全文获取类型
收费全文 | 29010篇 |
免费 | 5998篇 |
国内免费 | 9003篇 |
专业分类
化学 | 21508篇 |
晶体学 | 1177篇 |
力学 | 1965篇 |
综合类 | 1023篇 |
数学 | 4576篇 |
物理学 | 13762篇 |
出版年
2024年 | 94篇 |
2023年 | 377篇 |
2022年 | 1014篇 |
2021年 | 1065篇 |
2020年 | 1107篇 |
2019年 | 1040篇 |
2018年 | 1004篇 |
2017年 | 1237篇 |
2016年 | 1127篇 |
2015年 | 1527篇 |
2014年 | 1680篇 |
2013年 | 2242篇 |
2012年 | 2441篇 |
2011年 | 2601篇 |
2010年 | 2318篇 |
2009年 | 2372篇 |
2008年 | 2783篇 |
2007年 | 2420篇 |
2006年 | 2278篇 |
2005年 | 1961篇 |
2004年 | 1570篇 |
2003年 | 1276篇 |
2002年 | 1308篇 |
2001年 | 1267篇 |
2000年 | 1201篇 |
1999年 | 806篇 |
1998年 | 447篇 |
1997年 | 351篇 |
1996年 | 393篇 |
1995年 | 359篇 |
1994年 | 319篇 |
1993年 | 286篇 |
1992年 | 243篇 |
1991年 | 201篇 |
1990年 | 213篇 |
1989年 | 186篇 |
1988年 | 151篇 |
1987年 | 122篇 |
1986年 | 100篇 |
1985年 | 72篇 |
1984年 | 93篇 |
1983年 | 89篇 |
1982年 | 75篇 |
1981年 | 53篇 |
1980年 | 38篇 |
1979年 | 30篇 |
1978年 | 14篇 |
1977年 | 10篇 |
1973年 | 8篇 |
1959年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
de Broglie relation is revisited, in consideration of a generalization of canonical commuting relation. The possible effects on particle's localization and black hole physics are also discussed, in a heuristic manner. 相似文献
52.
建立蝙蝠发声组织模型对超声机理研究及在智能设备的应用具有重要意义。根据蝙蝠喉部发声组织结构特点,通过有限元方法构建了蝙蝠的3种不同发声组织模型,分析了尺寸、材料力学参数、组织结构和张力4个因素对发声组织特征频率的影响。结果表明,如果用人类声带,按比例缩小构建蝙蝠喉部组织模型,蝙蝠无法发出超声波。构建组织结构含甲状软骨和声带的半鼓状模型和只含声带的条状模型,两种模型的特征频率相近且在合理的参数域内均无法达到超声范围。而含膜条状模型的特征频率可以通过张力进行超声频率的调节,这与文献的实验结果一致。因此,可基于含膜条状模型对蝙蝠喉管发声组织进行建模及其发声机理研究。 相似文献
53.
Twin-field quantum key distribution (TF-QKD) has attracted considerable attention because it can exceed the basic rate-distance limit without quantum repeaters. Its variant protocol, sending or not-sending quantum key distribution (SNS-QKD), not only fixes the security vulnerability of TF-QKD, but also can tolerate large misalignment errors. However, the current SNS-QKD protocol is based on the active decoy-state method, which may lead to side channel information leakage when multiple light intensities are modulated in practice. In this work, we propose a passive decoy-state SNS-QKD protocol to further enhance the security of SNS-QKD. Numerical simulation results show that the protocol not only improves the security in source, but also retains the advantages of tolerating large misalignment errors. Therefore, it may provide further guidance for the practical application of SNS-QKD. 相似文献
54.
偏序集上的滤子极大理想 总被引:3,自引:1,他引:2
在偏序集上引入并考察了滤子极大理想的概念,证明了相应的存在性定理。引入并考察了伪极大元和伪既约元的概念,利用图表的形式对连续格中各种类型的既约元和素元之间的关系进行了归纳总结,完善了文献《Continuous Lattices and Domains》(作者:G.Gierz,et al)中的一个图表的相关内容,填补了在分配的连续格情形该图表的一个未知内容,部分地回答了该文献中的一个问题。 相似文献
55.
56.
Jie Wang Yuntian Xing Yang Dai Yingnan Li Wenyan Xiang Jianrong Dai Fei Xu 《Molecules (Basel, Switzerland)》2022,27(13)
Pomacea canaliculata, one of the 100 most destructive invasive species in the world, and it is an important intermediate host of Angiostrongylus cantonensis. The molluscicides in current use are an effective method for controlling snails. However, most molluscicides have no slow-release effect and are toxic to nontarget organisms. Thus, these molluscicides cannot be used on a large scale to effectively act on snails. In this study, gelatin, a safe and nontoxic substance, was combined with sustained-release molluscicide and was found to reduce the toxicity of niclosamide to nontarget organisms. We assessed the effects of gelatin and molluscicide in controlling P. canaliculata snails and eggs. The results demonstrated that the niclosamide retention time with 1.0% and 1.5% gelatin sustained-release agents reached 20 days. Additionally, the mortality rate of P. canaliculata and their eggs increased as the concentration of the niclosamide sustained-release agents increased. The adult mortality rate of P. canaliculata reached 50% after the snails were exposed to gelatin with 0.1 mg/L niclosamide for 48 h. The hatching rate of P. canaliculata was only 28.5% of the normal group after the treatment was applied. The sustained-release molluscicide at this concentration was less toxic to zebrafish, which means that this molluscicide can increase the safety of niclosamide to control P. canaliculata in aquatic environments. In this study, we explored the safety of using niclosamide sustained-release agents with gelatin against P. canaliculata. The results suggest that gelatin is an ideal sustained-release agent that can provide a foundation for subsequent improvements in control of P. canaliculata. 相似文献
57.
