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991.
San Vicente B Navarro Villoslada F Moreno-Bondi MC 《Analytical and bioanalytical chemistry》2004,380(1):115-122
A bisphenol A (BPA) molecularly imprinted polymer, the composition of which was optimised using a chemometric approach, has been applied to the selective preconcentration of the template from aqueous samples. The selectivity of the polymer toward BPA and related compounds was evaluated chromatographically. The BPA-imprinted polymer was packed in a column and used for continuous on-column solid-phase extraction (MISPE) of aqueous samples followed by subsequent analysis by HPLC with fluorescence detection of the eluted fractions. The composition of the washing solvent applied in the MISPE procedure was optimised to favour the specific interactions of the MIP with BPA and to remove the non-selectively bound matrix components. The MISPE method has proven to be effective for selective preconcentration of BPA in aqueous samples (recoveries >84% obtained in the eluate for 10–100 mL sample volumes) enabling detection and quantification limits of 1.0 and 3.3 ng mL–1, respectively (based on 25 mL sample size). Analytical recoveries were between 92 and 101% for river water samples spiked with known amounts of BPA (30, 60, and 80 ng mL–1); relative standard deviations (RSD) were lower than 5.0%. 相似文献
992.
On the Korteweg-de Vries equation 总被引:7,自引:0,他引:7
Tosio Kato 《manuscripta mathematica》1979,28(1-3):89-99
Existence, uniqueness, and continuous dependence on the initial data are proved for the local (in time) solution of the (generalized) Korteweg-de Vries equation on the real line, with the initial function in the Sobolev space of order s>3/2 and the solution u(t) staying in the same space, s= being included For the proper KdV equation, existence of global solutions follows if s2. The proof is based on the theory of abstract quasilinear evolution equations developed elsewhere.Dedicated to Hans Lewy and Charles B. Morrey Jr.Partially supported by NSF Grant MCS76-04655. 相似文献
993.
H. Spieler H. J. K?rner K. E. Rehm M. Richter H. P. Rother 《Zeitschrift für Physik A Hadrons and Nuclei》1976,53(5):241-250
The reactions120Sn+72 MeV18O and122Sn+74 MeV16O were investigated with time of-flightE-E-telescopes. Data are presented for all quasi-elastic reaction channels. The two neutron stripping and pickup reactions (18O,16O), (18O,20O) and (16O,18O) are analyzed in detail. It is shown that these heavy ion induced two neutron transfer reactions proceed with essentially the same type of selectivity as the corresponding light ion induced reactions. The differential cross sections for transfer reactions leaving the120, 122Sn nuclei in their 2+ first excited states are shown to be influenced by interference effects due to additional inelastic excitations. 相似文献
994.
I. Tserruya R. Schulé H. Schmidt-B?cking K. Bethge 《Zeitschrift für Physik A Hadrons and Nuclei》1976,89(1):233-241
TheK-shell ionization cross sections of Mn, Ni, Cu, Zn and Ge under32S bombardment have been measured in the energy range from 5 to 48 MeV. The cross sections are compared with available theories based on a direct Coulomb ionization mechanism and with the predictions of theK-vacancy sharing process. This last process can reasonably account for the measured cross sections at high bombarding energies. The energy shifts of theK
- andK
-lines and theK
/K
-intensity ratios have also been measured. This information is used to deduce the defect configuration of the atoms. The mechanisms responsible for the multiple vacancy production are discussed. 相似文献
995.
996.
Lubomír Kubá?ek 《Mathematica Slovaca》2012,62(4):765-774
An uncertainty of an estimated parameter can be, in general, decomposed into two parts, i.e. an uncertainty caused by errors in the actual experiment (the type A uncertainty) and an uncertainty caused by errors in preceding experiment, where some wanted constants were estimated (the type B uncertainty). These constants are necessary for an estimation of the useful parameters. The aim of the paper is to find a condition for elimination of the type B uncertainty. 相似文献
997.
998.
I. P. Studenyak V. E. Ponomaryov M. Kranj?ec Yu. V. Minets L. M. Suslikov 《Journal of Applied Spectroscopy》2012,79(1):83-86
The effect of anionic substitution of halogen atoms on the spectral position and shape of the optical absorption edge and
the dispersion of the refractive index of crystals of Cu6PS5I1–xClx solid solutions are studied. The concentration dependences of the width of the optical pseudogap, refractive index, and lattice
parameters are shown to be interrelated in these solid solution crystals. 相似文献
999.
1000.
Ruthenium‐Catalyzed Cycloisomerization of 2,2′‐Diethynyl‐ biphenyls Involving Cleavage of a Carbon–Carbon Triple Bond 下载免费PDF全文
Prof. Dr. Takanori Matsuda Kotaro Kato Tsuyoshi Goya Shingo Shimada Prof. Dr. Masahiro Murakami 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(6):1941-1943
A ruthenium complex catalyzes a new cycloisomerization reaction of 2,2′‐diethynylbiphenyls to form 9‐ethynylphenanthrenes, thereby cleaving the carbon–carbon triple bond of the original ethynyl group. A metal–vinylidene complex is generated from one of the two ethynyl groups, and its carbon–carbon double bond undergoes a [2+2] cycloaddition with the other ethynyl group to form a cyclobutene. The phenanthrene skeleton is constructed by the subsequent electrocyclic ring opening of the cyclobutene moiety. 相似文献