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101.
If G is a graph on n vertices and r ≥ 2, we let mr(G) denote the minimum number of complete multipartite subgraphs, with r or fewer parts, needed to partition the edge set, E(G). In determining mr(G), we may assume that no two vertices of G have the same neighbor set. For such reducedgraphs G, we prove that mr(G) ≥ log2 (n + r − 1)/r. Furthermore, for each k ≥ 0 and r ≥ 2, there is a unique reduced graph G = G(r, k) with mr(G) = k for which equality holds. We conclude with a short proof of the known eigenvalue bound mr(G) ≥ max{n+ (G, n−(G)/(r − 1)}, and show that equality holds if G = G(r, k). © 1996 John Wiley & Sons, Inc. 相似文献
102.
103.
Ana Isabel González Flórez Eike Mucha Dr. Doo‐Sik Ahn Sandy Gewinner Dr. Wieland Schöllkopf Prof. Dr. Kevin Pagel Dr. Gert von Helden 《Angewandte Chemie (International ed. in English)》2016,55(10):3295-3299
Here we present a combined experimental and theoretical study on the secondary structure of isolated proteins as a function of charge state. In infrared spectra of the proteins ubiquitin and cytochrome c, amide I (C=O stretch) and amide II (N–H bend) bands can be found at positions that are typical for condensed‐phase proteins. For high charge states a new band appears, substantially red‐shifted from the amide II band observed at lower charge states. The observations are interpreted in terms of Coulomb‐driven transitions in secondary structures from mostly helical to extended C5‐type hydrogen‐bonded structures. Support for this interpretation comes from simple energy considerations as well as from quantum chemical calculations on model peptides. This transition in secondary structure is most likely universal for isolated proteins that occur in mass spectrometric experiments. 相似文献
104.
105.
We present experimental evidence for the spontaneous formation of a macroscopic spin polarization in overlapping regions of two independent Bose-Einstein condensates produced in different hyperfine states of 87Rb. The condensates are independent in the sense that we do not explicitly introduce a relative phase between them. A single "spin-tip" pulse maps the transverse spin polarization into longitudinal spin polarization, and the atomic density distributions are measured with a Stern-Gerlach imaging method. The resulting matter-wave interference patterns are anticorrelated. 相似文献
106.
We report a resonantly fiber-laser-pumped Er:YAG laser operating at the eye-safe wavelength of 1645 nm, exhibiting 43% optical efficiency and 54% incident slope efficiency and emitting 7-W average power when repetitively Q switched at 10 kHz. To our knowledge, this is the best performance (conversion efficiency and average power) obtained from a bulk solid-state Q-switched erbium laser. At a 1.1-kHz pulse repetition frequency the laser produces 3.4-mJ pulses with a corresponding peak power of 162 kW. Frequency doubling to produce 822.5-nm, 4.7-kW pulses at 10 kHz was performed to demonstrate the laser's utility. 相似文献
107.
The influence of material and thickness on the subwavelength imaging performance of a negative dielectric constant slab is studied. Resonance in the plane-wave transfer function produces a high spatial frequency ripple that could be useful in fabricating periodic structures. A cost function based on the plane-wave transfer function provides a useful metric to evaluate the planar slab lens performance, and using this, the optimal slab dielectric constant can be determined. 相似文献
108.
Kevin Ann 《Physics letters. A》2008,372(5):579-583
We demonstrate the existence of entanglement sudden death (ESD), the complete loss of entanglement in finite time, in qubit-qutrit systems. In particular, ESD is shown to occur in such systems initially prepared in a one-parameter class of entangled mixed states and then subjected to local dephasing noise. Together with previous results, this proves the existence of ESD for some states in all quantum systems for which rigorously defined mixed-state entanglement measures have been identified. We conjecture that ESD exists in all quantum systems prepared in appropriate bipartite states. 相似文献
109.
Dr. Kevin Pappert Dr. Kateryna Loza Dr. Meital Shviro Dr. Ulrich Hagemann Dr. Marc Heggen Prof. Dr. Rafal E. Dunin-Borkowski Dr. Roland Schierholz Dr. Takuya Maeda Prof. Dr. Kenji Kaneko Prof. Dr. Matthias Epple 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(47):11048-11057
Porous particle superstructures of about 15 nm diameter, consisting of ultrasmall nanoparticles of iridium and iridium dioxide, are prepared through the reduction of sodium hexachloridoiridate(+IV) with sodium citrate/sodium borohydride in water. The water-dispersible porous particles contain about 20 wt % poly(N-vinylpyrrolidone) (PVP), which was added for colloidal stabilization. High-resolution transmission electron microscopy confirms the presence of both iridium and iridium dioxide primary particles (1–2 nm) in each porous superstructure. The internal porosity (≈58 vol%) is demonstrated by electron tomography. In situ transmission electron microscopy up to 1000 °C under oxygen, nitrogen, argon/hydrogen (all at 1 bar), and vacuum shows that the porous particles undergo sintering and subsequent compaction upon heating, a process that starts at around 250 °C and is completed at around 800 °C. Finally, well-crystalline iridium dioxide is obtained under all four environments. The catalytic activity of the as-prepared porous superstructures in electrochemical water splitting (oxygen evolution reaction; OER) is reduced considerably upon heating owing to sintering of the pores and loss of internal surface area. 相似文献
110.
Kevin Salzmann Dr. Candela Segarra Prof. Dr. Martin Albrecht 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(23):9017-9021
An exceptionally efficient ruthenium-based catalyst for olefin oxidation has been designed by exploiting N,N′-bis(pyridylidene)oxalamide (bisPYA) as a donor-flexible ligand. The dynamic donor ability of the bisPYA ligand, imparted by variable zwitterionic and neutral resonance structure contributions, paired with the redox activity of ruthenium provided catalytic activity for Lemieux–Johnson-type oxidative cleavage of olefins to efficiently prepare ketones and aldehydes. The ruthenium bisPYA complex significantly outperforms state-of-the-art systems and displays extraordinary catalytic activity in this oxidation, reaching turnover frequencies of 650 000 h−1 and turnover numbers of several millions. 相似文献