桑蚕种良卵率是蚕种质量检验的重要指标,控制样本间卵粒数的偏差是保证良卵率准确性的关键。通过对桑蚕卵粒重的调查分析,得出其分布服从正态分布。若从一批蚕种中抽取1g卵作为样本,则来自同一总体的2个样本的卵粒数之差不超过16粒,其置信概率为95%;当置信概率取99%时,两个样本的卵粒数之差不超过21粒。文章为蚕业生产提供了一种实用的克卵粒数偏差控制方法。 相似文献
58.
59.
Mengya Kong Yuyang Gu Yingjie Chai Jiaming Ke Yulai Liu Xincheng Xu Zhanxian Li Wei Feng Fuyou Li 《中国科学:化学(英文版)》2021,(6):974-984
Luminescence nanothermometry makes non-invasive and real-time temperature readings possible in living animals. However,the spectral fluctuation in tissues and fluids, as well as the interaction between fluorophores and environment hinders accuracy of the thermometry. Here, we report a luminescence lifetime-based nanothermometry which specifically addresses this problem. A temporal based calibration(lifetime sensing) in the NIR range, an endogenous thermal response as well as a polymer encapsulation evading environmental factors, altogether help to pinpoint temperature in vivo. Thanks to the highly condensed NdYb ions in a well-protected tiny core-shell nanocrystal(overall 11 nm), a temperature sensitivity about 2.07% K~(-1)(with 5% Yb~(3+) doped nanoparticles) and an accuracy of 0.27 K(with 25% Yb~(3+) doped nanoparticles) in biological fluids are achieved.Hopefully, combining thermally activated energy transfer nanothermometer with anti-interference lifetime thermometry would provide a more accurate temperature measurement for biological and preclinical studies. 相似文献
60.
Jinlong Cai Yongtong Xiong Xiang Zhu Jinyu Hu Yunping Wang Junkai Li Jianfeng Wu Qinglai Wu 《Molecules (Basel, Switzerland)》2022,27(15)
The Kleier model and Carrier-mediated theory are effective for molecularly designing pesticides with phloem mobility. However, the single Kleier model or Carrier-mediated theory cannot achieve a reliable explanation of the phloem mobility of all exogenous substances. A detailed investigation of the two models and the scope of their applications can provide a more accurate and highly efficient basis for the guidance of the design and development of phloem-mobile pesticides. In the present paper, a strategy using active ingredient-amino acid conjugates as mode compounds is developed based on Carrier-mediated theory. An N-alkylated amino acid is used to improve the pesticide’s physicochemical properties following the Kleier model, thus allowing the conjugates to fall on the predicted and more accessible transportation region of phloem. Moreover, the influence of this movement on phloem is inspected by the Kleier model and Carrier-mediated theory. To verify this strategy, a series of N-alkylated phenazine-1-carboxylic acid-glycine compounds (PCA-Gly) were designed and synthesized. The results related to the castor bean seeds (R. communis L.) indicated that all the target compounds (4a–4f) had phloem mobility. The capacity for phloem mobility shows that N-alkylated glycine containing small substituents can significantly improve PCA phloem mobility, such as 4c(i-C3H7-N) > 4a(CH3-N) ≈ 4b(C2H5-N) > 4d (t-C4H9-N) > PCA-Gly > 4e(C6H5-N) > 4f(CH2COOH-N), with an oil–water partition coefficient between 1.2~2.5. In particular, compounds 4a(CH3-N), 4b(C2H5-N), and 4c(i-C3H7-N) present better phloem mobility, with the average concentrations in phloem sap of 14.62 μΜ, 13.98 μΜ, and 17.63 μΜ in the first 5 h, which are 8 to 10 times higher than PCA-Gly (1.71 μΜ). The results reveal that the Kleier model and Carrier-mediated theory play a guiding role in the design of phloem-mobile pesticides. However, the single Kleier model or Carrier-mediated theory are not entirely accurate. Still, there is a synergism between Carrier-mediated theory and the Kleier model for promoting the phloem transport of exogenous compounds. Therefore, we suggest the introduction of endogenous plant compounds as a promoiety to improve the phloem mobility of pesticides through Carrier-mediated theory. It is necessary to consider the improvement of physicochemical properties according to the Kleier model, which can contribute to a scientific theory for developing phloem-mobile pesticides. 相似文献