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71.
The retention behavior of polyethylene glycol (PEG) on different types of hydrophobic interaction chromatography (HIC) resins containing butyl, octyl, and phenyl ligands was analyzed. An incomplete elution or splitting of the polymer peak into two parts was observed, where the first one was eluted at the dead time of the column, whereas the second one was strongly retained. The phenomenon was attributed to conformation changes of the polymer upon its adsorption on hydrophobic surface. The effect enhanced with increasing molecular weight of the polymer and hydrophobicity of the HIC media. Addition of PEG to the mobile phase reduced binding of proteins to HIC resins, which was demonstrated with two model systems: lysozyme (LYZ) and immunoglobulin G (IgG), and their mixtures. In case of LYZ, the presence of PEG caused reduction in the protein retention, whereas for IgG—a decrease in efficiency of the protein capture. The effect depended on the adsorption pattern of PEG; it was pronounced in the systems in which conformational changes of the polymer were suggested to occur. 相似文献
72.
It is shown that two real functionsf andg, defined on a real intervalI, satisfy the inequalitiesf(x + (1 – )y) g(x) + (1 – )g(y) andg(x + (1 – )y) f(x) + (1 – )f(y) for allx, y I and [0, 1], iff there exists an affine functionh: I such thatf h g. As a consequence we obtain a stability result of Hyers—Ulam type for affine functions. 相似文献
73.
Bis(triethanolamine)ytterbium(II) diperchlorate was obtained by electrochemical reduction. The metal ion is surrounded by two triethanolamine molecules only, and its first sphere of coordination consists of six O and two N atoms. The compound shows weak luminescence at 77 K with a very broad emission band (488—667 nm). The complexation of triethanolamine shifts the Yb (III) reduction potential of 0.46 V towards more negative values. 相似文献
74.
The kinetics of the bromination of acetanilide has been studied with the diffusion layer titration method. The results have been obtained using the apparatus which consists of the ring-disc electrode and an amperostat-potentiostat system. Dependence of the ring current on the disc current has been determined as a function of rotation speeds of the electrode, of the solution concentration and temperature. It has been shown the bromination reaction of acetanilide exhibits by first order kinetics. In that case Br2 and Br3 ? are the brominating species. The rate of bromination changes with the concentration of the Br? ions. This reaction rate depends on reactions of molecular bromine with acetanilide. For 0.033<[Br?]<0.173M the rate constant changes in the following range: $$17530M^{ - 1} s^{ - 1}< k< 6400M^{ - 1} s^{ - 1} ([H + ] = 1,34;T = 298K)$$ 相似文献
75.
Immoos CE Sulc F Farmer PJ Czarnecki K Bocian DF Levina A Aitken JB Armstrong RS Lay PA 《Journal of the American Chemical Society》2005,127(3):814-815
The EXAFS and resonance Raman spectra on the HNO-myoglobin adduct, 1, are consistent with the presence of HNO bound to a heme center. The three-dimensional structure about the heme center of 1 obtained from multiple-scattering (MS) analysis of the EXAFS of the heme protein yielded an Fe-N-O bond angle of 131 degrees and an Fe-N bond length of 1.82 A, which compare well with published values for model complexes containing RNO ligands. Resonance Raman spectra identified the nu(N=O) stretch at 1385 cm-1 (confirmed by 15N labeling), which corresponds well with those reported for small molecule HNO complexes. The wavelength of the nu(Fe-N) at 636 cm-1 of 1 is significantly higher than those of MbIINO and MbIIINO (554 and 595 cm-1, respectively). The XAFS, XANES, and resonance Raman data are all consistent with the structure deduced from the NMR experiments, providing more detail on the bonding between HNO and the metal center. 相似文献
76.
We postulate the energy-momentum functionE for the ECSK theory of gravity and formulate the functional Hamiltonian equation in terms of the energy-momentum functionE and the symplectic 2-form . The system of partial differential equations which follows from the functional Hamilton equation is equivalent to the system of variational equations of the ECSK theory. The Hamiltonian method gives rise to a natural division of these equations into 10 constraint equations and the set of dynamical equations. We discuss the geometric sense of the constraint equations and their relations to the initial value problem. 相似文献
77.
Kazimierz Frąckiewicz 《General Relativity and Gravitation》1985,17(10):939-952
This paper is the first of a two-article series in which the connections between the gauge group, degeneration, and degrees of freedom in the ECSK theory coupled to an arbitrary tensor field are discussed. In this paper a multisymplectic formulation of the ECSK theory is presented and the symplectic 2-form, which plays a leading role in our considerations, is found. 相似文献
78.
A broad range echelle spectrograph with a CCD matrix detector is developed for different applications in atomic spectroscopy. The compact optical design in combination with a dispersive entrance slit illumination offers a low stray light level and high throughput in the UV spectral region comparable only with spectrographs of higher focal length. Ray tracing calculations for typical wavelengths and the multi-line spectrum of an iron arc show the excellent overall spectrum quality. The subtraction of two partial spectra of different steel alloys demonstrates the spectra evaluation possibilities of the CCD spectrograph. 相似文献
79.
Kazimierz Szymiczek 《代数通讯》2013,41(4):1125-1149
A Simplicial derivation procedure for crossed module valued functors is established. As a consequence, a theory of higher Baer invariants and relative homology is settle on crossed modules. Then we illustrative how this method is efficient, as it extends classical formulations and results, like various known five term sequences on crossed modules by Conduché and Ellis (1989), the author (1993) and Ladra and R-Grandjeán (1994). 相似文献
80.
Abstract Per(6-deoxy-6-halo) cyclodextrins (bromo, chloro or iodo) have been prepared in excellent yield and high selectivity by treatment of the native cyclodextrins with the corresponding N-halosuccinimide and triphenylphosphine in N,N-dimethylformamide. 相似文献