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911.
912.
Kentaro Miki 《中国物理 C》2007,31(12)
Azimuthal anisotropy of direct photon is measured in (√SNN)=200GeV Au Au collisions at RHICPHENIX. Direct photon is one of the most effective probes to study properties of hot dence medium at initial state (also QGP state) of heavy ion collisions because photons almost do not interact strongly with any other particles caused by its long mean free path and they keep their conditions when they are created. Within statistical and systematic errors, the elliptic flow parameter (v2) of direct photon is consistent with zero.Direct photon v2 is estimated by hadron decay photon contamination are subtracted from inclusive photon v2 in intermediate to high transverse momentum (pT) region (0 to 10GeV/c) for 3 centrality selections (20% steps) and minimum bias. 相似文献
913.
Kotaro Suzaki Kentaro Tsuchiya Atsumu Tezaki 《Proceedings of the Combustion Institute》2007,31(1):295-303
The time resolved product formation in oxidation of dimethyl ether (DME) has been studied between 298-625 K and 20-90 torr total pressure. Near-infrared frequency modulation spectroscopy (FMS) with Herriott type multi pass optics and UV absorption spectroscopy (UV) were conducted in the same cell. The reaction was initiated by pulsed photolysis in a mixture of Cl2, O2, and DME via CH3OCH2 radical formation. The reaction process was investigated through FMS measurement of HO2 and OH, and UV measurement of CH3OCH2O2. The yields of HO2 and OH are obtained by comparison with reference mixtures, Cl2, O2, and CH3OH for HO2, and Cl2, O2, CH3OH, and NO for OH, which convert 100% of initial Cl to HO2 and OH. The CH3OCH2O2 yield is also obtained. It was found that the HO2 yield increases sharply over 500 K mainly with a longer time constant than that of R + O2 reaction, while a prompt component exists throughout the temperature range at a few percent yield. OH was found to be produced promptly at a yield considerably larger than that known for the simplest alkanes. The CH3OCH2O2 profile has a prompt rise followed by a gradual decay whose rate is consistent with the slow HO2 formation. The species profiles were successfully predicted with a model constructed by modifying the existing one to suit the reduced pressure condition. After modification, it was inferred that the HO2 formation over 500 K is secondary from HCHO + OH and HCO + O2 and a part of HCO is formed directly from the O2 adduct, whereas the HO2 formation below 500 K is governed by CH3OCH2O2 chemistry. The HCO forming pathway via isomerization-decomposition of the O2 adduct, which was not included in the former models, was supported by our quantum-chemical calculations. 相似文献
914.
P-type InP single crystals doped with zinc or cadmium have been prepared from a solution using indium as a solvent in which a temperature gradient was maintained for the transport of the InP solute. The average growth rate was between 1.1 and 3.0 mm/week. The room temperature hole concentration of the crystals obtained was in a range of 1017 to 1018 cm-3. The distribution coefficients of zinc and cadmium were 0.8 and 0.004, respectively. The temperature gradient method makes it possible to dope the crystals with volatile impurities in a controlled manner. 相似文献
915.
Poecillastrin E,F, and G,cytotoxic chondropsin-type macrolides from a marine sponge Poecillastra sp.
Raku Irie Yuki Hitora Yuji Ise Shigeru Okada Kentaro Takada Shigeki Matsunaga 《Tetrahedron》2018,74(13):1430-1434
Poecillastrin E (1), F (2), and G (3) were isolated from a marine sponge Poecillastra sp. as the cytotoxic constituents. Their planar structures were determined by analyzing the MS and NMR spectra. They are closely related to the known poecillastrin C (4). The absolute configuration of the β-hydroxyaspartic acid (OHAsp) residue was determined to be D-threo by Marfey's analysis of the hydrolysate. The mode of lactone ring formation of OHAsp residue in 1–3 was determined by selective reduction of the ester linkage followed by acid hydrolysis. 相似文献
916.
Per atom muon capture ratios and effects of molecular structure on muon capture by γ-Fe2O3 and Fe3O4
Ninomiya Kazuhiko Kajino Meito Inagaki Makoto Terada Kentaro Sato Akira Tomono Dai Kawashima Yoshitaka Shinohara Atsushi 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(1):403-408
Journal of Radioanalytical and Nuclear Chemistry - An elemental analysis method utilizing muons has been demonstrated to be effective for non-destructive and quantitative analysis of precious bulk... 相似文献
917.
