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101.
102.
This work establishes an asymptotic bound on the characteristic function of signed linear serial rank statistics. The result is obtained under rather general conditions including the important case of van der Waerden scores. It generalizes the result of Seoh (1983, Ph.D. Thesis, Department of Mathematics, Indiana University) and constitutes an essential step to the elaboration of Berry-Esséen's bounds and the establishment of Edgeworth expansions. These statistics constitute a natural tool for testing the hypothesis of white noise with a symmetrical (unspecified) distribution in comparison to other alternative hypothesis of serial dependence. 相似文献
103.
Ralph E. Schlief Wlodzimierz Jarzeba Khalid A. M. Thakur Joseph C. Alfano Alan E. Johnson Paul F. Barbara 《Journal of Molecular Liquids》1994,60(1-3):201-220
Ultrafast pump - probe measurements have been made on the benzene - bromine atom charge transfer (CT) complex in CCl4 and cyclohexane solutions. Ultrafast optical excitation of the CT band of the complex yields an ion pair, which is comprised of a benzene cation and a bromide anion. The rate of charge recombination between the bromide and the benzene cation in the ion pair has been observed to be much faster than the rate of diffusion apart. The charge recombination rate is accelerated at high benzene concentrations as a result of the formation of a benzene dimer cation - bromide ion pair which undergoes much faster charge recombination than the benzene cation - bromide ion pair. 相似文献
104.
Letn be an integer greater than one. Our main result, called the “Structure Theorem” is that a set that containsn−1 disjoint continua that are cut by a single line cannot be ann-point set, that is, a set that meets every line in preciselyn points. This theorem unifies and significantly improves upon a number of known theorems. The second part of the paper is
devoted to several theorems that address the question when a set that meets every line in at mostn points can be extended to ann-point set. These theorems also highlight the sharpness of the Structure Theorem. 相似文献
105.
Fatima Javed Saqib Ali Saira Shahzadi Nasir Khalid Saira Tabassum Imran Khan Saroj K. Sharma Kushal Qanungo 《中国化学会会志》2015,62(8):728-738
New organotin(IV) complexes have been synthesized by treating potassium o‐isopropyl carbonodithioate with R2SnCl2/R3SnCl in 1 : 2/1 : 1 M/L ratio. All complexes have been characterized by IR and NMR (1H, 13C) spectroscopy. IR results shows that ligand acts as bidentate which is also confirmed by semi‐empirical study. NMR data reveals four coordinated geometry in solution. Computed positive heat of formation shows that complex 5 is thermodynamically unstable. UV/visible spectroscopy was used to assess the mode of interaction and binding of the complexes with DNA which shows that complex 5 exhibits higher binding constant as compared to complex 3 . In protein kinase inhibition assay, compound 3 was found most active, while other biological activities shows that triorganotin(IV) complexes are biologically more active as compared to diorganotin(IV) complexes. 相似文献
106.
107.
Tariq M. Sirajuddin M. Ali S. Khalid N. Shah N. A. 《Russian Journal of General Chemistry》2017,87(11):2690-2698
Six new organotin(IV) carboxylates, [Me2SnL2] (1), [n-Bu2SnL2] (2), [n-Oct2SnL2] (3), [Me3SnL] (4), [n-Bu3SnL] (5) and [Ph3SnL] (6), where L = 3-(4-ethoxyphenyl)-2-methylacrylate, have been synthesized and characterized by FT-IR, NMR spectroscopy and elemental analyses. The synthesized compounds were tested for in vitro antibacterial and antifungal activities. The complexes 4–6 demonstrated higher activity than the complexes 1–3. UV-Vis absorption spectroscopy indicated that the ligand and its complexes interacted with DNA via partial intercalation as well as minor groove binding.
相似文献108.
The commensurability index between two subgroups A,B of a group G is [A:A∩B][B:A∩B]. This gives a notion of distance among finite index subgroups of G, which is encoded in the p-local commensurability graphs of G. We show that for any metabelian group, any component of the p-local commensurabilty graph of G has diameter bounded above by 4. However, no universal upper bound on diameters of components exists for the class of finite solvable groups. In the appendix we give a complete classification of components for upper triangular matrix groups in GL(2,𝔽q). 相似文献
109.
The gelation kinetics of aqueous solutions of acrylamideacrylic acid copolymers in the presence of chromium ions was studied with different rheometers. The gel time is found to vary with the principle of the apparatus because of a low shear dependence of the elongation of the macromolecules. The variations of the gel time with the experimental conditions of the gel preparation were investigated and we conclude that the gelation is governed by the oligornerization kinetics of the chromium ions which are instantaneously, complexated by the carboxylate groups of the polymer. The variation laws of the gel time and of the elastic modulus with chromium and polymer concentrations, temperature and ionic strength are in qualitative agreement with the structure of the temporary network of the semi-dilute solutions of these copolymers. 相似文献
110.
For transient excitation, it is well known that the Singularity Expansion Method (SEM) is a late time technique that is not in general suitable for early time. Lossy dielectric slab studies, with bounded integrable finite-duration input signal, have shown that the SEM representation for early time requires an additional branch cut contribution and a modification of the SEM series for completeness. Other researchers indicated that the SEM representation is not complete for most cases of practical interest and that it may not converge for early time. In this paper, we present an approach, using the input signal, to obtain a convergent SEM series that is valid for early as well as for late time. In this approach the branch cut contribution is not needed and instead we have pole contributions form the input signal and a modified SEM series. In addition, two forms of SEM representations will be presented, the traditional form and the time varying coupling coefficient form. Furthermore, the interaction and the effect of the input signal choice on the SEM representation will be clarified. This will be done for a dielectric slab backed by a perfect conductor. 相似文献