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91.
Khaled SM Sui R Charpentier PA Rizkalla AS 《Langmuir : the ACS journal of surfaces and colloids》2007,23(7):3988-3995
Inorganic-polymer nanocomposites are of significant interest for emerging materials due to their improved properties and unique combination of properties. Methacrylic acid (MA), a functionalization agent that can chemically link TiO2 nanomaterials (n-TiO2) and polymer matrix, was used to modify the surface of n-TiO2 using a Ti-carboxylic coordination bond. Then, the double bond in MA was copolymerized with methyl methacrylate (MMA) to form a n-TiO2-PMMA nanocomposite. The resulting n-TiO2-PMMA nanocomposite materials were characterized by using thermal analysis, electron microscopy, and elemental analysis. The dynamic mechanical properties (Young's and shear modulus) were measured using an ultrasonic pulse technique. The electron microscopy results showed a good distribution of the nanofillers in the polymer matrix. The glass transition temperature, thermal degradation temperature, and dynamic elastic moduli of the nanocomposites were shown to increase with an increase in the weight percentage of nanofibers in the composite. The resulting nanocomposites exhibited improved elastic properties and have potential application in dental composites and bone cements. 相似文献
92.
The geometry, frequency and intensity of the vibrational bands of 8-hydroxyquinoline and its 5,7-dichloro, 5,7-dibromo, 5,7-diiodo
and 5,7-dinitro derivatives were obtained by the density functional theory (DFT) calculations with Becke3-Lee-Parr (B3LYP)
functional and 6-31G* basis set. The effects of chloride, bromide, iodide and nitro substituent on the vibrational frequencies
of 8-hydroxyquinoline have been investigated. The assignments have been proposed with aid of the results of normal coordinate
analysis. The observed and calculated spectra are found to be in good agreement.
相似文献
93.
An effective one‐pot, convenient process for the synthesis of 1‐ and 5‐substituted 1H‐tetrazoles from nitriles and amines is described using1,4‐dihydroxyanthraquinone–copper(II) supported on Fe3O4@SiO2 magnetic porous nanospheres as a novel recyclable catalyst. The application of this catalyst allows the synthesis of a variety of tetrazoles in good to excellent yields. The preparation of the magnetic nanocatalyst with core–shell structure is presented by using nano‐Fe3O4 as the core, tetraethoxysilane as the silica source and poly(vinyl alcohol) as the surfactant, and then Fe3O4@SiO2 was coated with 1,4‐dihydroxyanthraquinone–copper(II) nanoparticles. The new catalyst was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, dynamic light scattering, thermogravimetric analysis, vibration sample magnetometry, X‐ray photoelectron spectroscopy, nitrogen adsorption–desorption isotherm analysis and inductively coupled plasma analysis. This new procedure offers several advantages such as short reaction times, excellent yields, operational simplicity, practicability and applicability to various substrates and absence of any tedious workup or purification. In addition, the excellent catalytic performance, thermal stability and separation of the catalyst make it a good heterogeneous system and a useful alternative to other heterogeneous catalysts. Also, the catalyst could be magnetically separated and reused six times without significant loss of catalytic activity. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
94.
Omid Jahanmahin Mohammad Mehdi Montazer Rahmati Toraj Mohammadi Jaber Babaee Arash Khosravi 《Chemical Papers》2016,70(7):913-925
In this study, a novel flat-type synergic-supported liquid membrane was evaluated with a mixture of N-methyl-N,N,N-trioctylammonium chloride (Aliquat 336) and tributyl phosphate (TBP) as the carrier and kerosene as the diluent to remove Cr(VI) from synthetic waste water. The main parameters involved in the process were identified and optimised. The parameters were divided into two groups, those that were independent and those having an interaction. The parameters of the carrier/kerosene volumetric proportion and stirring rate were optimised individually due to their nature. The optimal values of these parameters were 0.5 and 500 min?1, respectively, for a constant carrier/kerosene ratio and stirring rate in the designed experiments using the response surface method (RSM). The four parameters of TBP/Aliquat 336, chromium concentration in the feed phase, feed and product pH were optimised using RSM; it was observed that the TBP/Aliquat 336 ratio, feed pH, pH of the stripping phase and interaction of this parameter with feed concentration have the most important effects on the removal of Cr(VI). The optimal levels of these parameters were 0.61, 71.75 mg L?1, 3.5 and 12.66 for the ratio of TBP/Aliquat 336, feed chromium concentration, pH of the feed and pH of the product, respectively. An experimental removal rate of 94.63 % at the optimized levels was obtained. 相似文献
95.