Arai K Lucarini S Salter MM Ohta K Yamashita Y Kobayashi S 《Journal of the American Chemical Society》2007,129(26):8103-8111
The discovery and development of a new Lewis acid system based on a complex formed from niobium(V) methoxide and (R)-3,3'-bis(2-hydroxy-3-isopropylbenzyl)-1,1'-binaphthalene-2,2'-diol, a novel tetradentate BINOL derivative, is presented. The system was shown to be extremely effective in promoting the desymmetrative ring opening of linear and cyclic meso-epoxides using anilines as nucelophiles, delivering the corresponding (R,R) anti-amino alcohols in good to excellent yields (up to quantitative) and excellent enantioselectivity (up to 96% ee). Furthermore, the catalyst system displays a remarkable sensitivity to steric bulk at the beta-carbon of the epoxide, selectively facilitating ring opening of smaller epoxides in the presence of more sterically hindered epoxides. This property was confirmed by a series of competition reactions using a mixture of meso-2-butene oxide and another aliphatic meso-epoxide, with the result that the former, less encumbered epoxide reacted preferentially with up to 98% chemical selectivity. While it was found to be most convenient to conduct the reactions with 10 mol % catalyst loading at 0.16 M, at higher overall concentration the reaction still proceeded efficiently with as little as 0.25 mol % catalyst to give the desired products with no significant reduction in yields or enantioselectivities. In addition, the current catalyst system was also found to mediate the asymmetric ring opening of nonsymmetrical cis-2-alkene oxides with anilines to give preferentially the corresponding (2R,3R)-2-amino-3-ols arising from ring opening at the methyl terminus, in excellent yields (up to quantitative) and good to excellent regio- and enantioselectivities (up to 18:1 and >99% ee, respectively). Intriguingly, it was discovered that the same catalyst system also promoted the ring-opening desymmetrization of aziridines with aniline nucleophiles to give the corresponding (S,S) vicinal diamines in good to excellent yields and enantioselectivity (up to 95% and 84% ee [>99% ee following a single recrystallization]). Catalyst systems that promote closely related reactions with opposite stereochemical outcomes in high selectivity such as the current niobium system are extremely unusual. To the best of our knowledge, this report constitutes not only the first example of the catalytic desymmetrization of both meso-epoxides and meso-aziridines but also a rare example of such complementary stereoselectivity in a catalytic reaction. 相似文献
918.
A diarylethene possessing one [4]thiaheterohelicene and one benzothiophene, the latter with a chiral methoxymethoxyethyl group on its C-3 position, was proved to work as a switch of specific optical rotation at a wavelength at which both colored and colorless forms have no absorption in solution. The difference of the specific optical rotation was 1300 degrees between the open form and the photostationary state. The specific optical rotation of one of the isolated optically active major colored forms was -4680 degrees. The conversion to the colored form was 64%, and the diastereomeric excess of photocyclization was 47%. 相似文献
919.
Thermolysis of 3,3-di-tert-butylthiirane-2-thione S-oxide 4 gave di-tert-butyl ketone 5 and carbon disulfide (CS2). Treatment of α-dithiolactone S-oxide 4 with excess m-CPBA or triphenylphosphine gave di-tert-butylthioketene S-oxide 3 almost quantitatively. Treatment of 4 with (η2-ethylene)bis(triphenylphosphine)platinum(0) 13 or tetrakis(triphenylphosphine) palladium 17 resulted in the formation of thiolato sulfinato-platinum complex 15 or palladium complex 18, respectively. The structure of complex 15 was determined by X-ray crystallographic analysis. 相似文献
920.
Sulfurization of β-dithiolactone (4) gave corresponding 1,2-dithiolane-3-thione (2a) via an ionic intermediate. Oxidation of β-dithiolactone 4 by m-CPBA afforded corresponding S-oxide (11), while dioxide (12) was obtained when 3 equiv of m-CPBA was used. Dithiolane-3-thione 2a reacted with ethylenebis(triphenylphosphine)platinum or tetrakis(triphenylphosphine)palladium to afford the corresponding dithiolato-platinum (20) and dithiolato-palladium (21) complexes in good yields. 相似文献