrode in the potentiometric titration of iodide ions, and also in the determination of iodide from seawater samples and drug formulations. 相似文献
3.
4.
Abdel Raouf F. Elhefnawy Galal M. Moatimid Abd Elmonem Khalil Elcoot 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2004,86(2):63-91
The nonlinear electrohydrodynamic stability of
cylindrical interface, supporting surface charge, among two
conducting fluids is investigated. The two fluids are subjected to
a radial electric field. The analysis based on the multiple scale
technique. It is shown that the evolution of the amplitude is
governed by two partial differential equations. These equations
are combined to yield two alternate Schrödinger equations with
cubic nonlinearity. One of which calculates the nonlinear cutoff
electric field, separating stable and unstable disturbances, while
the other is used to analyze the stability of the system. The
stability criteria are analytically discussed and numerically
confirmed. Numerical calculations resulted in set of graphs to
indicate the stability picture of the considered system. 相似文献
5.
Khalil MM Mohamed HA El-Medani SM Ramadan RM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1341-1347
Reaction of Cr(CO)(6) with 2-(2'-pyridyl)benzimidazole (pbiH) under reduced pressure resulted in the formation of the dinuclear complex [Cr(2)(CO)(6)(pbiH)(2)]. Infra-red (IR) spectroscopy revealed the presence of terminal and bridge Cr-CO bonds. Interaction of M(CO)(6), M=Cr, Mo and W, with pbiH in the presence of 2,2'-bipyridine (bpy) gave the tetracarbonyl complexes [M(CO)(4)(pbiH)].bpy. Spectroscopic studies of the complexes indicated the presence of hydrogen bonding between the bpy nitrogen and the NH group of pbiH. Reactions of M(CO)(6) with pbiH in the presence of PPh(3) gave the tricarbonyl monosubstituted derivatives [M(CO)(3)(PPh(3))(pbiH)]. The spectroscopic studies of the complexes suggested the proposed structures. 相似文献
6.
Phytochemical investigation of the methanol extract of Euchresta formosana resulted in the isolation of thirty-four compounds. Compounds 1, 3-12, 15, 27, 29 and 32-24 were isolated from this species for the first time. These compounds were identified by spectral analyses and tested for antiplatelet aggregation and anti-HIV activities. Among these compounds, tectorigenin (1), 3',4',5-trihydroxyisoflavone (3), and euchretin F (19) were the most effective antiplatelet aggregation compounds; they inhibited both AA- (arachidonic acid) and collagen-induced platelet aggregation. Meanwhile, flemiphyllin (B), quercetin (13), euchretin M (23), and formosanatin C (26) inhibited HIV replication in H9 lymphocyte cells. 相似文献
7.
Ya‐Ching Shen Yun‐Sheng Lin Shaw‐Man Hsu Ashraf Taha Khalil Shih‐Sheng Wang Ching‐Te Chien Yao‐Haur Kuo Chang‐Hung Chou 《Helvetica chimica acta》2007,90(7):1319-1329
The phytochemical investigation of the more polar fractions from the leaves and twigs of Taxus sumatrana (Taxaceae) afforded five new taxane diterpene esters, tasumatrols P–T ( 1 – 5 ) possessing an 11(15→1),11(10→9)‐diabeotaxane skeleton. Compounds 1, 4 , and 5 contain an α‐hydroxy group at C(14), while 3 has no OH group at either C(13) or C(14). Compound 2 is a natural 4,5‐acetonide derivative, while 4 has an unusual spiro‐connected 2‐hydroxy‐2‐phenyl‐1,3‐dioxolane ring. Ten known taxoids, were also isolated in the course of the chromatographic fractionation. Five additional new O‐acetyl derivatives 3a, 4a, 4b, 5a , and 5b were prepared from the taxanes 3 – 5 . The structures of all new compounds were established on the basis of their spectroscopic analyses. Compound 1 showed mild cytotoxic activity against human Hela and Daoy tumor cells. 相似文献
8.
M. S. Masoud E. A. Khalil E. El-Sayed El-Shereafy S. A. El-Enein 《Journal of Thermal Analysis and Calorimetry》1990,36(3):1033-1038
The thermal behaviour of the entitled nickel(II) and copper(II) complexes of ¯4-acetylamino-2-hydroxy-5-methyl azobenzene has been studied by means of differential thermal analysis (DTA), thermogravimetry (TG), X-ray powder diffraction, IR and electrical conductivity. A light has been thrown on the nature of interaction of the solvents of crystallization with the host complex. Some of the kinetic parameters are calculated and discussed. 相似文献
9.
Tarek A. Salama Abdel-Aziz S. El-Ahl Abdel-Galil M. Khalil Margret M. Girges Bernd Lackner Christian Steindl Saad S. Elmorsy 《Monatshefte für Chemie / Chemical Monthly》2003,20(5):1241-1252
Several new 1-aryl-, aralkyl-, and heteroaryl-5-(4-phenylbuta-1,3-dienyl)tetrazole derivatives and annulated tetrazole derivatives were efficiently and regiospecifically prepared in nearly quantitative yield via a facile one step reaction of dienones with a combination of tetrachlorosilane and sodium azide in acetonitrile under mild conditions. A complete structure assignment of three representative examples of the tetrazoles was achieved by advanced 2D NMR measurements including COSY, TOCSY, HSQC, HMBC, NOESY, and ROESY experiments. 相似文献
10.
The [Et4N][M(CO)5SCOPh] complexes (1a, M = Mo; 2a, M = W) have been prepared at ambient temperatures by reacting the photogenerated M(CO)5 THF intermediate with [Et4N][SCOPh] in THF. Kinetic studies of the reactions of the anions [M(CO)5SCOPh]– with the tri(iso-propyl)phosphite (L) ligand under pseudo-first-order conditions indicate that these reactions are first-order in substrate and are independent of the P(OPr-i)3 concentration. It is thus envisaged that these CO substitutions proceed via a mechanism which involves initial cis-M—CO bond-breaking, followed by fast attack of the incoming nucleophile on the resulting intermediate to give [cis-M(CO)4{P(O-Pri)3}SCOPh]–. This facile displacement of cis-CO indicates the labilizing nature of the thiobenzoate ligand, most probably by virtue of distal oxygen atom participation. Activation parameters for the reactions are: [M(CO)5SCOPh]– + L cis-[M(CO)4(L)SCOPh]– + CO M = Mo, H
= 24.6(2) kcal mol–1, S
= 8.2(6) eu; M = W, H
= 28.4(2) kcal mol–1, S
= 11.3(5) eu. Kinetic data and the mechanism of these ligand-substitutions are discussed. 相似文献