Highly sensitive catalytic determination of molybdenum 总被引:1,自引:0,他引:1
A novel, highly sensitive, selective, and simple kinetic method was developed for the determination of Mo(VI) based on its catalytic effect on the oxidation of 1-amino-2-naphthol-4-sulfonic acid (ANSA) with H2O2. The reaction was followed spectrophotometrically by tracing the oxidized product at 465 nm after 30 min of mixing the reagents. The optimum reaction conditions were: 10 mmol l−1 ANSA, 50 mmol l−1 H2O2, 100 mmol l−1 acetate buffer of pH 5.0 ± 0.05 and at 40 °C. Addition of 200 μg ml−1 diethylenetriaminepentaacetic acid (DTPA) conferred high selectivity for the proposed method. Following the recommended procedure, Mo(VI) could be determined with a linear calibration graph up to 2.5 ng ml−1 and a detection limit, based on the 3Sb-criterion, of 0.027 ng ml−1. The unique sensitivity and selectivity of the implemented method allowed its direct application to the determination of Mo(VI) in natural and industrial waste water. The method was validated by comparison with the standard ETAAS method. Moreover, published catalytic-spectrophotometric methods for the determination of molybdenum were reviewed. 相似文献
96.
A simple method for the synthesis of 6-thioxo-[1,3,5]-triazinane-2,4-dione derivatives was reported. The electrogenerated cyanomethyl base obtained from electroreduction of neat acetonitrile assisted the reaction between thiourea derivatives and alkyl or aryl isocyanate. This protocol had the advantage of giving good yields using mild conditions. The obtained products have been identified by spectroscopic data, mass spectrometry, and high-resolution mass spectra or elemental analysis. 相似文献
97.
The vapor pressures and osmotic coefficients of solutions of (R4N)2[MoS4] (R = ethyl, n-propyl and n-butyl) in acetone have been measured by head space-gas chromatography (HS-GC). Experimental data for the osmotic coefficients have been expressed by three thermodynamic models including the ionic interaction model of Pitzer, the electrolyte non-random two liquid (e-NRTL) model and the non-random factor (NRF) model. The ability of the models to fit the osmotic coefficient was compared on the basis of the standard deviation of the fittings. The results show that the considered models provide reliable results, but the Pitzer's model gives better results than the NRTL and the NRF methods, especially in the dilute region. 相似文献
98.
A number of groups have utilized molecular dynamics (MD) to calculate slow-motional electron paramagnetic resonance (EPR) spectra of spin labels attached to biomolecules. Nearly all such calculations have been based on some variant of the trajectory method introduced by Robinson, Slutsky and Auteri (J. Chem. Phys. 1992,96, 2609-2616). Here we present an alternative approach that is specifically adapted to the diffusion operator-based stochastic Liouville equation (SLE) formalism that is also widely used to calculate slow-motional EPR line shapes. Specifically, the method utilizes MD trajectories to derive diffusion parameters such as the rotational diffusion tensor, diffusion tilt angles, and expansion coefficients of the orienting potential, which are then used as direct inputs to the SLE line shape program. This approach leads to a considerable improvement in computational efficiency over trajectory-based methods, particularly for high frequency, high field EPR. It also provides a basis for deconvoluting the effects of local spin label motion and overall motion of the labeled molecule or domain: once the local motion has been characterized by this approach, the label diffusion parameters may be used in conjunction with line shape analysis at lower EPR frequencies to characterize global motions. The method is validated by comparison of the MD predicted line shapes to experimental high frequency (250 GHz) EPR spectra. 相似文献
99.
Mohy eldinAbdelFattah Samir ElRayes ElSayedAhmed Soliman Anthony Linden Khaled Abou‐Hadeed Hans‐Jürgen Hansen 《Helvetica chimica acta》2005,88(5):1085-1101
3‐(Phenylsulfonyl)benzo[a]heptalene‐2,4‐diols 1 can be desulfonylated with an excess of LiAlH4/MeLi?LiBr in boiling THF in good yields (Scheme 6). When the reaction is run with LiAlH4/MeLi, mainly the 3,3′‐disulfides 6 of the corresponding 2,4‐dihydroxybenzo[a]heptalene‐3‐thiols are formed after workup (Scheme 7). However, the best yields of desulfonylated products are obtained when the 2,4‐dimethoxy‐substituted benzo[a]heptalenes 2 are reduced with an excess of LiAlH4/TiCl4 at ?78→20° in THF (Scheme 10). Attempts to substitute the PhSO2 group of 2 with freshly prepared MeONa in boiling THF led to a highly selective ether cleavage of the 4‐MeO group, rather than to desulfonylation (Scheme 13). 相似文献
100.
The problem of coupled heat and mass transfer by natural convection from a semi-infinite inclined flat plate in the presence
of an external magnetic field and internal heat generation or absorption effects is formulated. The plate surface has a power-law
variation of both wall temperature and concentration and is permeable to allow for possible fluid wall suction or blowing.
The resulting governing equations are transformed using a similarity transformation and then solved numerically by an implicit,
iterative, finite-difference scheme. Comparisons with previously published work are performed and good agreement is obtained.
A parametric study of all involved parameters is conducted and a representative set of numerical results for the velocity
and temperature profiles as well as the skin-friction parameter, average Nusselt number, and the average Sherwood number is
illustrated graphically to show typical trends of the solutions.
Received on 26 October 1998 相似文献